Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
Identifieur interne : 000355 ( Pmc/Curation ); précédent : 000354; suivant : 000356Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
Auteurs : Abderrazzak Assani [Maroc] ; Mohamed Saadi [Maroc] ; Mohammed Zriouil [Maroc] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.
Abstract
The title compound, Pb2Mn3(HPO4)2(PO4)2, was synthesized by a hydrothermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO4 tetrahedra and two types of MnO6 octahedra, one almost ideal and the other very distorted with one very long Mn—O bond [2.610 (4) Å compared an average of 2.161 Å for the other bonds]. The centrosymetric octahedron is linked to two distorted MnO6 octahedra by an edge common, forming infinite zigzag Mn3O14 chains running along the
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DOI: 10.1107/S1600536812033259
PubMed: 22904702
PubMed Central: 3414095
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xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Zriouil, Mohammed" sort="Zriouil, Mohammed" uniqKey="Zriouil M" first="Mohammed" last="Zriouil">Mohammed Zriouil</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country 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last="Assani">Abderrazzak Assani</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Zriouil, Mohammed" sort="Zriouil, Mohammed" uniqKey="Zriouil M" first="Mohammed" last="Zriouil">Mohammed Zriouil</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2012">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>The title compound, Pb<sub>2</sub>Mn<sub>3</sub>(HPO<sub>4</sub>)<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>, was synthesized by a hydrothermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO<sub>4</sub> tetrahedra and two types of MnO<sub>6</sub> octahedra, one almost ideal and the other very distorted with one very long Mn—O bond [2.610 (4) Å compared an average of 2.161 Å for the other bonds]. The centrosymetric octahedron is linked to two distorted MnO<sub>6</sub> octahedra by an edge common, forming infinite zigzag Mn<sub>3</sub>O<sub>14</sub> chains running along the <italic>b</italic> axis. Adjacent chains are linked by PO<sub>4</sub> and PO<sub>3</sub>(OH) tetrahedra through vertices or by edge sharing, forming sheets perpendicular to [100]. The Pb<sup>2+</sup> cations are sandwiched between the layers and ensure the cohesion of the crystal structure. O—H⋯O hydrogen bonding between the layers is also observed.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id><journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title></journal-title-group><issn pub-type="epub">1600-5368</issn><publisher><publisher-name>International Union of Crystallography</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">22904702</article-id><article-id pub-id-type="pmc">3414095</article-id><article-id pub-id-type="publisher-id">hp2043</article-id><article-id pub-id-type="doi">10.1107/S1600536812033259</article-id><article-id pub-id-type="coden">ACSEBH</article-id><article-id pub-id-type="pii">S1600536812033259</article-id><article-categories><subj-group subj-group-type="heading"><subject>Inorganic Papers</subject></subj-group></article-categories><title-group><article-title>Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)</article-title><alt-title><italic>Pb<sub>2</sub>Mn<sub>3</sub>(HPO<sub>4</sub>)<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub></italic></alt-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Assani</surname><given-names>Abderrazzak</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Saadi</surname><given-names>Mohamed</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Zriouil</surname><given-names>Mohammed</given-names></name><xref ref-type="aff" rid="a">a</xref><xref ref-type="corresp" rid="cor">*</xref></contrib><contrib contrib-type="author"><name><surname>El Ammari</surname><given-names>Lahcen</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><aff id="a"><label>a</label>Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></aff></contrib-group><author-notes><corresp id="cor">Correspondence e-mail: <email>m_zriouil@yahoo.fr</email></corresp></author-notes><pub-date pub-type="collection"><day>01</day><month>8</month><year>2012</year></pub-date><pub-date pub-type="epub"><day>28</day><month>7</month><year>2012</year></pub-date><pub-date pub-type="pmc-release"><day>28</day><month>7</month><year>2012</year></pub-date><pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
<volume>68</volume><issue>Pt 8</issue><issue-id pub-id-type="publisher-id">e120800</issue-id><fpage>i66</fpage><lpage>i66</lpage><history><date date-type="received"><day>19</day><month>6</month><year>2012</year></date><date date-type="accepted"><day>23</day><month>7</month><year>2012</year></date></history><permissions><copyright-statement>© Assani et al. 2012</copyright-statement><copyright-year>2012</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p></license></permissions><self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536812033259">A full version of this article is available from Crystallography Journals Online.</self-uri><abstract><p>The title compound, Pb<sub>2</sub>Mn<sub>3</sub>(HPO<sub>4</sub>)<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>, was synthesized by a hydrothermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO<sub>4</sub> tetrahedra and two types of MnO<sub>6</sub> octahedra, one almost ideal and the other very distorted with one very long Mn—O bond [2.610 (4) Å compared an average of 2.161 Å for the other bonds]. The centrosymetric octahedron is linked to two distorted MnO<sub>6</sub> octahedra by an edge common, forming infinite zigzag Mn<sub>3</sub>O<sub>14</sub> chains running along the <italic>b</italic> axis. Adjacent chains are linked by PO<sub>4</sub> and PO<sub>3</sub>(OH) tetrahedra through vertices or by edge sharing, forming sheets perpendicular to [100]. The Pb<sup>2+</sup> cations are sandwiched between the layers and ensure the cohesion of the crystal structure. O—H⋯O hydrogen bonding between the layers is also observed.</p></abstract></article-meta></front><floats-group><table-wrap id="table1" position="float"><label>Table 1</label><caption><title>Hydrogen-bond geometry (Å, °)</title></caption><table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H</th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th></tr></thead><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O8—H8⋯O4</td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">1.60</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.437 (5)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">164</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O8—H8⋯O1</td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.76</td><td style="" rowspan="1" colspan="1" align="left" valign="top">3.393 (5)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">132</td></tr></tbody></table></table-wrap></floats-group></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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