CobaltMaghrebV1, PascalFrancis, Curation, bibRecord, 000231

Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4'-dimethyl-2,2'-bipyridine and azide

Identifieur interne : 000231 ( PascalFrancis/Curation ); précédent : 000230; suivant : 000232

Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4'-dimethyl-2,2'-bipyridine and azide

Auteurs : Asma Lehleh [Algérie] ; Adel Beghidja [Algérie] ; Chahrazed Beghidja [Algérie] ; Olivier Mentre [France] ; Richard Welter [France]

Source :

Comptes rendus. Chimie [ 1631-0748 ] ; 2011.

RBID : Pascal:11-0403162

Descripteurs français

Pascal (Inist)
- Synthèse, Structure cristalline, Coordinat organique, Décomposition thermique, Azoture, Bipyridyle, Thermogravimétrie, Cuivre II, Cobalt II, Manganèse II, Analyse thermique, Analyse thermique différentielle, Spectrométrie IR, Monocristal, Diffraction RX, Structure moléculaire, Liaison hydrogène, Complexe de métal de transition, Complexe de cobalt, Complexe de cuivre, Complexe de manganèse, Acide cystéique, 2,2p-Bipyridyle(4,4p-diméthyl).

English descriptors

KwdEn :
- Azides, Bipyridines, Cobalt II, Cobalt complex, Copper II, Copper complex, Crystalline structure, Differential thermal analysis, Hydrogen bond, Infrared spectrometry, Manganese II, Manganese complex, Molecular structure, Organic ligand, Single crystal, Synthesis, Thermal analysis, Thermal decomposition, Thermogravimetry, Transition element complexes, X ray diffraction.

Abstract

Three new transition metal complexes, [Cu(L-cyst)(dmbpy)(H₂O)] (1), [Mn(dmbpy)₂ (N₃)(Cl)] (2) and [Co(dmbpy)₃].[CoCl₄].Cl.7H₂O (3) with (L-cyst=L-cysteic acid, dmbpy = 4,4'-dimethyl-2,2'-bipyridine, N₃ = azide) have been synthesized and characterized by elemental analysis, thermal analysis (DTA/TGA), IR spectroscopy and single crystal X-ray diffraction (XRD). In the complex 1, the copper atoms are five-coordinated in a distorted square pyramidal site. It forms monomeric species, which are further connected into a three-dimensional supramolecular network through hydrogen bonding interactions. In the complex 2, the manganese atoms have a distorted octahedral environment with four nitrogen atoms of the two dmbpy, one nitrogen atom provided from azide ligand, the coordination sphere being completed by a chlorine atom. (2) is also a monomeric complex and the molecular structure of compound 2 is stabilized by non standard weak C-H...Cl hydrogen-bonds. The asymmetric unit of the complex 3 is built of two cobalt-containing fragments: the cationic [Co^II(dmbpy)₃]⁺² and the anionic (Co^IICl₄)^-2groups. The molecular structure of compound 3 is stabilized by hydrogen bonds via O-H...O, O-H...Cl and C-H...Cl interactions. The thermal decompositions for 1 and 3 in the temperature range 30-1000 °C has revealed that the Cu complex decomposes in three steps whereas Co complex decomposes in four steps and transforms into the corresponding metal oxide.

