Dicobalt(II) lead(II) hydrogenphosphate(V) phosphate(V) hydroxide monohydrate
Identifieur interne : 000352 ( Pmc/Curation ); précédent : 000351; suivant : 000353Dicobalt(II) lead(II) hydrogenphosphate(V) phosphate(V) hydroxide monohydrate
Auteurs : Abderrazzak Assani [Maroc] ; Mohamed Saadi [Maroc] ; Mohammed Zriouil [Maroc] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.
Abstract
The title compound, Co2Pb(HPO4)(PO4)OH·H2O, which was synthesized under hydrothermal conditions, crystallizes in a new structure type. Except for two O atoms in general positions and two Co atoms on centres of symmetry, all other atoms in the asymmetric unit (1 Pb, 2 Co, 2 P, 8 O and 4 H) are located on mirror planes. The structure is built up from two infinite linear chains,
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DOI: 10.1107/S1600536812014870
PubMed: 22590050
PubMed Central: 3344284
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Dicobalt(II) lead(II) hydrogenphosphate(V) phosphate(V) hydroxide monohydrate</title><author><name sortKey="Assani, Abderrazzak" sort="Assani, Abderrazzak" uniqKey="Assani A" first="Abderrazzak" last="Assani">Abderrazzak Assani</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Zriouil, Mohammed" sort="Zriouil, Mohammed" uniqKey="Zriouil M" first="Mohammed" last="Zriouil">Mohammed Zriouil</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">22590050</idno><idno type="pmc">3344284</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344284</idno><idno type="RBID">PMC:3344284</idno><idno type="doi">10.1107/S1600536812014870</idno><date when="2012">2012</date><idno type="wicri:Area/Pmc/Corpus">000353</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000353</idno><idno type="wicri:Area/Pmc/Curation">000352</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000352</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Dicobalt(II) lead(II) hydrogenphosphate(V) phosphate(V) hydroxide monohydrate</title><author><name sortKey="Assani, Abderrazzak" sort="Assani, Abderrazzak" uniqKey="Assani A" first="Abderrazzak" last="Assani">Abderrazzak Assani</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Zriouil, Mohammed" sort="Zriouil, Mohammed" uniqKey="Zriouil M" first="Mohammed" last="Zriouil">Mohammed Zriouil</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2012">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>The title compound, Co<sub>2</sub>Pb(HPO<sub>4</sub>)(PO<sub>4</sub>)OH·H<sub>2</sub>O, which was synthesized under hydrothermal conditions, crystallizes in a new structure type. Except for two O atoms in general positions and two Co atoms on centres of symmetry, all other atoms in the asymmetric unit (1 Pb, 2 Co, 2 P, 8 O and 4 H) are located on mirror planes. The structure is built up from two infinite linear chains, <italic>viz.</italic><sup>1</sup><sub>∞</sub>[CoO<sub>2/1</sub>(H<sub>2</sub>O)<sub>2/2</sub>O<sub>2/2</sub>] and <sup>1</sup><sub>∞</sub>[CoO<sub>2/1</sub>(OH)<sub>2/2</sub>O<sub>2/2</sub>], of edge-sharing CoO<sub>6</sub> octahedra running along [010]. Adjacent chains are linked to each other through PO<sub>4</sub> and PO<sub>3</sub>(OH) tetrahedra, leading to the formation of layers parallel to (100). The three-dimensional framework is formed by stacking along [100] of adjacent layers that are held together by distorted PbO<sub>8</sub> polyhedra. Hydrogen bonds of the type O—H⋯O involving the water molecule are very strong, while those O atoms involving the OH groups form weak bifurcated and trifurcated hydrogen bonds.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id><journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title></journal-title-group><issn pub-type="epub">1600-5368</issn><publisher><publisher-name>International Union of Crystallography</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">22590050</article-id><article-id pub-id-type="pmc">3344284</article-id><article-id pub-id-type="publisher-id">wm2609</article-id><article-id pub-id-type="doi">10.1107/S1600536812014870</article-id><article-id pub-id-type="coden">ACSEBH</article-id><article-id pub-id-type="pii">S1600536812014870</article-id><article-categories><subj-group subj-group-type="heading"><subject>Inorganic Papers</subject></subj-group></article-categories><title-group><article-title>Dicobalt(II) lead(II) hydrogenphosphate(V) phosphate(V) hydroxide monohydrate</article-title><alt-title><italic>Co<sub>2</sub>Pb(HPO<sub>4</sub>)(PO<sub>4</sub>)OH·H<sub>2</sub>O</italic></alt-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Assani</surname><given-names>Abderrazzak</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Saadi</surname><given-names>Mohamed</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Zriouil</surname><given-names>Mohammed</given-names></name><xref ref-type="aff" rid="a">a</xref><xref ref-type="corresp" rid="cor">*</xref></contrib><contrib contrib-type="author"><name><surname>El Ammari</surname><given-names>Lahcen</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><aff id="a"><label>a</label>Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country></aff></contrib-group><author-notes><corresp id="cor">Correspondence e-mail: <email>m_zriouil@yahoo.fr</email></corresp></author-notes><pub-date pub-type="collection"><day>01</day><month>5</month><year>2012</year></pub-date><pub-date pub-type="epub"><day>18</day><month>4</month><year>2012</year></pub-date><pub-date pub-type="pmc-release"><day>18</day><month>4</month><year>2012</year></pub-date><pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
