catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]
Identifieur interne : 000221 ( Pmc/Checkpoint ); précédent : 000220; suivant : 000222catena-Poly[[bis[4-(dimethylamino)pyridine-κN1]cobalt(II)]-di-μ-azido-κ4N1:N3]
Auteurs : Fatiha Guenifa [Algérie] ; Ouahida Zeghouan [Algérie] ; Nasreddine Hadjadj [Algérie] ; Lamia Bendjeddou [Algérie] ; Hocine Merazig [Algérie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.
Abstract
The title layered polymer, [Co(N3)2(C7H10N2)2]
Url:
DOI: 10.1107/S1600536813005205
PubMed: 23476514
PubMed Central: 3588528
Affiliations:
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en"><italic>catena</italic>-Poly[[bis[4-(dimethylamino)pyridine-κ<italic>N</italic><sup>1</sup>]cobalt(II)]-di-μ-azido-κ<sup>4</sup><italic>N</italic><sup>1</sup>:<italic>N</italic><sup>3</sup>]</title><author><name sortKey="Guenifa, Fatiha" sort="Guenifa, Fatiha" uniqKey="Guenifa F" first="Fatiha" last="Guenifa">Fatiha Guenifa</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Zeghouan, Ouahida" sort="Zeghouan, Ouahida" uniqKey="Zeghouan O" first="Ouahida" last="Zeghouan">Ouahida Zeghouan</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Hadjadj, Nasreddine" sort="Hadjadj, Nasreddine" uniqKey="Hadjadj N" first="Nasreddine" last="Hadjadj">Nasreddine Hadjadj</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bendjeddou, Lamia" sort="Bendjeddou, Lamia" uniqKey="Bendjeddou L" first="Lamia" last="Bendjeddou">Lamia Bendjeddou</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">23476514</idno><idno type="pmc">3588528</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588528</idno><idno type="RBID">PMC:3588528</idno><idno type="doi">10.1107/S1600536813005205</idno><date when="2013">2013</date><idno type="wicri:Area/Pmc/Corpus">000363</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000363</idno><idno type="wicri:Area/Pmc/Curation">000362</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000362</idno><idno type="wicri:Area/Pmc/Checkpoint">000221</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000221</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main"><italic>catena</italic>-Poly[[bis[4-(dimethylamino)pyridine-κ<italic>N</italic><sup>1</sup>]cobalt(II)]-di-μ-azido-κ<sup>4</sup><italic>N</italic><sup>1</sup>:<italic>N</italic><sup>3</sup>]</title><author><name sortKey="Guenifa, Fatiha" sort="Guenifa, Fatiha" uniqKey="Guenifa F" first="Fatiha" last="Guenifa">Fatiha Guenifa</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Zeghouan, Ouahida" sort="Zeghouan, Ouahida" uniqKey="Zeghouan O" first="Ouahida" last="Zeghouan">Ouahida Zeghouan</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Hadjadj, Nasreddine" sort="Hadjadj, Nasreddine" uniqKey="Hadjadj N" first="Nasreddine" last="Hadjadj">Nasreddine Hadjadj</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bendjeddou, Lamia" sort="Bendjeddou, Lamia" uniqKey="Bendjeddou L" first="Lamia" last="Bendjeddou">Lamia Bendjeddou</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2013">2013</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>The title layered polymer, [Co(N<sub>3</sub>)<sub>2</sub>(C<sub>7</sub>H<sub>10</sub>N<sub>2</sub>)<sub>2</sub>]<sub><italic>n</italic></sub>, contains Co<sup>II</sup>, azide and 4-(dimethylamino)pyridine (4-DMAP) species with site symmetries <italic>m</italic>2<italic>m</italic>, 2 and <italic>m</italic>, respectively. The Co<sup>2+</sup> ion adopts an octahedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co<sup>II</sup> atoms are connected by two bridging azide ligands, resulting in a chain parallel to the <italic>c</italic> axis.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id><journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title></journal-title-group><issn pub-type="epub">1600-5368</issn><publisher><publisher-name>International Union of Crystallography</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">23476514</article-id><article-id pub-id-type="pmc">3588528</article-id><article-id pub-id-type="publisher-id">vm2189</article-id><article-id pub-id-type="doi">10.1107/S1600536813005205</article-id><article-id pub-id-type="coden">ACSEBH</article-id><article-id