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Synthesis, structural and magnetic studies of the CuCr1-xCoxO2 delafossite oxide

Identifieur interne : 000261 ( PascalFrancis/Curation ); précédent : 000260; suivant : 000262

Synthesis, structural and magnetic studies of the CuCr1-xCoxO2 delafossite oxide

Auteurs : T. Elkhouni [Tunisie] ; M. Amami [Tunisie] ; C. V. Colin [France] ; P. Strobel [France] ; A. Ben Salah [Tunisie]

Source :

RBID : Pascal:13-0110347

Descripteurs français

English descriptors

Abstract

We modulate the spin chirality and the magnetization in CuCrO2, by doping at Cr3+ sites with magnetic ions of slightly different size. Structure and magnetic properties of delafossite oxide CuCr1-xCoxO2 (0≤x≤0.06) have been investigated. With the substitution of magnetic Co3+ for Cr3+ (S=3/2), the antiferromagnetic (AF) transition becomes broader and the transition temperature increases. However, at low temperature, the magnetic data for CuCr, -xCoxO2 shows evidence for weak ferromagnetism. Comparing the substitution effect of Co3+ to those of other magnetic metal transition, magnetization around the AF transition does not seem to correlate with randomness and lattice parameter.
pA  
A01 01  1    @0 0304-8853
A02 01      @0 JMMMDC
A03   1    @0 J. magn. magn. mater.
A05       @2 330
A08 01  1  ENG  @1 Synthesis, structural and magnetic studies of the CuCr1-xCoxO2 delafossite oxide
A11 01  1    @1 ELKHOUNI (T.)
A11 02  1    @1 AMAMI (M.)
A11 03  1    @1 COLIN (C. V.)
A11 04  1    @1 STROBEL (P.)
A11 05  1    @1 SALAH (A. Ben)
A14 01      @1 Laboratoire des Sciences de Matériaux et d'environnement, Faculté des Sciences de Sfax, BP 763 @2 3038 @3 TUN @Z 1 aut. @Z 2 aut. @Z 5 aut.
A14 02      @1 Institut Néel, CNRS et Université Joseph Fourier, B.P. 166 @2 38042 Grenoble @3 FRA @Z 3 aut. @Z 4 aut.
A14 03      @1 Unite de Recherche de Chimie des Matériaux, ISSBAT, Université Tunis ElManar, 9, Avenue Dr. Zouhaier Safi @2 1006 Tunis @3 TUN @Z 2 aut.
A20       @1 101-105
A21       @1 2013
A23 01      @0 ENG
A43 01      @1 INIST @2 17230 @5 354000182568350180
A44       @0 0000 @1 © 2013 INIST-CNRS. All rights reserved.
A45       @0 31 ref.
A47 01  1    @0 13-0110347
A60       @1 P
A61       @0 A
A64 01  1    @0 Journal of magnetism and magnetic materials
A66 01      @0 NLD
C01 01    ENG  @0 We modulate the spin chirality and the magnetization in CuCrO2, by doping at Cr3+ sites with magnetic ions of slightly different size. Structure and magnetic properties of delafossite oxide CuCr1-xCoxO2 (0≤x≤0.06) have been investigated. With the substitution of magnetic Co3+ for Cr3+ (S=3/2), the antiferromagnetic (AF) transition becomes broader and the transition temperature increases. However, at low temperature, the magnetic data for CuCr, -xCoxO2 shows evidence for weak ferromagnetism. Comparing the substitution effect of Co3+ to those of other magnetic metal transition, magnetization around the AF transition does not seem to correlate with randomness and lattice parameter.
C02 01  3    @0 001B70E60E
C02 02  3    @0 001B70E30K
C02 03  3    @0 001B70E50P
C03 01  3  FRE  @0 Chiralité @5 02
C03 01  3  ENG  @0 Chirality @5 02
C03 02  3  FRE  @0 Aimantation @5 03
C03 02  3  ENG  @0 Magnetization @5 03
C03 03  3  FRE  @0 Impureté @5 05
C03 03  3  ENG  @0 Impurities @5 05
C03 04  3  FRE  @0 Structure magnétique @5 06
C03 04  3  ENG  @0 Magnetic structure @5 06
C03 05  3  FRE  @0 Spectre Raman @5 07
C03 05  3  ENG  @0 Raman spectra @5 07
C03 06  3  FRE  @0 Ferromagnétisme faible @5 08
C03 06  3  ENG  @0 Weak ferromagnetism @5 08
C03 07  3  FRE  @0 Transition magnétique @5 09
C03 07  3  ENG  @0 Magnetic transitions @5 09
C03 08  3  FRE  @0 Structure cristalline @5 10
C03 08  3  ENG  @0 Crystal structure @5 10
C03 09  3  FRE  @0 Antiferromagnétisme @5 11
C03 09  3  ENG  @0 Antiferromagnetism @5 11
C03 10  X  FRE  @0 Structure delafossite @5 12
C03 10  X  ENG  @0 Delafossite structure @5 12
C03 10  X  SPA  @0 Estructura delafossite @5 12
C03 11  X  FRE  @0 Chrome Cuivre Oxyde Mixte @2 NC @2 NA @5 13
C03 11  X  ENG  @0 Chromium Copper Oxides Mixed @2 NC @2 NA @5 13
C03 11  X  SPA  @0 Mixto @2 NC @2 NA @5 13
C03 12  3  FRE  @0 Addition cobalt @5 14
C03 12  3  ENG  @0 Cobalt additions @5 14
C03 13  3  FRE  @0 Semiconducteur semimagnétique @5 15
C03 13  3  ENG  @0 Semimagnetic semiconductors @5 15
C03 14  3  FRE  @0 Semiconducteur type p @5 17
C03 14  3  ENG  @0 p type semiconductor @5 17
C03 15  3  FRE  @0 CuCrO2 @4 INC @5 52
N21       @1 084

