Bis{bis-(azido-κN)bis-[bis-(pyridin-2-yl-κN)amine]cobalt(III)} sulfate dihydrate.
Identifieur interne : 000004 ( PubMed/Corpus ); précédent : 000003; suivant : 000005Bis{bis-(azido-κN)bis-[bis-(pyridin-2-yl-κN)amine]cobalt(III)} sulfate dihydrate.
Auteurs : Fatima Setifi ; Jacqueline M. Knaust ; Zouaoui Setifi ; Rachid TouzaniSource :
- Acta crystallographica. Section E, Crystallographic communications ; 2016.
Abstract
The search for new mol-ecular materials with inter-esting magnetic properties, using the pseudohalide azide ion and di-2-pyridyl-amine (dpa, C10H9N3) as a chelating ligand, led to the synthesis and structure determination of the title compound, [Co(N3)2(dpa)2]2SO4·2H2O. The crystal structure comprises discrete [Co(dpa)2(N3)2](+) cations, sulfate anions, as well as H2O solvent mol-ecules. The Co(III) cations display a slightly distorted octa-hedral coordination sphere defined by two N atoms from azide anions and four N atoms from the pyridyl rings of two dpa ligands. In the crystal, extensive C-H⋯O, N-H⋯O, and O-H⋯O inter-actions result in supra-molecular sheets that lie parallel to the ab plane. The sheets are further linked through O-H⋯N inter-actions between the water mol-ecules of one sheet and azide anions of another sheet, forming a supra-molecular framework.
DOI: 10.1107/S2056989016003662
PubMed: 27375867
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Knaust</name><affiliation><nlm:affiliation>Department of Chemistry, Mathematics and Physics, Clarion University, 840 Wood Street, Clarion, PA 16214, USA.</nlm:affiliation></affiliation></author><author><name sortKey="Setifi, Zouaoui" sort="Setifi, Zouaoui" uniqKey="Setifi Z" first="Zouaoui" last="Setifi">Zouaoui Setifi</name><affiliation><nlm:affiliation>Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.</nlm:affiliation></affiliation></author><author><name sortKey="Touzani, Rachid" sort="Touzani, Rachid" uniqKey="Touzani R" first="Rachid" last="Touzani">Rachid Touzani</name><affiliation><nlm:affiliation>Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000, Oujda, Morocco, and, Faculté Pluridisciplinaire Nador BP 300, Selouane, 62702, Nador, Morocco.</nlm:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2016">2016</date><idno type="RBID">pubmed:27375867</idno><idno type="pmid">27375867</idno><idno type="doi">10.1107/S2056989016003662</idno><idno type="wicri:Area/PubMed/Corpus">000004</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000004</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Bis{bis-(azido-κN)bis-[bis-(pyridin-2-yl-κN)amine]cobalt(III)} sulfate dihydrate.</title><author><name sortKey="Setifi, Fatima" sort="Setifi, Fatima" uniqKey="Setifi F" first="Fatima" last="Setifi">Fatima Setifi</name><affiliation><nlm:affiliation>Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.</nlm:affiliation></affiliation></author><author><name sortKey="Knaust, Jacqueline M" sort="Knaust, Jacqueline M" uniqKey="Knaust J" first="Jacqueline M" last="Knaust">Jacqueline M. Knaust</name><affiliation><nlm:affiliation>Department of Chemistry, Mathematics and Physics, Clarion University, 840 Wood Street, Clarion, PA 16214, USA.</nlm:affiliation></affiliation></author><author><name sortKey="Setifi, Zouaoui" sort="Setifi, Zouaoui" uniqKey="Setifi Z" first="Zouaoui" last="Setifi">Zouaoui Setifi</name><affiliation><nlm:affiliation>Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.</nlm:affiliation></affiliation></author><author><name sortKey="Touzani, Rachid" sort="Touzani, Rachid" uniqKey="Touzani R" first="Rachid" last="Touzani">Rachid Touzani</name><affiliation><nlm:affiliation>Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000, Oujda, Morocco, and, Faculté Pluridisciplinaire Nador BP 300, Selouane, 62702, Nador, Morocco.</nlm:affiliation></affiliation></author></analytic><series><title level="j">Acta crystallographica. Section E, Crystallographic communications</title><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The search for new mol-ecular materials with inter-esting magnetic properties, using the pseudohalide azide ion and di-2-pyridyl-amine (dpa, C10H9N3) as a chelating ligand, led to the synthesis and structure determination of the title compound, [Co(N3)2(dpa)2]2SO4·2H2O. The crystal structure comprises discrete [Co(dpa)2(N3)2](+) cations, sulfate anions, as well as H2O solvent mol-ecules. The Co(III) cations display a slightly distorted octa-hedral coordination sphere defined by two N atoms from azide anions and four N atoms from the pyridyl rings of two dpa ligands. In the crystal, extensive C-H⋯O, N-H⋯O, and O-H⋯O inter-actions result in supra-molecular sheets that lie parallel to the ab plane. The sheets are further linked through O-H⋯N inter-actions between the water mol-ecules of one sheet and azide anions of another sheet, forming a supra-molecular framework.