Bis[tris-(phenanthroline-κ(2) N,N')cobalt(II)] undeca-tungsto(VI)vanado(V)phosphate dihydrate.
Identifieur interne : 000022 ( PubMed/Corpus ); précédent : 000021; suivant : 000023Bis[tris-(phenanthroline-κ(2) N,N')cobalt(II)] undeca-tungsto(VI)vanado(V)phosphate dihydrate.
Auteurs : Assia Hajsalem ; Sameh Aoun ; Aurelien Planchat ; Mohamed Rzaigui ; Samah Akriche ToumiSource :
- Acta crystallographica. Section E, Structure reports online ; 2014.
Abstract
In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co(2+) ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octa-hedron. Possible very weak intra-molecular C-H⋯π inter-actions occur in the cation. In the crystal, the components are linked by O-H⋯O and C-H⋯O inter-actions, building a three-dimensional network featuring one-dimensional voids along the c-axis direction.
DOI: 10.1107/S160053681400484X
PubMed: 24826091
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Section E, Structure reports online</title><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co(2+) ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octa-hedron. Possible very weak intra-molecular C-H⋯π inter-actions occur in the cation. In the crystal, the components are linked by O-H⋯O and C-H⋯O inter-actions, building a three-dimensional network featuring one-dimensional voids along the c-axis direction.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">24826091</PMID><DateCreated><Year>2014</Year><Month>5</Month><Day>14</Day></DateCreated><DateCompleted><Year>2014</Year><Month>05</Month><Day>14</Day></DateCompleted><DateRevised><Year>2014</Year><Month>5</Month><Day>19</Day></DateRevised><Article PubModel="Electronic-eCollection"><Journal><JournalIssue CitedMedium="Print"><Volume>70</Volume><Issue>Pt 4</Issue><PubDate><Year>2014</Year><Month>Apr</Month><Day>1</Day></PubDate></JournalIssue><Title>Acta crystallographica. Section E, Structure reports online</Title><ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation></Journal><ArticleTitle>Bis[tris-(phenanthroline-κ(2) N,N')cobalt(II)] undeca-tungsto(VI)vanado(V)phosphate dihydrate.</ArticleTitle><Pagination><MedlinePgn>m125-6</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S160053681400484X</ELocationID><Abstract><AbstractText>In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co(2+) ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octa-hedron. Possible very weak intra-molecular C-H⋯π inter-actions occur in the cation. In the crystal, the components are linked by O-H⋯O and C-H⋯O inter-actions, building a three-dimensional network featuring one-dimensional voids along the c-axis direction.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Hajsalem</LastName><ForeName>Assia</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Aoun</LastName><ForeName>Sameh</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>Laboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Planchat</LastName><ForeName>Aurelien</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>Laboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rzaigui</LastName><ForeName>Mohamed</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Toumi</LastName><ForeName>Samah Akriche</ForeName><Initials>SA</Initials><AffiliationInfo><Affiliation>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2014</Year><Month>Mar</Month><Day>08</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA><NlmUniqueID>101089178</NlmUniqueID><ISSNLinking>1600-5368</ISSNLinking></MedlineJournalInfo><OtherID Source="NLM">PMC3998553</OtherID></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2014</Year><Month>2</Month><Day>26</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2014</Year><Month>3</Month><Day>03</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>5</Month><Day>15</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>5</Month><Day>16</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>5</Month><Day>16</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">24826091</ArticleId><ArticleId IdType="doi">10.1107/S160053681400484X</ArticleId><ArticleId IdType="pii">hb7203</ArticleId><ArticleId IdType="pmc">PMC3998553</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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