pub-id-type="pii">S1600536813005205</article-id><article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject></subj-group></article-categories><title-group><article-title><italic>catena</italic>-Poly[[bis[4-(dimethylamino)pyridine-κ<italic>N</italic><sup>1</sup>]cobalt(II)]-di-μ-azido-κ<sup>4</sup><italic>N</italic><sup>1</sup>:<italic>N</italic><sup>3</sup>]</article-title><alt-title><italic>[Co(N<sub>3</sub>)<sub>2</sub>(C<sub>7</sub>H<sub>10</sub>N<sub>2</sub>)<sub>2</sub>]</italic></alt-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Guenifa</surname><given-names>Fatiha</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Zeghouan</surname><given-names>Ouahida</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Hadjadj</surname><given-names>Nasreddine</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Bendjeddou</surname><given-names>Lamia</given-names></name><xref ref-type="aff" rid="a">a</xref><xref ref-type="corresp" rid="cor">*</xref></contrib><contrib contrib-type="author"><name><surname>Merazig</surname><given-names>Hocine</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><aff id="a"><label>a</label>Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine,<country>Algeria</country></aff></contrib-group><author-notes><corresp id="cor">Correspondence e-mail: <email>Lamiabendjeddou@yahoo.fr</email></corresp></author-notes><pub-date pub-type="collection"><day>01</day><month>3</month><year>2013</year></pub-date><pub-date pub-type="epub"><day>28</day><month>2</month><year>2013</year></pub-date><pub-date pub-type="pmc-release"><day>28</day><month>2</month><year>2013</year></pub-date><pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
<volume>69</volume><issue>Pt 3</issue><issue-id pub-id-type="publisher-id">e130300</issue-id><fpage>m175</fpage><lpage>m175</lpage><history><date date-type="received"><day>10</day><month>2</month><year>2013</year></date><date date-type="accepted"><day>22</day><month>2</month><year>2013</year></date></history><permissions><copyright-statement>© Guenifa et al. 2013</copyright-statement><copyright-year>2013</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p></license></permissions><self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536813005205">A full version of this article is available from Crystallography Journals Online.</self-uri><abstract><p>The title layered polymer, [Co(N<sub>3</sub>)<sub>2</sub>(C<sub>7</sub>H<sub>10</sub>N<sub>2</sub>)<sub>2</sub>]<sub><italic>n</italic></sub>, contains Co<sup>II</sup>, azide and 4-(dimethylamino)pyridine (4-DMAP) species with site symmetries <italic>m</italic>2<italic>m</italic>, 2 and <italic>m</italic>, respectively. The Co<sup>2+</sup> ion adopts an octahedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co<sup>II</sup> atoms are connected by two bridging azide ligands, resulting in a chain parallel to the <italic>c</italic> axis.</p></abstract></article-meta></front><floats-group><table-wrap id="table1" position="float"><label>Table 1</label><caption><title>Selected bond lengths (Å)</title></caption><table frame="hsides" rules="groups"><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Co—N1</td><td style="" rowspan="1" colspan="1" align="char" valign="top">2.1764 (19)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Co—N1<italic>A</italic></td><td style="" rowspan="1" colspan="1" align="char" valign="top">2.110 (3)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Co—N1<italic>B</italic></td><td style="" rowspan="1" colspan="1" align="char" valign="top">2.135 (3)</td></tr></tbody></table></table-wrap></floats-group></pmc><affiliations><list><country><li>Algérie</li></country></list><tree><country name="Algérie"><noRegion><name sortKey="Guenifa, Fatiha" sort="Guenifa, Fatiha" uniqKey="Guenifa F" first="Fatiha" last="Guenifa">Fatiha Guenifa</name></noRegion><name sortKey="Bendjeddou, Lamia" sort="Bendjeddou, Lamia" uniqKey="Bendjeddou L" first="Lamia" last="Bendjeddou">Lamia Bendjeddou</name><name sortKey="Hadjadj, Nasreddine" sort="Hadjadj, Nasreddine" uniqKey="Hadjadj N" first="Nasreddine" last="Hadjadj">Nasreddine Hadjadj</name><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><name sortKey="Zeghouan, Ouahida" sort="Zeghouan, Ouahida" uniqKey="Zeghouan O" first="Ouahida" last="Zeghouan">Ouahida Zeghouan</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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