Na3Al(AsO4)2
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Auteurs : Noura Fakhar Bourguiba [Tunisie] ; Mohamed Faouzi Zid [Tunisie] ; Ahmed Driss [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.
Abstract
The structure of the title compound trisodium aluminium bis(arsenate), Na3Al(AsO4)2, is built up from AlO4 and AsO4 corner-sharing tetrahedra, forming an undulating two-dimensional framework parallel to (100). The layers are constituted of large Al6As6O36 rings made up from six AlO4 and AsO4 tetrahedra in which two sodium cations are situated, the third sodium cation being located in the interlayer space. The structural relationships between the title compound and Na3Fe(PO4)2, NaAlCo(PO4)2 and Al5Co3(PO4)8 are discussed.
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DOI: 10.1107/S1600536813002213
PubMed: 23424394
PubMed Central: 3569176
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Na<sub>3</sub>Al(AsO<sub>4</sub>)<sub>2</sub></title><author><name sortKey="Fakhar Bourguiba, Noura" sort="Fakhar Bourguiba, Noura" uniqKey="Fakhar Bourguiba N" first="Noura" last="Fakhar Bourguiba">Noura Fakhar Bourguiba</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 ElManar II Tunis,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 ElManar II Tunis,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 ElManar II Tunis,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">23424394</idno><idno type="pmc">3569176</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569176</idno><idno type="RBID">PMC:3569176</idno><idno type="doi">10.1107/S1600536813002213</idno><date when="2013">2013</date><idno type="wicri:Area/Pmc/Corpus">000360</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000360</idno><idno type="wicri:Area/Pmc/Curation">000359</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000359</idno><idno type="wicri:Area/Pmc/Checkpoint">000184</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000184</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Na<sub>3</sub>Al(AsO<sub>4</sub>)<sub>2</sub></title><author><name sortKey="Fakhar Bourguiba, Noura" sort="Fakhar Bourguiba, Noura" uniqKey="Fakhar Bourguiba N" first="Noura" last="Fakhar Bourguiba">Noura Fakhar Bourguiba</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 ElManar II Tunis,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 ElManar II Tunis,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 ElManar II Tunis,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2013">2013</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>The structure of the title compound trisodium aluminium bis(arsenate), Na<sub>3</sub>Al(AsO<sub>4</sub>)<sub>2</sub>, is built up from AlO<sub>4</sub> and AsO<sub>4</sub> corner-sharing tetrahedra, forming an undulating two-dimensional framework parallel to (100). The layers are constituted of large Al<sub>6</sub>As<sub>6</sub>O<sub>36</sub> rings made up from six AlO<sub>4</sub> and AsO<sub>4</sub> tetrahedra in which two sodium cations are situated, the third sodium cation being located in the interlayer space. The structural relationships between the title compound and Na<sub>3</sub>Fe(PO<sub>4</sub>)<sub>2</sub>, NaAlCo(PO<sub>4</sub>)<sub>2</sub> and Al<sub>5</sub>Co<sub>3</sub>(PO<sub>4</sub>)<sub>8</sub> are discussed.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id><journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title></journal-title-group><issn pub-type="epub">1600-5368</issn><publisher><publisher-name>International Union of Crystallography</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">23424394</article-id><article-id pub-id-type="pmc">3569176</article-id><article-id pub-id-type="publisher-id">vn2065</article-id><article-id pub-id-type="doi">10.1107/S1600536813002213</article-id><article-id pub-id-type="coden">ACSEBH</article-id><article-id pub-id-type="pii">S1600536813002213</article-id><article-categories><subj-group subj-group-type="heading"><subject>Inorganic Papers</subject></subj-group></article-categories><title-group><article-title>Na<sub>3</sub>Al(AsO<sub>4</sub>)<sub>2</sub></article-title><alt-title><italic>Na<sub>3</sub>Al(AsO<sub>4</sub>)<sub>2</sub></italic></alt-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Fakhar Bourguiba</surname><given-names>Noura</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Zid</surname><given-names>Mohamed Faouzi</given-names></name><xref ref-type="aff" rid="a">a</xref><xref ref-type="corresp" rid="cor">*</xref></contrib><contrib contrib-type="author"><name><surname>Driss</surname><given-names>Ahmed</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><aff id="a"><label>a</label>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 ElManar II Tunis,<country>Tunisia</country></aff></contrib-group><author-notes><corresp id="cor">Correspondence e-mail: <email>faouzi.zid@fst.rnu.tn</email></corresp></author-notes><pub-date pub-type="collection"><day>01</day><month>2</month><year>2013</year></pub-date><pub-date pub-type="epub"><day>31</day><month>1</month><year>2013</year></pub-date><pub-date pub-type="pmc-release"><day>31</day><month>1</month><year>2013</year></pub-date><pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