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Pascal:13-0110347

Le document en format XML

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Co
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O
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<title xml:lang="en" level="a">Synthesis, structural and magnetic studies of the CuCr
<sub>1-x</sub>
Co
<sub>x</sub>
O
<sub>2</sub>
delafossite oxide</title>
<author>
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<s3>TUN</s3>
<sZ>2 aut.</sZ>
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<name sortKey="Colin, C V" sort="Colin, C V" uniqKey="Colin C" first="C. V." last="Colin">C. V. Colin</name>
<affiliation wicri:level="1">
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<s1>Institut Néel, CNRS et Université Joseph Fourier, B.P. 166</s1>
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<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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</affiliation>
</author>
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<name sortKey="Strobel, P" sort="Strobel, P" uniqKey="Strobel P" first="P." last="Strobel">P. Strobel</name>
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<s1>Institut Néel, CNRS et Université Joseph Fourier, B.P. 166</s1>
<s2>38042 Grenoble</s2>
<s3>FRA</s3>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
</affiliation>
</author>
<author>
<name sortKey="Salah, A Ben" sort="Salah, A Ben" uniqKey="Salah A" first="A. Ben" last="Salah">A. Ben Salah</name>
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<sZ>5 aut.</sZ>
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<title level="j" type="main">Journal of magnetism and magnetic materials</title>
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<title level="j" type="main">Journal of magnetism and magnetic materials</title>
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<term>Antiferromagnetism</term>
<term>Chirality</term>
<term>Chromium Copper Oxides Mixed</term>
<term>Cobalt additions</term>
<term>Crystal structure</term>
<term>Delafossite structure</term>
<term>Impurities</term>
<term>Magnetic structure</term>
<term>Magnetic transitions</term>
<term>Magnetization</term>
<term>Raman spectra</term>
<term>Semimagnetic semiconductors</term>
<term>Weak ferromagnetism</term>
<term>p type semiconductor</term>
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<term>Chiralité</term>
<term>Aimantation</term>
<term>Impureté</term>
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<term>Spectre Raman</term>
<term>Ferromagnétisme faible</term>
<term>Transition magnétique</term>
<term>Structure cristalline</term>
<term>Antiferromagnétisme</term>
<term>Structure delafossite</term>
<term>Chrome Cuivre Oxyde Mixte</term>
<term>Addition cobalt</term>
<term>Semiconducteur semimagnétique</term>
<term>Semiconducteur type p</term>
<term>CuCrO2</term>
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<div type="abstract" xml:lang="en">We modulate the spin chirality and the magnetization in CuCrO
<sub>2</sub>
, by doping at Cr
<sup>3+</sup>
sites with magnetic ions of slightly different size. Structure and magnetic properties of delafossite oxide CuCr
<sub>1-x</sub>
Co
<sub>x</sub>
O
<sub>2</sub>
(0≤x≤0.06) have been investigated. With the substitution of magnetic Co
<sup>3+</sup>
for Cr
<sup>3+</sup>
(S=3/2), the antiferromagnetic (AF) transition becomes broader and the transition temperature increases. However, at low temperature, the magnetic data for CuCr, -
<sub>x</sub>
Co
<sub>x</sub>
O
<sub>2</sub>
shows evidence for weak ferromagnetism. Comparing the substitution effect of Co
<sup>3+</sup>
to those of other magnetic metal transition, magnetization around the AF transition does not seem to correlate with randomness and lattice parameter.</div>
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Co
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O
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<s0>We modulate the spin chirality and the magnetization in CuCrO
<sub>2</sub>
, by doping at Cr
<sup>3+</sup>
sites with magnetic ions of slightly different size. Structure and magnetic properties of delafossite oxide CuCr
<sub>1-x</sub>
Co
<sub>x</sub>
O
<sub>2</sub>
(0≤x≤0.06) have been investigated. With the substitution of magnetic Co
<sup>3+</sup>
for Cr
<sup>3+</sup>
(S=3/2), the antiferromagnetic (AF) transition becomes broader and the transition temperature increases. However, at low temperature, the magnetic data for CuCr, -
<sub>x</sub>
Co
<sub>x</sub>
O
<sub>2</sub>
shows evidence for weak ferromagnetism. Comparing the substitution effect of Co
<sup>3+</sup>
to those of other magnetic metal transition, magnetization around the AF transition does not seem to correlate with randomness and lattice parameter.</s0>
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<s5>02</s5>
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<s5>05</s5>
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<s5>06</s5>
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<s5>06</s5>
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<s5>07</s5>
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<s5>08</s5>
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<s5>08</s5>
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<s5>09</s5>
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<s0>Magnetic transitions</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Structure cristalline</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Crystal structure</s0>
<s5>10</s5>
</fC03>
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<s0>Antiferromagnétisme</s0>
<s5>11</s5>
</fC03>
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<s0>Antiferromagnetism</s0>
<s5>11</s5>
</fC03>
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<s0>Structure delafossite</s0>
<s5>12</s5>
</fC03>
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<s0>Delafossite structure</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Estructura delafossite</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Chrome Cuivre Oxyde Mixte</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Chromium Copper Oxides Mixed</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Mixto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Addition cobalt</s0>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Cobalt additions</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Semiconducteur semimagnétique</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Semimagnetic semiconductors</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Semiconducteur type p</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>p type semiconductor</s0>
<s5>17</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>CuCrO2</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fN21>
<s1>084</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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