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Phase equilibria at 1150°C in the Co-rich alloys Sm-Co-Zr and structure of the 1:7 phase

Identifieur interne : 000354 ( PascalFrancis/Curation ); précédent : 000353; suivant : 000355

Phase equilibria at 1150°C in the Co-rich alloys Sm-Co-Zr and structure of the 1:7 phase

Auteurs : S. Derkaoui [Maroc] ; N. Valignat [France] ; C. H. Allibert [France]

Source :

RBID : Pascal:96-0215434

Descripteurs français

English descriptors

Abstract

Copyright (c) 1996 Elsevier Science B.V. All rights reserved. In the concentration range 75-100at.%Co, the isothermal section at 1150°C of the system Sm-Co-Zr is determined experimentally. The following features are evidenced: a very small Sm solubility in Co, Zr2Co11, and Zr6Co23, an extended Zr for Sm substitution rate in SmCo3, Sm2Co7 and Sm5Co19, and a significant Zr solubility in SmCo5 and Sm2Co17 that induces the existence of a continuous ternary single phase 1:7. On the basis of the lattice parameter data, the formation of this phase by the substitution of Co dumbbells and/or Sm atoms for Zr atoms is proposed.
pA  
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A08 01  1  ENG  @1 Phase equilibria at 1150°C in the Co-rich alloys Sm-Co-Zr and structure of the 1:7 phase
A11 01  1    @1 DERKAOUI (S.)
A11 02  1    @1 VALIGNAT (N.)
A11 03  1    @1 ALLIBERT (C. H.)
A14 01      @1 Département de Physique, Faculté des Sciences, BP 28/S, Université Ibnou Zohr @2 8000 Agadir @3 MAR @Z 1 aut.
A14 02      @1 Laboratoire de Thermodynamique et de Physico-Chimie Métallurgiques associé au CNRS (URA 29), ENSEEG, BP 75 @2 38402 Saint Martin d'Hères @3 FRA @Z 2 aut. @Z 3 aut.
A20       @1 296-301
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A64 01  1    @0 Journal of alloys and compounds
A66 01      @0 CHE
C01 01    ENG  @0 Copyright (c) 1996 Elsevier Science B.V. All rights reserved. In the concentration range 75-100at.%Co, the isothermal section at 1150°C of the system Sm-Co-Zr is determined experimentally. The following features are evidenced: a very small Sm solubility in Co, Zr2Co11, and Zr6Co23, an extended Zr for Sm substitution rate in SmCo3, Sm2Co7 and Sm5Co19, and a significant Zr solubility in SmCo5 and Sm2Co17 that induces the existence of a continuous ternary single phase 1:7. On the basis of the lattice parameter data, the formation of this phase by the substitution of Co dumbbells and/or Sm atoms for Zr atoms is proposed.
C02 01  3    @0 001B60A66D
C02 02  X    @0 240
C03 01  3  FRE  @0 Equilibre phase @5 01
C03 01  3  ENG  @0 Phase equilibria @5 01
C03 02  3  FRE  @0 Alliage base cobalt @2 NK @5 02
C03 02  3  ENG  @0 Cobalt base alloys @2 NK @5 02
C03 03  3  FRE  @0 Samarium alliage @5 03
C03 03  3  ENG  @0 Samarium alloys @5 03
C03 04  3  FRE  @0 Zirconium alliage @5 04
C03 04  3  ENG  @0 Zirconium alloys @5 04
C03 05  3  FRE  @0 Alliage ternaire @5 05
C03 05  3  ENG  @0 Ternary alloys @5 05
C03 06  3  FRE  @0 Structure cristalline @5 06
C03 06  3  ENG  @0 Crystal structure @5 06
C03 07  3  FRE  @0 Diagramme phase @5 07
C03 07  3  ENG  @0 Phase diagrams @5 07
C03 08  X  FRE  @0 Section isotherme @5 08
C03 08  X  ENG  @0 Isothermal section @5 08
C03 08  X  GER  @0 Isothermer Schnitt @5 08
C03 08  X  SPA  @0 Sección isotérmica @5 08
C03 09  3  FRE  @0 Paramètre cristallin @5 09
C03 09  3  ENG  @0 Lattice parameters @5 09
C03 10  3  FRE  @0 SEM @5 10
C03 10  3  ENG  @0 SEM @5 10
C03 11  3  FRE  @0 Etude expérimentale @5 23
C03 11  3  ENG  @0 Experimental study @5 23
C03 12  3  FRE  @0 6166D @2 PAC @4 INC @5 95
N21       @1 148

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<div type="abstract" xml:lang="en">Copyright (c) 1996 Elsevier Science B.V. All rights reserved. In the concentration range 75-100at.%Co, the isothermal section at 1150°C of the system Sm-Co-Zr is determined experimentally. The following features are evidenced: a very small Sm solubility in Co, Zr
<sub>2</sub>
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<sub>11</sub>
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<sub>2</sub>
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<sub>17</sub>
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<sub>2</sub>
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<sub>11</sub>
, and Zr
<sub>6</sub>
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<sub>23</sub>
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<sub>2</sub>
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<sub>5</sub>
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<sub>2</sub>
Co
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