CobaltMaghrebV1, PascalFrancis, Curation, bibRecord, 000350

LiNi1-yCoyO2 positive electrode materials : relationships between the structure, physical properties and electrochemical behaviour

Identifieur interne : 000350 ( PascalFrancis/Curation ); précédent : 000349; suivant : 000351

LiNi1-yCoyO2 positive electrode materials : relationships between the structure, physical properties and electrochemical behaviour

Auteurs : ISMAEL SAADOUNE [Maroc] ; C. Delmas [France]

Source :

Journal of materials chemistry [ 0959-9428 ] ; 1996.

RBID : Pascal:96-0129636

Descripteurs français

Pascal (Inist)
- Batterie, Lithium, Relation structure propriété, Structure cristalline, Propriété physique, Susceptibilité magnétique, Caractéristique électrique, Cycle charge décharge, Matériau électrode, Lithium Oxyde, Cobalt Oxyde, Nickel Oxyde, Composé quaternaire, LiNi0,7Co0,3O2, Co Li Ni O.

English descriptors

KwdEn :
- Battery, Cobalt Oxides, Crystalline structure, Discharge charge cycle, Electrical characteristic, Electrode material, Lithium, Lithium Oxides, Magnetic susceptibility, Nickel Oxides, Physical properties, Property structure relationship, Quaternary compound.

Abstract

The LiNi_1-yCo_yO₂ oxides crystallize in the rhombohedral system with 1-NaFeO₂ type structure. A structural study of these materials shows the presence of a few nickel ions in the Li plane for y ≤ 0.2. This phenomenon has been confirmed by a study of the magnetic and electrical properties. The LiNi_1-yCo_yO₂ lamellar oxides are used as positive electrode materials in Li batteries. The Li∥Li_xNi_1-yCO_yO₂ cells exhibit electrochemical behaviour strongly related to the existence of structural defects. A high specific energy (close to 500 W h kg ^-1 of active material) is obtained for y = 0.3. These performances are attractive from an applications point of view.

