Phase equilibria at 1150°C in the Co-rich alloys Sm-Co-Zr and structure of the 1:7 phase
Identifieur interne : 000354 ( PascalFrancis/Curation ); précédent : 000353; suivant : 000355Phase equilibria at 1150°C in the Co-rich alloys Sm-Co-Zr and structure of the 1:7 phase
Auteurs : S. Derkaoui [Maroc] ; N. Valignat [France] ; C. H. Allibert [France]Source :
- Journal of alloys and compounds [ 0925-8388 ] ; 1996.
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- Pascal (Inist)
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Abstract
Copyright (c) 1996 Elsevier Science B.V. All rights reserved. In the concentration range 75-100at.%Co, the isothermal section at 1150°C of the system Sm-Co-Zr is determined experimentally. The following features are evidenced: a very small Sm solubility in Co, Zr2Co11, and Zr6Co23, an extended Zr for Sm substitution rate in SmCo3, Sm2Co7 and Sm5Co19, and a significant Zr solubility in SmCo5 and Sm2Co17 that induces the existence of a continuous ternary single phase 1:7. On the basis of the lattice parameter data, the formation of this phase by the substitution of Co dumbbells and/or Sm atoms for Zr atoms is proposed.
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<front><div type="abstract" xml:lang="en">Copyright (c) 1996 Elsevier Science B.V. All rights reserved. In the concentration range 75-100at.%Co, the isothermal section at 1150°C of the system Sm-Co-Zr is determined experimentally. The following features are evidenced: a very small Sm solubility in Co, Zr<sub>2</sub>
Co<sub>11</sub>
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Co<sub>19</sub>
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and Sm<sub>2</sub>
Co<sub>17</sub>
that induces the existence of a continuous ternary single phase 1:7. On the basis of the lattice parameter data, the formation of this phase by the substitution of Co dumbbells and/or Sm atoms for Zr atoms is proposed.</div>
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