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">27375867</PMID><DateCreated><Year>2016</Year><Month>7</Month><Day>4</Day></DateCreated><DateCompleted><Year>2016</Year><Month>07</Month><Day>04</Day></DateCompleted><DateRevised><Year>2016</Year><Month>7</Month><Day>8</Day></DateRevised><Article PubModel="Electronic-eCollection"><Journal><JournalIssue CitedMedium="Print"><Volume>72</Volume><Issue>Pt 4</Issue><PubDate><Year>2016</Year><Month>Apr</Month><Day>1</Day></PubDate></JournalIssue><Title>Acta crystallographica. Section E, Crystallographic communications</Title><ISOAbbreviation>Acta Crystallogr E Crystallogr Commun</ISOAbbreviation></Journal><ArticleTitle>Bis{bis-(azido-κN)bis-[bis-(pyridin-2-yl-κN)amine]cobalt(III)} sulfate dihydrate.</ArticleTitle><Pagination><MedlinePgn>470-6</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S2056989016003662</ELocationID><Abstract><AbstractText>The search for new mol-ecular materials with inter-esting magnetic properties, using the pseudohalide azide ion and di-2-pyridyl-amine (dpa, C10H9N3) as a chelating ligand, led to the synthesis and structure determination of the title compound, [Co(N3)2(dpa)2]2SO4·2H2O. The crystal structure comprises discrete [Co(dpa)2(N3)2](+) cations, sulfate anions, as well as H2O solvent mol-ecules. The Co(III) cations display a slightly distorted octa-hedral coordination sphere defined by two N atoms from azide anions and four N atoms from the pyridyl rings of two dpa ligands. In the crystal, extensive C-H⋯O, N-H⋯O, and O-H⋯O inter-actions result in supra-molecular sheets that lie parallel to the ab plane. The sheets are further linked through O-H⋯N inter-actions between the water mol-ecules of one sheet and azide anions of another sheet, forming a supra-molecular framework.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Setifi</LastName><ForeName>Fatima</ForeName><Initials>F</Initials><AffiliationInfo><Affiliation>Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Knaust</LastName><ForeName>Jacqueline M</ForeName><Initials>JM</Initials><AffiliationInfo><Affiliation>Department of Chemistry, Mathematics and Physics, Clarion University, 840 Wood Street, Clarion, PA 16214, USA.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Setifi</LastName><ForeName>Zouaoui</ForeName><Initials>Z</Initials><AffiliationInfo><Affiliation>Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Touzani</LastName><ForeName>Rachid</ForeName><Initials>R</Initials><AffiliationInfo><Affiliation>Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000, Oujda, Morocco, and, Faculté Pluridisciplinaire Nador BP 300, Selouane, 62702, Nador, Morocco.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2016</Year><Month>Mar</Month><Day>08</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Acta Crystallogr E Crystallogr Commun</MedlineTA><NlmUniqueID>101648987</NlmUniqueID></MedlineJournalInfo><OtherID Source="NLM">PMC4910331</OtherID><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">CoIII complex</Keyword><Keyword MajorTopicYN="N">azide</Keyword><Keyword MajorTopicYN="N">coordination compound</Keyword><Keyword MajorTopicYN="N">crystal structure</Keyword><Keyword MajorTopicYN="N">di-2-pyridylamine (dpa)</Keyword><Keyword MajorTopicYN="N">hydrogen bonding</Keyword><Keyword MajorTopicYN="N">supramolecular structure</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2016</Year><Month>2</Month><Day>04</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2016</Year><Month>3</Month><Day>02</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2016</Year><Month>7</Month><Day>5</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2016</Year><Month>7</Month><Day>5</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2016</Year><Month>7</Month><Day>5</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">27375867</ArticleId><ArticleId IdType="doi">10.1107/S2056989016003662</ArticleId><ArticleId IdType="pii">zl2656</ArticleId><ArticleId IdType="pmc">PMC4910331</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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