catena-Poly[[bis-[4-(dimethyl-amino)-pyridine-κN (1)]cobalt(II)]-di-μ-azido-κ(4) N (1):N (3)].
Identifieur interne : 000034 ( PubMed/Curation ); précédent : 000033; suivant : 000035catena-Poly[[bis-[4-(dimethyl-amino)-pyridine-κN (1)]cobalt(II)]-di-μ-azido-κ(4) N (1):N (3)].
Auteurs : Fatiha Guenifa [Algérie] ; Ouahida Zeghouan ; Nasreddine Hadjadj ; Lamia Bendjeddou ; Hocine MerazigSource :
- Acta crystallographica. Section E, Structure reports online ; 2013.
Abstract
The title layered polymer, [Co(N3)2(C7H10N2)2] n , contains Co(II), azide and 4-(dimethyl-amino)-pyridine (4-DMAP) species with site symmetries m2m, 2 and m, respectively. The Co(2+) ion adopts an octa-hedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co(II) atoms are connected by two bridging azide ligands, resulting in a chain parallel to the c axis.
DOI: 10.1107/S1600536813005205
PubMed: 23476514
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<author><name sortKey="Guenifa, Fatiha" sort="Guenifa, Fatiha" uniqKey="Guenifa F" first="Fatiha" last="Guenifa">Fatiha Guenifa</name>
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<front><div type="abstract" xml:lang="en">The title layered polymer, [Co(N3)2(C7H10N2)2] n , contains Co(II), azide and 4-(dimethyl-amino)-pyridine (4-DMAP) species with site symmetries m2m, 2 and m, respectively. The Co(2+) ion adopts an octa-hedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co(II) atoms are connected by two bridging azide ligands, resulting in a chain parallel to the c axis.</div>
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<Abstract><AbstractText>The title layered polymer, [Co(N3)2(C7H10N2)2] n , contains Co(II), azide and 4-(dimethyl-amino)-pyridine (4-DMAP) species with site symmetries m2m, 2 and m, respectively. The Co(2+) ion adopts an octa-hedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co(II) atoms are connected by two bridging azide ligands, resulting in a chain parallel to the c axis.</AbstractText>
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