Ionic conductivity of the Na1+xMxIIIZr2−x(PO4)3 systems (M = Al, Ga, Cr, Fe, Sc, In, Y, Yb)
Identifieur interne : 000410 ( Main/Curation ); précédent : 000409; suivant : 000411Ionic conductivity of the Na1+xMxIIIZr2−x(PO4)3 systems (M = Al, Ga, Cr, Fe, Sc, In, Y, Yb)
Auteurs : RBID : ISTEX:10853_1990_Article_BF00582473.pdfAbstract
The existence and ionic conductivity of solid solutions Na1+xMxIIIZr2−x(PO4)3 with Nasicon-like structure have been investigated and the results compared with literature data. A limited range of solid solutions is formed with MIII = aluminium, gallium, yttrium, ytterbium, whereas a continuous series is obtained for MIII = chromium, iron, scandium, indium. The pure end member Na3ln2(PO4)3 is reported for the first time; according to powder diffraction data, it is hexagonal witha = 0.8966(1) andc = 2.2104(4) nm. The small monoclinic distortion already known for MIII = chromium, iron and scandium is restricted tox values very close to 2. Ionic conductivity measurements show that for a given value ofx, the mobility of the Na+ ions is strongly influenced both by the ionic radius and the type of electronic structure of the MIII ion. However, no simple correlation can be found.
DOI: 10.1007/BF00582473
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<author><name>J. M. Winand</name>
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<author><name>A. Rulmont</name>
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<author><name>P. Tarte</name>
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<front><div type="abstract" xml:lang="eng">The existence and ionic conductivity of solid solutions Na1+xMxIIIZr2−x(PO4)3 with Nasicon-like structure have been investigated and the results compared with literature data. A limited range of solid solutions is formed with MIII = aluminium, gallium, yttrium, ytterbium, whereas a continuous series is obtained for MIII = chromium, iron, scandium, indium. The pure end member Na3ln2(PO4)3 is reported for the first time; according to powder diffraction data, it is hexagonal witha = 0.8966(1) andc = 2.2104(4) nm. The small monoclinic distortion already known for MIII = chromium, iron and scandium is restricted tox values very close to 2. Ionic conductivity measurements show that for a given value ofx, the mobility of the Na+ ions is strongly influenced both by the ionic radius and the type of electronic structure of the MIII ion. However, no simple correlation can be found.</div>
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<abstract lang="eng">The existence and ionic conductivity of solid solutions Na1+xMxIIIZr2−x(PO4)3 with Nasicon-like structure have been investigated and the results compared with literature data. A limited range of solid solutions is formed with MIII = aluminium, gallium, yttrium, ytterbium, whereas a continuous series is obtained for MIII = chromium, iron, scandium, indium. The pure end member Na3ln2(PO4)3 is reported for the first time; according to powder diffraction data, it is hexagonal witha = 0.8966(1) andc = 2.2104(4) nm. The small monoclinic distortion already known for MIII = chromium, iron and scandium is restricted tox values very close to 2. Ionic conductivity measurements show that for a given value ofx, the mobility of the Na+ ions is strongly influenced both by the ionic radius and the type of electronic structure of the MIII ion. However, no simple correlation can be found.</abstract>
<relatedItem type="series"><titleInfo type="abbreviated"><title>J Mater Sci</title>
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<titleInfo><title>Journal of Materials Science</title>
<partNumber>Year: 1990</partNumber>
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