A01	`01`	`1`		`@0 1631-0748`
A05				`@2 14`
A06				`@2 5`
A08	`01`	`1`	`ENG`	`@1 Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4'-dimethyl-2,2'-bipyridine and azide`
A11	`01`	`1`		`@1 LEHLEH (Asma)`
A11	`02`	`1`		`@1 BEGHIDJA (Adel)`
A11	`03`	`1`		`@1 BEGHIDJA (Chahrazed)`
A11	`04`	`1`		`@1 MENTRE (Olivier)`
A11	`05`	`1`		`@1 WELTER (Richard)`
A14	`01`			`@1 Unité de recherche de chimie de l'environnement et moléculaire structurale (CHEMS), université Mentouri de Constantine, route Aïnelbey @2 25000 Constantine @3 DZA @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A14	`02`			`@1 Unité de catalyse et de chimie du solide, CNRS UMR 8181, université Lille Nord de France, ENSC Lille - UST Lille, BP 90108 @2 59652 Villeneuve d'Ascq @3 FRA @Z 4 aut.`
A14	`03`			`@1 UMR CNRS 7177, laboratoire DECOMET, universite de Strasbourg, 4, rue Blaise-Pascal @2 67070 Strasbourg @3 FRA @Z 5 aut.`
A20				`@1 462-470`
A21				`@1 2011`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 116BC1B @5 354000500141180070`
A44				`@0 0000 @1 © 2011 INIST-CNRS. All rights reserved.`
A45				`@0 61 ref.`
A47	`01`	`1`		`@0 11-0403162`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`2`		`@0 Comptes rendus. Chimie`
A66	`01`			`@0 FRA`
C01	`01`		`ENG`	@0 Three new transition metal complexes, [Cu(L-cyst)(dmbpy)(H₂O)] (1), [Mn(dmbpy)₂ (N₃)(Cl)] (2) and [Co(dmbpy)₃].[CoCl₄].Cl.7H₂O (3) with (L-cyst=L-cysteic acid, dmbpy = 4,4'-dimethyl-2,2'-bipyridine, N₃ = azide) have been synthesized and characterized by elemental analysis, thermal analysis (DTA/TGA), IR spectroscopy and single crystal X-ray diffraction (XRD). In the complex 1, the copper atoms are five-coordinated in a distorted square pyramidal site. It forms monomeric species, which are further connected into a three-dimensional supramolecular network through hydrogen bonding interactions. In the complex 2, the manganese atoms have a distorted octahedral environment with four nitrogen atoms of the two dmbpy, one nitrogen atom provided from azide ligand, the coordination sphere being completed by a chlorine atom. (2) is also a monomeric complex and the molecular structure of compound 2 is stabilized by non standard weak C-H...Cl hydrogen-bonds. The asymmetric unit of the complex 3 is built of two cobalt-containing fragments: the cationic [Co^II(dmbpy)₃]⁺² and the anionic (Co^IICl₄)^-2groups. The molecular structure of compound 3 is stabilized by hydrogen bonds via O-H...O, O-H...Cl and C-H...Cl interactions. The thermal decompositions for 1 and 3 in the temperature range 30-1000 °C has revealed that the Cu complex decomposes in three steps whereas Co complex decomposes in four steps and transforms into the corresponding metal oxide.
C02	`01`	`X`		`@0 001C02B04`
C03	`01`	`X`	`FRE`	`@0 Synthèse @5 01`
C03	`01`	`X`	`ENG`	`@0 Synthesis @5 01`
C03	`01`	`X`	`SPA`	`@0 Síntesis @5 01`
C03	`02`	`X`	`FRE`	`@0 Structure cristalline @5 02`
C03	`02`	`X`	`ENG`	`@0 Crystalline structure @5 02`
C03	`02`	`X`	`SPA`	`@0 Estructura cristalina @5 02`
C03	`03`	`X`	`FRE`	`@0 Coordinat organique @5 03`
C03	`03`	`X`	`ENG`	`@0 Organic ligand @5 03`
C03	`03`	`X`	`SPA`	`@0 Ligando orgánico @5 03`
C03	`04`	`X`	`FRE`	`@0 Décomposition thermique @5 04`
C03	`04`	`X`	`ENG`	`@0 Thermal decomposition @5 04`
C03	`04`	`X`	`SPA`	`@0 Descomposición térmica @5 04`
C03	`05`	`X`	`FRE`	`@0 Azoture @2 NA @5 06`
C03	`05`	`X`	`ENG`	`@0 Azides @2 NA @5 06`
C03	`05`	`X`	`SPA`	`@0 Azoturo @2 NA @5 06`
C03	`06`	`3`	`FRE`	`@0 Bipyridyle @2 NK @5 07`
C03	`06`	`3`	`ENG`	`@0 Bipyridines @2 NK @5 07`
C03	`07`	`X`	`FRE`	`@0 Thermogravimétrie @5 08`
C03	`07`	`X`	`ENG`	`@0 Thermogravimetry @5 08`
C03	`07`	`X`	`SPA`	`@0 Termogravimetría @5 08`
C03	`08`	`X`	`FRE`	`@0 Cuivre II @2 NC @5 09`
C03	`08`	`X`	`ENG`	`@0 Copper II @2 NC @5 09`
C03	`08`	`X`	`SPA`	`@0 Cobre II @2 NC @5 09`
C03	`09`	`X`	`FRE`	`@0 Cobalt II @2 NC @5 10`
C03	`09`	`X`	`ENG`	`@0 Cobalt II @2 NC @5 10`
C03	`09`	`X`	`SPA`	`@0 Cobalto II @2 NC @5 10`
C03	`10`	`X`	`FRE`	`@0 Manganèse II @2 NC @5 11`
C03	`10`	`X`	`ENG`	`@0 Manganese II @2 NC @5 11`
C03	`10`	`X`	`SPA`	`@0 Manganeso II @2 NC @5 11`
C03	`11`	`X`	`FRE`	`@0 Analyse thermique @5 12`
C03	`11`	`X`	`ENG`	`@0 Thermal analysis @5 12`
C03	`11`	`X`	`SPA`	`@0 Análisis térmico @5 12`
C03	`12`	`X`	`FRE`	`@0 Analyse thermique différentielle @5 13`
C03	`12`	`X`	`ENG`	`@0 Differential thermal analysis @5 13`
C03	`12`	`X`	`SPA`	`@0 Análisis térmico diferencial @5 13`
C03	`13`	`X`	`FRE`	`@0 Spectrométrie IR @5 14`
C03	`13`	`X`	`ENG`	`@0 Infrared spectrometry @5 14`
C03	`13`	`X`	`SPA`	`@0 Espectrometría IR @5 14`
C03	`14`	`X`	`FRE`	`@0 Monocristal @5 15`
C03	`14`	`X`	`ENG`	`@0 Single crystal @5 15`
C03	`14`	`X`	`SPA`	`@0 Monocristal @5 15`
C03	`15`	`X`	`FRE`	`@0 Diffraction RX @5 16`
C03	`15`	`X`	`ENG`	`@0 X ray diffraction @5 16`
C03	`15`	`X`	`SPA`	`@0 Difracción RX @5 16`
C03	`16`	`X`	`FRE`	`@0 Structure moléculaire @5 22`
C03	`16`	`X`	`ENG`	`@0 Molecular structure @5 22`
C03	`16`	`X`	`SPA`	`@0 Estructura molecular @5 22`
C03	`17`	`X`	`FRE`	`@0 Liaison hydrogène @5 23`
C03	`17`	`X`	`ENG`	`@0 Hydrogen bond @5 23`
C03	`17`	`X`	`SPA`	`@0 Enlace hidrógeno @5 23`
C03	`18`	`3`	`FRE`	`@0 Complexe de métal de transition @5 27`
C03	`18`	`3`	`ENG`	`@0 Transition element complexes @5 27`
C03	`19`	`X`	`FRE`	`@0 Complexe de cobalt @5 28`
C03	`19`	`X`	`ENG`	`@0 Cobalt complex @5 28`
C03	`19`	`X`	`SPA`	`@0 Cobalto complejo @5 28`
C03	`20`	`X`	`FRE`	`@0 Complexe de cuivre @5 29`
C03	`20`	`X`	`ENG`	`@0 Copper complex @5 29`
C03	`20`	`X`	`SPA`	`@0 Cobre complejo @5 29`
C03	`21`	`X`	`FRE`	`@0 Complexe de manganèse @5 30`
C03	`21`	`X`	`ENG`	`@0 Manganese complex @5 30`
C03	`21`	`X`	`SPA`	`@0 Manganeso complejo @5 30`
C03	`22`	`X`	`FRE`	`@0 Acide cystéique @4 INC @5 32`
C03	`23`	`X`	`FRE`	`@0 2,2p-Bipyridyle(4,4p-diméthyl) @4 INC @5 33`
N21				`@1 276`

