CobaltMaghrebV1, PubMed, Checkpoint, bibRecord, 000012

Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.

Identifieur interne : 000012 ( PubMed/Checkpoint ); précédent : 000011; suivant : 000013

Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.

Auteurs : Amira Derbel [Tunisie] ; Tahar Mhiri [Tunisie] ; Mohsen Graia [Tunisie]

Source :

Acta crystallographica. Section E, Crystallographic communications ; 2015.

RBID : pubmed:26594402

Abstract

In the title complex, chlorido-tetra-kis-(1H-imidazole-κN (3))cobalt(II) chloride, [CoCl(C3H4N2)4]Cl, the Co(II) cation has a distorted square-pyramidal coordination environment. It is coordinated by four N atoms of four imidazole (Im) groups in the basal plane, and by a Cl atom in the apical position. It is isostructural with [Cu(Im)4Cl]Cl [Morzyk-Ociepa et al. (2012 ▸). J. Mol. Struct. 1028, 49-56] and [Cu(Im)4Br]Br [Hossaini Sadr et al. (2004 ▸). Acta Cryst. E60, m1324-m1326]. In the crystal, the [CoCl(C3H4N2)4](+) cations and Cl(-) anions are linked via N-H⋯Cl hydrogen bonds, forming layers parallel to (010). These layers are linked via C-H⋯Cl hydrogen bonds and C-H⋯π and π-π [inter-centroid distance = 3.794 (2) Å] inter-actions, forming a three-dimensional framework. The IR spectrum shows vibrational bands typical for imidazol groups. The monoclinic unit cell of the title compound emulates an ortho-rhom-bic cell as its β angle is close to 90°. The crystal is twinned, with the refined ratio of twin components being 0.569 (1):0.431 (1).

DOI: 10.1107/S2056989015015807
PubMed: 26594402

Affiliations:

Links toward previous steps (curation, corpus...)

to stream PubMed, to step Corpus: 000009
to stream PubMed, to step Curation: 000009

