Bis{1-[(E)-(2-chlorophenyl)diazenyl]naphthalen-2-olato}copper(II)
Identifieur interne : 000209 ( Pmc/Checkpoint ); précédent : 000208; suivant : 000210Bis{1-[(E)-(2-chlorophenyl)diazenyl]naphthalen-2-olato}copper(II)
Auteurs : Mohamed Amine Benaouida [Algérie] ; Ali Benosmane [Algérie] ; Hassiba Bouguerria [Algérie] ; Salah Eddine Bouaoud [Algérie] ; Hocine Merazig [Algérie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.
Abstract
The CuII atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetracoordinated by two N and two O atoms from two bidentate 1-[(
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DOI: 10.1107/S1600536813016681
PubMed: 24046576
PubMed Central: 3772433
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis{1-[(<italic>E</italic>)-(2-chlorophenyl)diazenyl]naphthalen-2-olato}copper(II)</title><author><name sortKey="Benaouida, Mohamed Amine" sort="Benaouida, Mohamed Amine" uniqKey="Benaouida M" first="Mohamed Amine" last="Benaouida">Mohamed Amine Benaouida</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Benosmane, Ali" sort="Benosmane, Ali" uniqKey="Benosmane A" first="Ali" last="Benosmane">Ali Benosmane</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bouguerria, Hassiba" sort="Bouguerria, Hassiba" uniqKey="Bouguerria H" first="Hassiba" last="Bouguerria">Hassiba Bouguerria</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bouaoud, Salah Eddine" sort="Bouaoud, Salah Eddine" uniqKey="Bouaoud S" first="Salah Eddine" last="Bouaoud">Salah Eddine Bouaoud</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">24046576</idno><idno type="pmc">3772433</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772433</idno><idno type="RBID">PMC:3772433</idno><idno type="doi">10.1107/S1600536813016681</idno><date when="2013">2013</date><idno type="wicri:Area/Pmc/Corpus">000369</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000369</idno><idno type="wicri:Area/Pmc/Curation">000368</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000368</idno><idno type="wicri:Area/Pmc/Checkpoint">000209</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000209</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis{1-[(<italic>E</italic>)-(2-chlorophenyl)diazenyl]naphthalen-2-olato}copper(II)</title><author><name sortKey="Benaouida, Mohamed Amine" sort="Benaouida, Mohamed Amine" uniqKey="Benaouida M" first="Mohamed Amine" last="Benaouida">Mohamed Amine Benaouida</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Benosmane, Ali" sort="Benosmane, Ali" uniqKey="Benosmane A" first="Ali" last="Benosmane">Ali Benosmane</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bouguerria, Hassiba" sort="Bouguerria, Hassiba" uniqKey="Bouguerria H" first="Hassiba" last="Bouguerria">Hassiba Bouguerria</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bouaoud, Salah Eddine" sort="Bouaoud, Salah Eddine" uniqKey="Bouaoud S" first="Salah Eddine" last="Bouaoud">Salah Eddine Bouaoud</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2013">2013</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>The Cu<sup>II</sup> atom in the title compound, [Cu(C<sub>16</sub>H<sub>10</sub>ClN<sub>2</sub>O)<sub>2</sub>], is located on an inversion center and is tetracoordinated by two N and two O atoms from two bidentate 1-[(<italic>E</italic>)-(2-chlorophenyl)diazenyl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, molecules are linked <italic>via</italic> weak C—H⋯O and C—H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π–π interactions present involving adjacent naphthalene rings [centroid–centroid distance = 3.661 (13) Å].</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id><journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title></journal-title-group><issn pub-type="epub">1600-5368</issn><publisher><publisher-name>International Union of Crystallography</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">24046576</article-id><article-id pub-id-type="pmc">3772433</article-id><article-id pub-id-type="publisher-id">su2613</article-id><article-id pub-id-type="doi">10.1107/S1600536813016681</article-id><article-id pub-id-type="coden">ACSEBH</article-id><article-id pub-id-type="pii">S1600536813016681</article-id><article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject></subj-group></article-categories><title-group><article-title>Bis{1-[(<italic>E</italic>)-(2-chlorophenyl)diazenyl]naphthalen-2-olato}copper(II)</article-title><alt-title><italic>[Cu(C<sub>16</sub>H<sub>10</sub>ClN<sub>2</sub>O)<sub>2</sub>]</italic></alt-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Benaouida</surname><given-names>Mohamed Amine</given-names></name><xref ref-type="aff" rid="a">a</xref><xref ref-type="corresp" rid="cor">*</xref></contrib><contrib contrib-type="author"><name><surname>Benosmane</surname><given-names>Ali</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Bouguerria</surname><given-names>Hassiba</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Bouaoud</surname><given-names>Salah Eddine</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Merazig</surname><given-names>Hocine</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><aff id="a"><label>a</label>Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1,<country>Algeria</country></aff></contrib-group><author-notes><corresp id="cor">Correspondence e-mail: <email>mbenaouida@yahoo.fr</email></corresp></author-notes><pub-date pub-type="collection"><day>01</day><month>7</month><year>2013</year></pub-date><pub-date pub-type="epub"><day>22</day><month>6</month><year>2013</year></pub-date><pub-date pub-type="pmc-release"><day>22</day><month>6</month><year>2013</year></pub-date><pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
<volume>69</volume><issue>Pt 7</issue><issue-id pub-id-type="publisher-id">e130700</issue-id><fpage>m405</fpage><lpage>m405</lpage><history><date date-type="received"><day>13</day><month>6</month><year>2013</year></date><date date-type="accepted"><day>15</day><month>6</month><year>2013</year></date></history><permissions><copyright-statement>© Benaouida et al. 2013</copyright-statement><copyright-year>2013</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p></license></permissions><self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536813016681">A full version of this article is available from Crystallography Journals Online.</self-uri><abstract><p>The Cu<sup>II</sup> atom in the title compound, [Cu(C<sub>16</sub>H<sub>10</sub>ClN<sub>2</sub>O)<sub>2</sub>], is located on an inversion center and is tetracoordinated by two N and two O atoms from two bidentate 1-[(<italic>E</italic>)-(2-chlorophenyl)diazenyl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, molecules are linked <italic>via</italic> weak C—H⋯O and C—H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π–π interactions present involving adjacent naphthalene rings [centroid–centroid distance = 3.661 (13) Å].</p></abstract></article-meta></front><floats-group><table-wrap id="table1" position="float"><label>Table 1</label><caption><title>Hydrogen-bond geometry (Å, °)</title></caption><table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H</th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th></tr></thead><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">C5—H5⋯O1<sup>i</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.93</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.62</td><td style="" rowspan="1" colspan="1" align="left" valign="top">3.300 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">130</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">C5—H5⋯Cl1<sup>i</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.93</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.94</td><td style="" rowspan="1" colspan="1" align="left" valign="top">3.682 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">138</td></tr></tbody></table><table-wrap-foot><p>Symmetry code: (i) <inline-formula><inline-graphic xlink:href="e-69-0m405-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>.</p></table-wrap-foot></table-wrap></floats-group></pmc><affiliations><list><country><li>Algérie</li></country></list><tree><country name="Algérie"><noRegion><name sortKey="Benaouida, Mohamed Amine" sort="Benaouida, Mohamed Amine" uniqKey="Benaouida M" first="Mohamed Amine" last="Benaouida">Mohamed Amine Benaouida</name></noRegion><name sortKey="Benosmane, Ali" sort="Benosmane, Ali" uniqKey="Benosmane A" first="Ali" last="Benosmane">Ali Benosmane</name><name sortKey="Bouaoud, Salah Eddine" sort="Bouaoud, Salah Eddine" uniqKey="Bouaoud S" first="Salah Eddine" last="Bouaoud">Salah Eddine Bouaoud</name><name sortKey="Bouguerria, Hassiba" sort="Bouguerria, Hassiba" uniqKey="Bouguerria H" first="Hassiba" last="Bouguerria">Hassiba Bouguerria</name><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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