<volume>69</volume><issue>Pt 2</issue><issue-id pub-id-type="publisher-id">e130200</issue-id><fpage>i14</fpage><lpage>i14</lpage><history><date date-type="received"><day>15</day><month>1</month><year>2013</year></date><date date-type="accepted"><day>22</day><month>1</month><year>2013</year></date></history><permissions><copyright-statement>© Fakhar Bourguiba et al. 2013</copyright-statement><copyright-year>2013</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p></license></permissions><self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536813002213">A full version of this article is available from Crystallography Journals Online.</self-uri><abstract><p>The structure of the title compound trisodium aluminium bis(arsenate), Na<sub>3</sub>Al(AsO<sub>4</sub>)<sub>2</sub>, is built up from AlO<sub>4</sub> and AsO<sub>4</sub> corner-sharing tetrahedra, forming an undulating two-dimensional framework parallel to (100). The layers are constituted of large Al<sub>6</sub>As<sub>6</sub>O<sub>36</sub> rings made up from six AlO<sub>4</sub> and AsO<sub>4</sub> tetrahedra in which two sodium cations are situated, the third sodium cation being located in the interlayer space. The structural relationships between the title compound and Na<sub>3</sub>Fe(PO<sub>4</sub>)<sub>2</sub>, NaAlCo(PO<sub>4</sub>)<sub>2</sub> and Al<sub>5</sub>Co<sub>3</sub>(PO<sub>4</sub>)<sub>8</sub> are discussed.</p></abstract></article-meta></front><floats-group><table-wrap id="table1" position="float"><label>Table 1</label><caption><title>Selected bond lengths (Å)</title></caption><table frame="hsides" rules="groups"><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Al1—O2<sup>i</sup></td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.771 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Al1—O4</td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.755 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Al1—O6<sup>ii</sup></td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.769 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Al1—O8<sup>iii</sup></td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.755 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">As1—O1</td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.654 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">As1—O2</td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.732 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">As1—O5<sup>iv</sup></td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.649 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">As2—O3</td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.655 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">As2—O4<sup>v</sup></td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.723 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">As2—O6</td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.734 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">As2—O7</td><td style="" rowspan="1" colspan="1" align="char" valign="top">1.655 (2)</td></tr></tbody></table><table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-69-00i14-efi4.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (ii) <inline-formula><inline-graphic xlink:href="e-69-00i14-efi5.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (iii) <inline-formula><inline-graphic xlink:href="e-69-00i14-efi6.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (iv) <inline-formula><inline-graphic xlink:href="e-69-00i14-efi7.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (v) <inline-formula><inline-graphic xlink:href="e-69-00i14-efi8.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>.</p></table-wrap-foot></table-wrap></floats-group></pmc><affiliations><list><country><li>Tunisie</li></country></list><tree><country name="Tunisie"><noRegion><name sortKey="Fakhar Bourguiba, Noura" sort="Fakhar Bourguiba, Noura" uniqKey="Fakhar Bourguiba N" first="Noura" last="Fakhar Bourguiba">Noura Fakhar Bourguiba</name></noRegion><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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