Links to Exploration step

pubmed:26594402

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.</title>
<author><name sortKey="Derbel, Amira" sort="Derbel, Amira" uniqKey="Derbel A" first="Amira" last="Derbel">Amira Derbel</name>
<affiliation wicri:level="1"><nlm:affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</nlm:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax</wicri:regionArea>
<wicri:noRegion>BP W 3038 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name>
<affiliation wicri:level="1"><nlm:affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</nlm:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax</wicri:regionArea>
<wicri:noRegion>BP W 3038 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Graia, Mohsen" sort="Graia, Mohsen" uniqKey="Graia M" first="Mohsen" last="Graia">Mohsen Graia</name>
<affiliation wicri:level="4"><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisie.</nlm:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis</wicri:regionArea>
<orgName type="university">Université de Tunis - El Manar</orgName>
<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2015">2015</date>
<idno type="RBID">pubmed:26594402</idno>
<idno type="pmid">26594402</idno>
<idno type="doi">10.1107/S2056989015015807</idno>
<idno type="wicri:Area/PubMed/Corpus">000009</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000009</idno>
<idno type="wicri:Area/PubMed/Curation">000009</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000009</idno>
<idno type="wicri:Area/PubMed/Checkpoint">000009</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000009</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.</title>
<author><name sortKey="Derbel, Amira" sort="Derbel, Amira" uniqKey="Derbel A" first="Amira" last="Derbel">Amira Derbel</name>
<affiliation wicri:level="1"><nlm:affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</nlm:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax</wicri:regionArea>
<wicri:noRegion>BP W 3038 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name>
<affiliation wicri:level="1"><nlm:affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</nlm:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax</wicri:regionArea>
<wicri:noRegion>BP W 3038 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Graia, Mohsen" sort="Graia, Mohsen" uniqKey="Graia M" first="Mohsen" last="Graia">Mohsen Graia</name>
<affiliation wicri:level="4"><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisie.</nlm:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis</wicri:regionArea>
<orgName type="university">Université de Tunis - El Manar</orgName>
<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta crystallographica. Section E, Crystallographic communications</title>
<imprint><date when="2015" type="published">2015</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">In the title complex, chlorido-tetra-kis-(1H-imidazole-κN (3))cobalt(II) chloride, [CoCl(C3H4N2)4]Cl, the Co(II) cation has a distorted square-pyramidal coordination environment. It is coordinated by four N atoms of four imidazole (Im) groups in the basal plane, and by a Cl atom in the apical position. It is isostructural with [Cu(Im)4Cl]Cl [Morzyk-Ociepa et al. (2012 ▸). J. Mol. Struct. 1028, 49-56] and [Cu(Im)4Br]Br [Hossaini Sadr et al. (2004 ▸). Acta Cryst. E60, m1324-m1326]. In the crystal, the [CoCl(C3H4N2)4](+) cations and Cl(-) anions are linked via N-H⋯Cl hydrogen bonds, forming layers parallel to (010). These layers are linked via C-H⋯Cl hydrogen bonds and C-H⋯π and π-π [inter-centroid distance = 3.794 (2) Å] inter-actions, forming a three-dimensional framework. The IR spectrum shows vibrational bands typical for imidazol groups. The monoclinic unit cell of the title compound emulates an ortho-rhom-bic cell as its β angle is close to 90°. The crystal is twinned, with the refined ratio of twin components being 0.569 (1):0.431 (1).</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">26594402</PMID>
<DateCreated><Year>2015</Year>
<Month>11</Month>
<Day>23</Day>
</DateCreated>
<DateCompleted><Year>2015</Year>
<Month>11</Month>
<Day>23</Day>
</DateCompleted>
<DateRevised><Year>2015</Year>
<Month>12</Month>
<Day>14</Day>
</DateRevised>
<Article PubModel="Electronic-eCollection"><Journal><JournalIssue CitedMedium="Print"><Volume>71</Volume>
<Issue>Pt 10</Issue>
<PubDate><Year>2015</Year>
<Month>Oct</Month>
<Day>1</Day>
</PubDate>
</JournalIssue>
<Title>Acta crystallographica. Section E, Crystallographic communications</Title>
<ISOAbbreviation>Acta Crystallogr E Crystallogr Commun</ISOAbbreviation>
</Journal>
<ArticleTitle>Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.</ArticleTitle>
<Pagination><MedlinePgn>1185-9</MedlinePgn>
</Pagination>
<ELocationID EIdType="doi" ValidYN="Y">10.1107/S2056989015015807</ELocationID>
<Abstract><AbstractText>In the title complex, chlorido-tetra-kis-(1H-imidazole-κN (3))cobalt(II) chloride, [CoCl(C3H4N2)4]Cl, the Co(II) cation has a distorted square-pyramidal coordination environment. It is coordinated by four N atoms of four imidazole (Im) groups in the basal plane, and by a Cl atom in the apical position. It is isostructural with [Cu(Im)4Cl]Cl [Morzyk-Ociepa et al. (2012 ▸). J. Mol. Struct. 1028, 49-56] and [Cu(Im)4Br]Br [Hossaini Sadr et al. (2004 ▸). Acta Cryst. E60, m1324-m1326]. In the crystal, the [CoCl(C3H4N2)4](+) cations and Cl(-) anions are linked via N-H⋯Cl hydrogen bonds, forming layers parallel to (010). These layers are linked via C-H⋯Cl hydrogen bonds and C-H⋯π and π-π [inter-centroid distance = 3.794 (2) Å] inter-actions, forming a three-dimensional framework. The IR spectrum shows vibrational bands typical for imidazol groups. The monoclinic unit cell of the title compound emulates an ortho-rhom-bic cell as its β angle is close to 90°. The crystal is twinned, with the refined ratio of twin components being 0.569 (1):0.431 (1).</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Derbel</LastName>
<ForeName>Amira</ForeName>
<Initials>A</Initials>
<AffiliationInfo><Affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Mhiri</LastName>
<ForeName>Tahar</ForeName>
<Initials>T</Initials>
<AffiliationInfo><Affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Graia</LastName>
<ForeName>Mohsen</ForeName>
<Initials>M</Initials>
<AffiliationInfo><Affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisie.</Affiliation>
</AffiliationInfo>
</Author>
</AuthorList>
<Language>ENG</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
<ArticleDate DateType="Electronic"><Year>2015</Year>
<Month>Sep</Month>
<Day>17</Day>
</ArticleDate>
</Article>
<MedlineJournalInfo><Country>England</Country>
<MedlineTA>Acta Crystallogr E Crystallogr Commun</MedlineTA>
<NlmUniqueID>101648987</NlmUniqueID>
</MedlineJournalInfo>
<OtherID Source="NLM">PMC4647365</OtherID>
<KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">cobalt complex</Keyword>
<Keyword MajorTopicYN="N">crystal structure</Keyword>
<Keyword MajorTopicYN="N">framework</Keyword>
<Keyword MajorTopicYN="N">hydrogen bonding</Keyword>
<Keyword MajorTopicYN="N">imidazole</Keyword>
</KeywordList>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="received"><Year>2015</Year>
<Month>8</Month>
<Day>06</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="accepted"><Year>2015</Year>
<Month>8</Month>
<Day>23</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2015</Year>
<Month>11</Month>
<Day>24</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="pubmed"><Year>2015</Year>
<Month>11</Month>
<Day>26</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2015</Year>
<Month>11</Month>
<Day>26</Day>
<Hour>6</Hour>
<Minute>1</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>epublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">26594402</ArticleId>
<ArticleId IdType="doi">10.1107/S2056989015015807</ArticleId>
<ArticleId IdType="pii">su5189</ArticleId>
<ArticleId IdType="pmc">PMC4647365</ArticleId>
</ArticleIdList>
</PubmedData>
</pubmed>
<affiliations><list><country><li>Tunisie</li>
</country>
<region><li>Gouvernorat de Tunis</li>
</region>
<settlement><li>Tunis</li>
</settlement>
<orgName><li>Université de Tunis - El Manar</li>
</orgName>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Derbel, Amira" sort="Derbel, Amira" uniqKey="Derbel A" first="Amira" last="Derbel">Amira Derbel</name>
</noRegion>
<name sortKey="Graia, Mohsen" sort="Graia, Mohsen" uniqKey="Graia M" first="Mohsen" last="Graia">Mohsen Graia</name>
<name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/PubMed/Checkpoint

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000012 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/PubMed/Checkpoint/biblio.hfd -nk 000012 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    PubMed
   |étape=   Checkpoint
   |type=    RBID
   |clé=     pubmed:26594402
   |texte=   Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Checkpoint/RBID.i   -Sk "pubmed:26594402" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Checkpoint/biblio.hfd   \
       | NlmPubMed2Wicri -a CobaltMaghrebV1

This area was generated with Dilib version V0.6.32.
Data generation: Tue Nov 14 12:56:51 2017. Site generation: Mon Feb 12 07:59:49 2024

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.

Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki