trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)
Identifieur interne : 000298 ( Pmc/Checkpoint ); précédent : 000297; suivant : 000299trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)
Auteurs : Fouad Bentiss [Maroc] ; Frédéric Capet [France] ; Michel Lagrenée [France] ; Mohamed Saadi [Maroc] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.
Abstract
The bidentate 1,3,4-thiadiazole ligand substituted by two 2-pyridyl rings (denoted
Url:
DOI: 10.1107/S1600536811020125
PubMed: 21836842
PubMed Central: 3151744
Affiliations:
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-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)</title>
<author><name sortKey="Bentiss, Fouad" sort="Bentiss, Fouad" uniqKey="Bentiss F" first="Fouad" last="Bentiss">Fouad Bentiss</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie de Coordination et d’Analytique (LCCA), Faculté des Sciences, Université Chouaib Doukkali, BP 20, M-24000 El Jadida,<country>Morocco</country>
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<country xml:lang="fr">Maroc</country>
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<author><name sortKey="Capet, Frederic" sort="Capet, Frederic" uniqKey="Capet F" first="Frédéric" last="Capet">Frédéric Capet</name>
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</nlm:aff>
<country xml:lang="fr">France</country>
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<affiliation wicri:level="1"><nlm:aff id="c">Université Lille Nord de France, F-59000 Lille,<country>France</country>
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<author><name sortKey="Lagrenee, Michel" sort="Lagrenee, Michel" uniqKey="Lagrenee M" first="Michel" last="Lagrenée">Michel Lagrenée</name>
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<country xml:lang="fr">Maroc</country>
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<author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main"><italic>trans</italic>
-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)</title>
<author><name sortKey="Bentiss, Fouad" sort="Bentiss, Fouad" uniqKey="Bentiss F" first="Fouad" last="Bentiss">Fouad Bentiss</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie de Coordination et d’Analytique (LCCA), Faculté des Sciences, Université Chouaib Doukkali, BP 20, M-24000 El Jadida,<country>Morocco</country>
</nlm:aff>
<country xml:lang="fr">Maroc</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Capet, Frederic" sort="Capet, Frederic" uniqKey="Capet F" first="Frédéric" last="Capet">Frédéric Capet</name>
<affiliation wicri:level="1"><nlm:aff id="b">Unité de Catalyse et de Chimie du Solide (UCCS), CNRS UMR 8181, ENSCL, BP 90108, F-59652 Villeneuve d’Ascq Cedex,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="c">Université Lille Nord de France, F-59000 Lille,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Lagrenee, Michel" sort="Lagrenee, Michel" uniqKey="Lagrenee M" first="Michel" last="Lagrenée">Michel Lagrenée</name>
<affiliation wicri:level="1"><nlm:aff id="b">Unité de Catalyse et de Chimie du Solide (UCCS), CNRS UMR 8181, ENSCL, BP 90108, F-59652 Villeneuve d’Ascq Cedex,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="c">Université Lille Nord de France, F-59000 Lille,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name>
<affiliation wicri:level="1"><nlm:aff id="d">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
</nlm:aff>
<country xml:lang="fr">Maroc</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name>
<affiliation wicri:level="1"><nlm:aff id="d">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
</nlm:aff>
<country xml:lang="fr">Maroc</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2011">2011</date>
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<front><div type="abstract" xml:lang="en"><p>The bidentate 1,3,4-thiadiazole ligand substituted by two 2-pyridyl rings (denoted <italic>L</italic>
) has been found to produce the new monomeric title complex, [Co(C<sub>12</sub>
H<sub>8</sub>
N<sub>4</sub>
S)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
](BF<sub>4</sub>
)<sub>2</sub>
. The thiadiazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]. The mean plane defined by these heterocyclic moieties makes a dihedral angle of 18.72 (6)° with the non-coordinated pyridyl ring. The Co<sup>2+</sup>
cation, located at a crystallographic center of symmetry, is bonded to two ligands and two water molecules in a <italic>trans</italic>
configuration in an octahedral environment. The tetrafluoridoborate ions can be regarded as free anions in the crystal lattice. Nevertheless, they are involved in an infinite two-dimensional network along the [010] and [101] directions of O—H⋯F hydrogen bonds.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
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<biblStruct></biblStruct>
<biblStruct></biblStruct>
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</listBibl>
</div1>
</back>
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<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">21836842</article-id>
<article-id pub-id-type="pmc">3151744</article-id>
<article-id pub-id-type="publisher-id">im2290</article-id>
<article-id pub-id-type="doi">10.1107/S1600536811020125</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536811020125</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title><italic>trans</italic>
-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)</article-title>
<alt-title><italic>[Co(C<sub>12</sub>
H<sub>8</sub>
N<sub>4</sub>
S)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
](BF<sub>4</sub>
)<sub>2</sub>
</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Bentiss</surname>
<given-names>Fouad</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Capet</surname>
<given-names>Frédéric</given-names>
</name>
<xref ref-type="aff" rid="b">b</xref>
<xref ref-type="aff" rid="c">c</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Lagrenée</surname>
<given-names>Michel</given-names>
</name>
<xref ref-type="aff" rid="b">b</xref>
<xref ref-type="aff" rid="c">c</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Saadi</surname>
<given-names>Mohamed</given-names>
</name>
<xref ref-type="aff" rid="d">d</xref>
</contrib>
<contrib contrib-type="author"><name><surname>El Ammari</surname>
<given-names>Lahcen</given-names>
</name>
<xref ref-type="aff" rid="d">d</xref>
</contrib>
<aff id="a"><label>a</label>
Laboratoire de Chimie de Coordination et d’Analytique (LCCA), Faculté des Sciences, Université Chouaib Doukkali, BP 20, M-24000 El Jadida,<country>Morocco</country>
</aff>
<aff id="b"><label>b</label>
Unité de Catalyse et de Chimie du Solide (UCCS), CNRS UMR 8181, ENSCL, BP 90108, F-59652 Villeneuve d’Ascq Cedex,<country>France</country>
</aff>
<aff id="c"><label>c</label>
Université Lille Nord de France, F-59000 Lille,<country>France</country>
</aff>
<aff id="d"><label>d</label>
Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>f_bentiss@yahoo.fr</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>7</month>
<year>2011</year>
</pub-date>
<pub-date pub-type="epub"><day>04</day>
<month>6</month>
<year>2011</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>04</day>
<month>6</month>
<year>2011</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
. </pmc-comment>
<volume>67</volume>
<issue>Pt 7</issue>
<issue-id pub-id-type="publisher-id">e110700</issue-id>
<fpage>m834</fpage>
<lpage>m835</lpage>
<history><date date-type="received"><day>18</day>
<month>5</month>
<year>2011</year>
</date>
<date date-type="accepted"><day>26</day>
<month>5</month>
<year>2011</year>
</date>
</history>
<permissions><copyright-statement>© Bentiss et al. 2011</copyright-statement>
<copyright-year>2011</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536811020125">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>The bidentate 1,3,4-thiadiazole ligand substituted by two 2-pyridyl rings (denoted <italic>L</italic>
) has been found to produce the new monomeric title complex, [Co(C<sub>12</sub>
H<sub>8</sub>
N<sub>4</sub>
S)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
](BF<sub>4</sub>
)<sub>2</sub>
. The thiadiazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]. The mean plane defined by these heterocyclic moieties makes a dihedral angle of 18.72 (6)° with the non-coordinated pyridyl ring. The Co<sup>2+</sup>
cation, located at a crystallographic center of symmetry, is bonded to two ligands and two water molecules in a <italic>trans</italic>
configuration in an octahedral environment. The tetrafluoridoborate ions can be regarded as free anions in the crystal lattice. Nevertheless, they are involved in an infinite two-dimensional network along the [010] and [101] directions of O—H⋯F hydrogen bonds.</p>
</abstract>
</article-meta>
</front>
<floats-group><table-wrap id="table1" position="float"><label>Table 1</label>
<caption><title>Hydrogen-bond geometry (Å, °)</title>
</caption>
<table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
</tr>
</thead>
<tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O1—H1<italic>W</italic>
⋯F1<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.88</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.7014 (16)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">161</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O1—H2<italic>W</italic>
⋯F4</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.94</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.7927 (16)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">172</td>
</tr>
</tbody>
</table>
<table-wrap-foot><p>Symmetry code: (i) <inline-formula><inline-graphic xlink:href="e-67-0m834-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
.</p>
</table-wrap-foot>
</table-wrap>
</floats-group>
</pmc>
<affiliations><list><country><li>France</li>
<li>Maroc</li>
</country>
</list>
<tree><country name="Maroc"><noRegion><name sortKey="Bentiss, Fouad" sort="Bentiss, Fouad" uniqKey="Bentiss F" first="Fouad" last="Bentiss">Fouad Bentiss</name>
</noRegion>
<name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name>
<name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name>
</country>
<country name="France"><noRegion><name sortKey="Capet, Frederic" sort="Capet, Frederic" uniqKey="Capet F" first="Frédéric" last="Capet">Frédéric Capet</name>
</noRegion>
<name sortKey="Capet, Frederic" sort="Capet, Frederic" uniqKey="Capet F" first="Frédéric" last="Capet">Frédéric Capet</name>
<name sortKey="Lagrenee, Michel" sort="Lagrenee, Michel" uniqKey="Lagrenee M" first="Michel" last="Lagrenée">Michel Lagrenée</name>
<name sortKey="Lagrenee, Michel" sort="Lagrenee, Michel" uniqKey="Lagrenee M" first="Michel" last="Lagrenée">Michel Lagrenée</name>
</country>
</tree>
</affiliations>
</record>
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