A01	`01`	`1`		`@0 0959-9428`
A03		`1`		`@0 J. mater. chem.`
A05				`@2 6`
A06				`@2 2`
A08	`01`	`1`	`ENG`	`@1 LiNi_1-yCo_yO₂ positive electrode materials : relationships between the structure, physical properties and electrochemical behaviour`
A11	`01`	`1`		`@1 ISMAEL SAADOUNE`
A11	`02`	`1`		`@1 DELMAS (C.)`
A14	`01`			`@1 Univ. Cadi-Ayyad, fac. sci.-Semlalia, lab. chimie solide minéral @2 Marackech @3 MAR @Z 1 aut.`
A14	`02`			`@1 Inst. chime matière condensée Bordeaux @2 33608 Pessac @3 FRA @Z 2 aut.`
A14	`03`			`@1 Ecole nationale supérieure chimie physique Bordeaux @2 33608 Pessac @3 FRA @Z 2 aut.`
A20				`@1 193-199`
A21				`@1 1996`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 22603 @5 354000052714410120`
A44				`@0 0000`
A45				`@0 23 ref.`
A47	`01`	`1`		`@0 96-0129636`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of materials chemistry`
A66	`01`			`@0 GBR`
C01	`01`		`ENG`	@0 The LiNi_1-yCo_yO₂ oxides crystallize in the rhombohedral system with 1-NaFeO₂ type structure. A structural study of these materials shows the presence of a few nickel ions in the Li plane for y ≤ 0.2. This phenomenon has been confirmed by a study of the magnetic and electrical properties. The LiNi_1-yCo_yO₂ lamellar oxides are used as positive electrode materials in Li batteries. The Li∥Li_xNi_1-yCO_yO₂ cells exhibit electrochemical behaviour strongly related to the existence of structural defects. A high specific energy (close to 500 W h kg ^-1 of active material) is obtained for y = 0.3. These performances are attractive from an applications point of view.
C02	`01`	`X`		`@0 001D05I03E`
C03	`01`	`X`	`FRE`	`@0 Batterie @5 01`
C03	`01`	`X`	`ENG`	`@0 Battery @5 01`
C03	`01`	`X`	`SPA`	`@0 Batería @5 01`
C03	`02`	`X`	`FRE`	`@0 Lithium @2 NC @5 02`
C03	`02`	`X`	`ENG`	`@0 Lithium @2 NC @5 02`
C03	`02`	`X`	`GER`	`@0 Lithium @2 NC @5 02`
C03	`02`	`X`	`SPA`	`@0 Litio @2 NC @5 02`
C03	`03`	`X`	`FRE`	`@0 Relation structure propriété @5 03`
C03	`03`	`X`	`ENG`	`@0 Property structure relationship @5 03`
C03	`03`	`X`	`SPA`	`@0 Relación estructura propiedad @5 03`
C03	`04`	`X`	`FRE`	`@0 Structure cristalline @5 04`
C03	`04`	`X`	`ENG`	`@0 Crystalline structure @5 04`
C03	`04`	`X`	`GER`	`@0 Kristallstruktur @5 04`
C03	`04`	`X`	`SPA`	`@0 Estructura cristalina @5 04`
C03	`05`	`X`	`FRE`	`@0 Propriété physique @5 05`
C03	`05`	`X`	`ENG`	`@0 Physical properties @5 05`
C03	`05`	`X`	`GER`	`@0 Physikalische Eigenschaft @5 05`
C03	`05`	`X`	`SPA`	`@0 Propiedad física @5 05`
C03	`06`	`X`	`FRE`	`@0 Susceptibilité magnétique @5 06`
C03	`06`	`X`	`ENG`	`@0 Magnetic susceptibility @5 06`
C03	`06`	`X`	`GER`	`@0 Magnetische Suszeptibilitaet @5 06`
C03	`06`	`X`	`SPA`	`@0 Susceptibilidad magnética @5 06`
C03	`07`	`X`	`FRE`	`@0 Caractéristique électrique @5 07`
C03	`07`	`X`	`ENG`	`@0 Electrical characteristic @5 07`
C03	`07`	`X`	`GER`	`@0 Elektrische Groesse @5 07`
C03	`07`	`X`	`SPA`	`@0 Característica eléctrica @5 07`
C03	`08`	`X`	`FRE`	`@0 Cycle charge décharge @5 08`
C03	`08`	`X`	`ENG`	`@0 Discharge charge cycle @5 08`
C03	`08`	`X`	`SPA`	`@0 Ciclo carga descarga @5 08`
C03	`09`	`X`	`FRE`	`@0 Matériau électrode @5 09`
C03	`09`	`X`	`ENG`	`@0 Electrode material @5 09`
C03	`09`	`X`	`SPA`	`@0 Material electrodo @5 09`
C03	`10`	`X`	`FRE`	`@0 Lithium Oxyde @2 NC @2 NA @5 10`
C03	`10`	`X`	`ENG`	`@0 Lithium Oxides @2 NC @2 NA @5 10`
C03	`10`	`X`	`SPA`	`@0 Litio Óxido @2 NC @2 NA @5 10`
C03	`11`	`X`	`FRE`	`@0 Cobalt Oxyde @2 NC @2 NA @5 11`
C03	`11`	`X`	`ENG`	`@0 Cobalt Oxides @2 NC @2 NA @5 11`
C03	`11`	`X`	`SPA`	`@0 Cobalto Óxido @2 NC @2 NA @5 11`
C03	`12`	`X`	`FRE`	`@0 Nickel Oxyde @2 NC @2 FX @2 NA @5 12`
C03	`12`	`X`	`ENG`	`@0 Nickel Oxides @2 NC @2 FX @2 NA @5 12`
C03	`12`	`X`	`SPA`	`@0 Niquel Óxido @2 NC @2 FX @2 NA @5 12`
C03	`13`	`X`	`FRE`	`@0 Composé quaternaire @5 14`
C03	`13`	`X`	`ENG`	`@0 Quaternary compound @5 14`
C03	`13`	`X`	`SPA`	`@0 Compuesto cuaternario @5 14`
C03	`14`	`X`	`FRE`	`@0 LiNi0,7Co0,3O2 @4 INC @5 62`
C03	`15`	`X`	`FRE`	`@0 Co Li Ni O @4 INC @5 63`
C07	`01`	`X`	`FRE`	`@0 Métal transition Composé @2 NC @2 NA @5 13`
C07	`01`	`X`	`ENG`	`@0 Transition metal Compounds @2 NC @2 NA @5 13`
C07	`01`	`X`	`SPA`	`@0 Metal transición Compuesto @2 NC @2 NA @5 13`
N21				`@1 085`

