Dicobalt copper bis[orthophosphate(V)] monohydrate, Co2.39Cu0.61(PO4)2·H2O
Identifieur interne : 000387 ( Pmc/Curation ); précédent : 000386; suivant : 000388Dicobalt copper bis[orthophosphate(V)] monohydrate, Co2.39Cu0.61(PO4)2·H2O
Auteurs : Abderrazzak Assani [Maroc] ; Mohamed Saadi [Maroc] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2010.
Abstract
In an attempt to hydrothermally synthesize a phase with composition Co2Cu(PO4)2·H2O, we obtained the title compound, Co2.39Cu0.61(PO4)2·H2O instead. Chemical analysis confirmed the presence of copper in the crystal. The crystal structure of the title compound can be described as a three- dimensional network constructed from the stacking of two types of layers extending parallel to (010). These layers are made up from more or less deformed polyhedra: CoO6 octahedra, (Cu/Co)O5 square pyramids and PO4 tetrahedra. The first layer is formed by pairs of edge-sharing (Cu/Co)O5 square pyramids linked
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DOI: 10.1107/S1600536810015382
PubMed: 21578990
PubMed Central: 2979060
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Dicobalt copper bis[orthophosphate(V)] monohydrate, Co<sub>2.39</sub>Cu<sub>0.61</sub>(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O</title><author><name sortKey="Assani, Abderrazzak" sort="Assani, Abderrazzak" uniqKey="Assani A" first="Abderrazzak" last="Assani">Abderrazzak Assani</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">21578990</idno><idno type="pmc">2979060</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979060</idno><idno type="RBID">PMC:2979060</idno><idno type="doi">10.1107/S1600536810015382</idno><date when="2010">2010</date><idno type="wicri:Area/Pmc/Corpus">000388</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000388</idno><idno type="wicri:Area/Pmc/Curation">000387</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000387</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Dicobalt copper bis[orthophosphate(V)] monohydrate, Co<sub>2.39</sub>Cu<sub>0.61</sub>(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O</title><author><name sortKey="Assani, Abderrazzak" sort="Assani, Abderrazzak" uniqKey="Assani A" first="Abderrazzak" last="Assani">Abderrazzak Assani</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2010">2010</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>In an attempt to hydrothermally synthesize a phase with composition Co<sub>2</sub>Cu(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O, we obtained the title compound, Co<sub>2.39</sub>Cu<sub>0.61</sub>(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O instead. Chemical analysis confirmed the presence of copper in the crystal. The crystal structure of the title compound can be described as a three- dimensional network constructed from the stacking of two types of layers extending parallel to (010). These layers are made up from more or less deformed polyhedra: CoO<sub>6</sub> octahedra, (Cu/Co)O<sub>5</sub> square pyramids and PO<sub>4</sub> tetrahedra. The first layer is formed by pairs of edge-sharing (Cu/Co)O<sub>5</sub> square pyramids linked <italic>via</italic> a common edge of each end of the (Cu/Co)<sub>2</sub>O<sub>8</sub> dimer to PO<sub>4</sub> tetrahedra. The second layer is undulating and is built up from edge-sharing CoO<sub>6</sub> octahedra. The linkage between the two layers is accomplished by PO<sub>4</sub> tetrahedra. The presence of water molecules in the CoO<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub> octahedron also contributes to the cohesion of the layers through O—H⋯O hydrogen bonding.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id><journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title></journal-title-group><issn pub-type="epub">1600-5368</issn><publisher><publisher-name>International Union of Crystallography</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">21578990</article-id><article-id pub-id-type="pmc">2979060</article-id><article-id pub-id-type="publisher-id">wm2323</article-id><article-id pub-id-type="doi">10.1107/S1600536810015382</article-id><article-id pub-id-type="coden">ACSEBH</article-id><article-id pub-id-type="pii">S1600536810015382</article-id><article-categories><subj-group subj-group-type="heading"><subject>Inorganic Papers</subject></subj-group></article-categories><title-group><article-title>Dicobalt copper bis[orthophosphate(V)] monohydrate, Co<sub>2.39</sub>Cu<sub>0.61</sub>(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O</article-title><alt-title><italic>Co<sub>2.39</sub>Cu<sub>0.61</sub>(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O</italic></alt-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Assani</surname><given-names>Abderrazzak</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Saadi</surname><given-names>Mohamed</given-names></name><xref ref-type="aff" rid="a">a</xref><xref ref-type="corresp" rid="cor">*</xref></contrib><contrib contrib-type="author"><name><surname>El Ammari</surname><given-names>Lahcen</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><aff id="a"><label>a</label>Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></aff></contrib-group><author-notes><corresp id="cor">Correspondence e-mail: <email>mohamedsaadi82@gmail.com</email></corresp></author-notes><pub-date pub-type="collection"><day>01</day><month>5</month><year>2010</year></pub-date><pub-date pub-type="epub"><day>30</day><month>4</month><year>2010</year></pub-date><pub-date pub-type="pmc-release"><day>30</day><month>4</month><year>2010</year></pub-date><pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
<volume>66</volume><issue>Pt 5</issue><issue-id pub-id-type="publisher-id">e100500</issue-id><fpage>i44</fpage><lpage>i44</lpage><history><date date-type="received"><day>06</day><month>4</month><year>2010</year></date><date date-type="accepted"><day>26</day><month>4</month><year>2010</year></date></history><permissions><copyright-statement>© Assani et al. 2010</copyright-statement><copyright-year>2010</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p></license></permissions><self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536810015382">A full version of this article is available from Crystallography Journals Online.</self-uri><abstract><p>In an attempt to hydrothermally synthesize a phase with composition Co<sub>2</sub>Cu(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O, we obtained the title compound, Co<sub>2.39</sub>Cu<sub>0.61</sub>(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O instead. Chemical analysis confirmed the presence of copper in the crystal. The crystal structure of the title compound can be described as a three- dimensional network constructed from the stacking of two types of layers extending parallel to (010). These layers are made up from more or less deformed polyhedra: CoO<sub>6</sub> octahedra, (Cu/Co)O<sub>5</sub> square pyramids and PO<sub>4</sub> tetrahedra. The first layer is formed by pairs of edge-sharing (Cu/Co)O<sub>5</sub> square pyramids linked <italic>via</italic> a common edge of each end of the (Cu/Co)<sub>2</sub>O<sub>8</sub> dimer to PO<sub>4</sub> tetrahedra. The second layer is undulating and is built up from edge-sharing CoO<sub>6</sub> octahedra. The linkage between the two layers is accomplished by PO<sub>4</sub> tetrahedra. The presence of water molecules in the CoO<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub> octahedron also contributes to the cohesion of the layers through O—H⋯O hydrogen bonding.</p></abstract></article-meta></front><floats-group><table-wrap id="table1" position="float"><label>Table 1</label><caption><title>Hydrogen-bond geometry (Å, °)</title></caption><table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H</th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th></tr></thead><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O9—H9<italic>A</italic>⋯O1</td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.83</td><td style="" rowspan="1" colspan="1" align="left" valign="top">1.97</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.768 (2)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">159</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O9—H9<italic>B</italic>⋯O5<sup>i</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.92</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.27</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.942 (2)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">130</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O9—H9<italic>B</italic>⋯O4<sup>ii</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.92</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.30</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.905 (2)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">123</td></tr></tbody></table><table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-66-00i44-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (ii) <inline-formula><inline-graphic xlink:href="e-66-00i44-efi3.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>.</p></table-wrap-foot></table-wrap></floats-group></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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