Poly[[diaqua-bis-(μ2-4,4'-bipyrid-yl)cobalt(II)] dinitrate tetra-hydrate].
Identifieur interne : 000033 ( PubMed/Corpus ); précédent : 000032; suivant : 000034Poly[[diaqua-bis-(μ2-4,4'-bipyrid-yl)cobalt(II)] dinitrate tetra-hydrate].
Auteurs : Asma Lehleh ; Mehdi Boutebdja ; Adel Beghidja ; Chahrazed Beghidja ; Hocine MerazigSource :
- Acta crystallographica. Section E, Structure reports online ; 2013.
Abstract
The title compound, {[Co(C10H8N2)2(H2O)2](NO3)2·4H2O} n , (C10H8N2 = 4,4'-bipyridine = 4,4'-bpy) is a layered coordination polymer built up from a cationic square grid extending in (101) enclosing uncoordinating nitrate ions and water mol-ecules. The Co(II) ion has site symmetry 2 and one of the 4,4'-bpy ligands is generated by twofold symmetry [two N atoms and two C atoms lie on the rotation axis and the dihedral angle between the pyridine rings is 45.66 (5)°]. The other 4,4'-bpy ligand is generated by a crystallographic inversion center. The Co(II) ion exhibits a slightly distorted octa-hedral coordination geometry defined by two O atoms of two coordinating water mol-ecules and four N atoms from four bridging 4,4'-bpy ligands. The structure is consolidated by O-H⋯O, C-H⋯O and C-H⋯N hydrogen bonds.
DOI: 10.1107/S1600536813005230
PubMed: 23633984
Links to Exploration step
pubmed:23633984Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Poly[[diaqua-bis-(μ2-4,4'-bipyrid-yl)cobalt(II)] dinitrate tetra-hydrate].</title>
<author><name sortKey="Lehleh, Asma" sort="Lehleh, Asma" uniqKey="Lehleh A" first="Asma" last="Lehleh">Asma Lehleh</name>
<affiliation><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Boutebdja, Mehdi" sort="Boutebdja, Mehdi" uniqKey="Boutebdja M" first="Mehdi" last="Boutebdja">Mehdi Boutebdja</name>
</author>
<author><name sortKey="Beghidja, Adel" sort="Beghidja, Adel" uniqKey="Beghidja A" first="Adel" last="Beghidja">Adel Beghidja</name>
</author>
<author><name sortKey="Beghidja, Chahrazed" sort="Beghidja, Chahrazed" uniqKey="Beghidja C" first="Chahrazed" last="Beghidja">Chahrazed Beghidja</name>
</author>
<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2013">2013</date>
<idno type="RBID">pubmed:23633984</idno>
<idno type="pmid">23633984</idno>
<idno type="doi">10.1107/S1600536813005230</idno>
<idno type="wicri:Area/PubMed/Corpus">000033</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000033</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Poly[[diaqua-bis-(μ2-4,4'-bipyrid-yl)cobalt(II)] dinitrate tetra-hydrate].</title>
<author><name sortKey="Lehleh, Asma" sort="Lehleh, Asma" uniqKey="Lehleh A" first="Asma" last="Lehleh">Asma Lehleh</name>
<affiliation><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Boutebdja, Mehdi" sort="Boutebdja, Mehdi" uniqKey="Boutebdja M" first="Mehdi" last="Boutebdja">Mehdi Boutebdja</name>
</author>
<author><name sortKey="Beghidja, Adel" sort="Beghidja, Adel" uniqKey="Beghidja A" first="Adel" last="Beghidja">Adel Beghidja</name>
</author>
<author><name sortKey="Beghidja, Chahrazed" sort="Beghidja, Chahrazed" uniqKey="Beghidja C" first="Chahrazed" last="Beghidja">Chahrazed Beghidja</name>
</author>
<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
</author>
</analytic>
<series><title level="j">Acta crystallographica. Section E, Structure reports online</title>
<imprint><date when="2013" type="published">2013</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The title compound, {[Co(C10H8N2)2(H2O)2](NO3)2·4H2O} n , (C10H8N2 = 4,4'-bipyridine = 4,4'-bpy) is a layered coordination polymer built up from a cationic square grid extending in (101) enclosing uncoordinating nitrate ions and water mol-ecules. The Co(II) ion has site symmetry 2 and one of the 4,4'-bpy ligands is generated by twofold symmetry [two N atoms and two C atoms lie on the rotation axis and the dihedral angle between the pyridine rings is 45.66 (5)°]. The other 4,4'-bpy ligand is generated by a crystallographic inversion center. The Co(II) ion exhibits a slightly distorted octa-hedral coordination geometry defined by two O atoms of two coordinating water mol-ecules and four N atoms from four bridging 4,4'-bpy ligands. The structure is consolidated by O-H⋯O, C-H⋯O and C-H⋯N hydrogen bonds.</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">23633984</PMID>
<DateCreated><Year>2013</Year>
<Month>5</Month>
<Day>1</Day>
</DateCreated>
<DateCompleted><Year>2013</Year>
<Month>05</Month>
<Day>02</Day>
</DateCompleted>
<DateRevised><Year>2013</Year>
<Month>5</Month>
<Day>3</Day>
</DateRevised>
<Article PubModel="Electronic-Print"><Journal><JournalIssue CitedMedium="Print"><Volume>69</Volume>
<Issue>Pt 4</Issue>
<PubDate><Year>2013</Year>
<Month>Apr</Month>
<Day>1</Day>
</PubDate>
</JournalIssue>
<Title>Acta crystallographica. Section E, Structure reports online</Title>
<ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation>
</Journal>
<ArticleTitle>Poly[[diaqua-bis-(μ2-4,4'-bipyrid-yl)cobalt(II)] dinitrate tetra-hydrate].</ArticleTitle>
<Pagination><MedlinePgn>m177-8</MedlinePgn>
</Pagination>
<ELocationID EIdType="doi" ValidYN="Y">10.1107/S1600536813005230</ELocationID>
<Abstract><AbstractText>The title compound, {[Co(C10H8N2)2(H2O)2](NO3)2·4H2O} n , (C10H8N2 = 4,4'-bipyridine = 4,4'-bpy) is a layered coordination polymer built up from a cationic square grid extending in (101) enclosing uncoordinating nitrate ions and water mol-ecules. The Co(II) ion has site symmetry 2 and one of the 4,4'-bpy ligands is generated by twofold symmetry [two N atoms and two C atoms lie on the rotation axis and the dihedral angle between the pyridine rings is 45.66 (5)°]. The other 4,4'-bpy ligand is generated by a crystallographic inversion center. The Co(II) ion exhibits a slightly distorted octa-hedral coordination geometry defined by two O atoms of two coordinating water mol-ecules and four N atoms from four bridging 4,4'-bpy ligands. The structure is consolidated by O-H⋯O, C-H⋯O and C-H⋯N hydrogen bonds.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Lehleh</LastName>
<ForeName>Asma</ForeName>
<Initials>A</Initials>
<AffiliationInfo><Affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Boutebdja</LastName>
<ForeName>Mehdi</ForeName>
<Initials>M</Initials>
</Author>
<Author ValidYN="Y"><LastName>Beghidja</LastName>
<ForeName>Adel</ForeName>
<Initials>A</Initials>
</Author>
<Author ValidYN="Y"><LastName>Beghidja</LastName>
<ForeName>Chahrazed</ForeName>
<Initials>C</Initials>
</Author>
<Author ValidYN="Y"><LastName>Merazig</LastName>
<ForeName>Hocine</ForeName>
<Initials>H</Initials>
</Author>
</AuthorList>
<Language>ENG</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
<ArticleDate DateType="Electronic"><Year>2013</Year>
<Month>Mar</Month>
<Day>02</Day>
</ArticleDate>
</Article>
<MedlineJournalInfo><Country>United States</Country>
<MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA>
<NlmUniqueID>101089178</NlmUniqueID>
<ISSNLinking>1600-5368</ISSNLinking>
</MedlineJournalInfo>
<OtherID Source="NLM">PMC3629466</OtherID>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="received"><Year>2013</Year>
<Month>2</Month>
<Day>04</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="accepted"><Year>2013</Year>
<Month>2</Month>
<Day>23</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2013</Year>
<Month>5</Month>
<Day>2</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="pubmed"><Year>2013</Year>
<Month>5</Month>
<Day>2</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2013</Year>
<Month>5</Month>
<Day>2</Day>
<Hour>6</Hour>
<Minute>1</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>epublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">23633984</ArticleId>
<ArticleId IdType="doi">10.1107/S1600536813005230</ArticleId>
<ArticleId IdType="pii">hb7035</ArticleId>
<ArticleId IdType="pmc">PMC3629466</ArticleId>
</ArticleIdList>
</PubmedData>
</pubmed>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/PubMed/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000033 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd -nk 000033 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Terre |area= CobaltMaghrebV1 |flux= PubMed |étape= Corpus |type= RBID |clé= pubmed:23633984 |texte= Poly[[diaqua-bis-(μ2-4,4'-bipyrid-yl)cobalt(II)] dinitrate tetra-hydrate]. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/RBID.i -Sk "pubmed:23633984" \ | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd \ | NlmPubMed2Wicri -a CobaltMaghrebV1
![]() | This area was generated with Dilib version V0.6.32. | ![]() |