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Le document en format XML

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Co<sub>y</sub>
O<sub>2</sub>
 positive electrode materials : relationships between the structure, physical properties and electrochemical behaviour</title>
<author><name sortKey="Ismael Saadoune" sort="Ismael Saadoune" uniqKey="Ismael Saadoune" last="Ismael Saadoune">ISMAEL SAADOUNE</name>
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<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Ecole nationale supérieure chimie physique Bordeaux</s1>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">LiNi<sub>1-y</sub>
Co<sub>y</sub>
O<sub>2</sub>
 positive electrode materials : relationships between the structure, physical properties and electrochemical behaviour</title>
<author><name sortKey="Ismael Saadoune" sort="Ismael Saadoune" uniqKey="Ismael Saadoune" last="Ismael Saadoune">ISMAEL SAADOUNE</name>
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<s2>Marackech</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
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<country>Maroc</country>
</affiliation>
</author>
<author><name sortKey="Delmas, C" sort="Delmas, C" uniqKey="Delmas C" first="C." last="Delmas">C. Delmas</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Inst. chime matière condensée Bordeaux</s1>
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<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Ecole nationale supérieure chimie physique Bordeaux</s1>
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<series><title level="j" type="main">Journal of materials chemistry</title>
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<seriesStmt><title level="j" type="main">Journal of materials chemistry</title>
<title level="j" type="abbreviated">J. mater. chem.</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Battery</term>
<term>Cobalt Oxides</term>
<term>Crystalline structure</term>
<term>Discharge charge cycle</term>
<term>Electrical characteristic</term>
<term>Electrode material</term>
<term>Lithium</term>
<term>Lithium Oxides</term>
<term>Magnetic susceptibility</term>
<term>Nickel Oxides</term>
<term>Physical properties</term>
<term>Property structure relationship</term>
<term>Quaternary compound</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Batterie</term>
<term>Lithium</term>
<term>Relation structure propriété</term>
<term>Structure cristalline</term>
<term>Propriété physique</term>
<term>Susceptibilité magnétique</term>
<term>Caractéristique électrique</term>
<term>Cycle charge décharge</term>
<term>Matériau électrode</term>
<term>Lithium Oxyde</term>
<term>Cobalt Oxyde</term>
<term>Nickel Oxyde</term>
<term>Composé quaternaire</term>
<term>LiNi0,7Co0,3O2</term>
<term>Co Li Ni O</term>
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<front><div type="abstract" xml:lang="en">The LiNi<sub>1-y</sub>
Co<sub>y</sub>
O<sub>2</sub>
 oxides crystallize in the rhombohedral system with 1-NaFeO<sub>2</sub>
 type structure. A structural study of these materials shows the presence of a few nickel ions in the Li plane for y ≤ 0.2. This phenomenon has been confirmed by a study of the magnetic and electrical properties. The LiNi<sub>1-y</sub>
Co<sub>y</sub>
O<sub>2</sub>
 lamellar oxides are used as positive electrode materials in Li batteries. The Li∥Li<sub>x</sub>
Ni<sub>1-y</sub>
CO<sub>y</sub>
O<sub>2</sub>
 cells exhibit electrochemical behaviour strongly related to the existence of structural defects. A high specific energy (close to 500 W h kg <sup>-1</sup>
 of active material) is obtained for y = 0.3. These performances are attractive from an applications point of view.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0959-9428</s0>
</fA01>
<fA03 i2="1"><s0>J. mater. chem.</s0>
</fA03>
<fA05><s2>6</s2>
</fA05>
<fA06><s2>2</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>LiNi<sub>1-y</sub>
Co<sub>y</sub>
O<sub>2</sub>
 positive electrode materials : relationships between the structure, physical properties and electrochemical behaviour</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>ISMAEL SAADOUNE</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>DELMAS (C.)</s1>
</fA11>
<fA14 i1="01"><s1>Univ. Cadi-Ayyad, fac. sci.-Semlalia, lab. chimie solide minéral</s1>
<s2>Marackech</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Inst. chime matière condensée Bordeaux</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Ecole nationale supérieure chimie physique Bordeaux</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
</fA14>
<fA20><s1>193-199</s1>
</fA20>
<fA21><s1>1996</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>22603</s2>
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<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of materials chemistry</s0>
</fA64>
<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The LiNi<sub>1-y</sub>
Co<sub>y</sub>
O<sub>2</sub>