<volume>68</volume><issue>Pt 5</issue><issue-id pub-id-type="publisher-id">e120500</issue-id><fpage>i30</fpage><lpage>i30</lpage><history><date date-type="received"><day>21</day><month>3</month><year>2012</year></date><date date-type="accepted"><day>04</day><month>4</month><year>2012</year></date></history><permissions><copyright-statement>© Assani et al. 2012</copyright-statement><copyright-year>2012</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p></license></permissions><self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536812014870">A full version of this article is available from Crystallography Journals Online.</self-uri><abstract><p>The title compound, Co<sub>2</sub>Pb(HPO<sub>4</sub>)(PO<sub>4</sub>)OH·H<sub>2</sub>O, which was synthesized under hydrothermal conditions, crystallizes in a new structure type. Except for two O atoms in general positions and two Co atoms on centres of symmetry, all other atoms in the asymmetric unit (1 Pb, 2 Co, 2 P, 8 O and 4 H) are located on mirror planes. The structure is built up from two infinite linear chains, <italic>viz.</italic><sup>1</sup><sub>∞</sub>[CoO<sub>2/1</sub>(H<sub>2</sub>O)<sub>2/2</sub>O<sub>2/2</sub>] and <sup>1</sup><sub>∞</sub>[CoO<sub>2/1</sub>(OH)<sub>2/2</sub>O<sub>2/2</sub>], of edge-sharing CoO<sub>6</sub> octahedra running along [010]. Adjacent chains are linked to each other through PO<sub>4</sub> and PO<sub>3</sub>(OH) tetrahedra, leading to the formation of layers parallel to (100). The three-dimensional framework is formed by stacking along [100] of adjacent layers that are held together by distorted PbO<sub>8</sub> polyhedra. Hydrogen bonds of the type O—H⋯O involving the water molecule are very strong, while those O atoms involving the OH groups form weak bifurcated and trifurcated hydrogen bonds.</p></abstract></article-meta></front><floats-group><table-wrap id="table1" position="float"><label>Table 1</label><caption><title>Hydrogen-bond geometry (Å, °)</title></caption><table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H</th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th></tr></thead><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O2—H2⋯O6<sup>i</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.28</td><td style="" rowspan="1" colspan="1" align="left" valign="top">3.027 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">145</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O2—H2⋯O6<sup>ii</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.28</td><td style="" rowspan="1" colspan="1" align="left" valign="top">3.027 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">145</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O7—H7⋯O2<sup>iii</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.20</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.915 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">140</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O7—H7⋯O3</td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.53</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.986 (2)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">114</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O7—H7⋯O3<sup>iv</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.53</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.986 (2)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">114</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O8—H8<italic>A</italic>⋯O4<sup>v</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">1.79</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.649 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">177</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O8—H8<italic>B</italic>⋯O7</td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">1.65</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.489 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">165</td></tr></tbody></table><table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-68-00i30-efi8.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (ii) <inline-formula><inline-graphic xlink:href="e-68-00i30-efi9.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (iii) <inline-formula><inline-graphic xlink:href="e-68-00i30-efi10.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (iv) <inline-formula><inline-graphic xlink:href="e-68-00i30-efi11.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (v) <inline-formula><inline-graphic xlink:href="e-68-00i30-efi12.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>.</p></table-wrap-foot></table-wrap></floats-group></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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