 oxides crystallize in the rhombohedral system with 1-NaFeO<sub>2</sub>
 type structure. A structural study of these materials shows the presence of a few nickel ions in the Li plane for y ≤ 0.2. This phenomenon has been confirmed by a study of the magnetic and electrical properties. The LiNi<sub>1-y</sub>
Co<sub>y</sub>
O<sub>2</sub>
 lamellar oxides are used as positive electrode materials in Li batteries. The Li∥Li<sub>x</sub>
Ni<sub>1-y</sub>
CO<sub>y</sub>
O<sub>2</sub>
 cells exhibit electrochemical behaviour strongly related to the existence of structural defects. A high specific energy (close to 500 W h kg <sup>-1</sup>
 of active material) is obtained for y = 0.3. These performances are attractive from an applications point of view.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D05I03E</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Batterie</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Battery</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Batería</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Lithium</s0>
<s2>NC</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Lithium</s0>
<s2>NC</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="GER"><s0>Lithium</s0>
<s2>NC</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Litio</s0>
<s2>NC</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Relation structure propriété</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Property structure relationship</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Relación estructura propiedad</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Structure cristalline</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Crystalline structure</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="GER"><s0>Kristallstruktur</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Estructura cristalina</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Propriété physique</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Physical properties</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="GER"><s0>Physikalische Eigenschaft</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Propiedad física</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Susceptibilité magnétique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Magnetic susceptibility</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="GER"><s0>Magnetische Suszeptibilitaet</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Susceptibilidad magnética</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Caractéristique électrique</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Electrical characteristic</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="GER"><s0>Elektrische Groesse</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Característica eléctrica</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Cycle charge décharge</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Discharge charge cycle</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Ciclo carga descarga</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Matériau électrode</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Electrode material</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Material electrodo</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Lithium Oxyde</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Lithium Oxides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Litio Óxido</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Cobalt Oxyde</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Cobalt Oxides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Cobalto Óxido</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Nickel Oxyde</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Nickel Oxides</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Niquel Óxido</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Composé quaternaire</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Quaternary compound</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Compuesto cuaternario</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>LiNi0,7Co0,3O2</s0>
<s4>INC</s4>
<s5>62</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Co Li Ni O</s0>
<s4>INC</s4>
<s5>63</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Métal transition Composé</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Transition metal Compounds</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Metal transición Compuesto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
</fC07>
<fN21><s1>085</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

LiNi1-yCoyO2 positive electrode materials : relationships between the structure, physical properties and electrochemical behaviour

LiNi1-yCoyO2 positive electrode materials : relationships between the structure, physical properties and electrochemical behaviour

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