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Le document en format XML

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<author><name sortKey="Lehleh, Asma" sort="Lehleh, Asma" uniqKey="Lehleh A" first="Asma" last="Lehleh">Asma Lehleh</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4'-dimethyl-2,2'-bipyridine and azide</title>
<author><name sortKey="Lehleh, Asma" sort="Lehleh, Asma" uniqKey="Lehleh A" first="Asma" last="Lehleh">Asma Lehleh</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Unité de recherche de chimie de l'environnement et moléculaire structurale (CHEMS), université Mentouri de Constantine, route Aïnelbey</s1>
<s2>25000 Constantine</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Algérie</country>
</affiliation>
</author>
<author><name sortKey="Beghidja, Adel" sort="Beghidja, Adel" uniqKey="Beghidja A" first="Adel" last="Beghidja">Adel Beghidja</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Unité de recherche de chimie de l'environnement et moléculaire structurale (CHEMS), université Mentouri de Constantine, route Aïnelbey</s1>
<s2>25000 Constantine</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Algérie</country>
</affiliation>
</author>
<author><name sortKey="Beghidja, Chahrazed" sort="Beghidja, Chahrazed" uniqKey="Beghidja C" first="Chahrazed" last="Beghidja">Chahrazed Beghidja</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Unité de recherche de chimie de l'environnement et moléculaire structurale (CHEMS), université Mentouri de Constantine, route Aïnelbey</s1>
<s2>25000 Constantine</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Algérie</country>
</affiliation>
</author>
<author><name sortKey="Mentre, Olivier" sort="Mentre, Olivier" uniqKey="Mentre O" first="Olivier" last="Mentre">Olivier Mentre</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Unité de catalyse et de chimie du solide, CNRS UMR 8181, université Lille Nord de France, ENSC Lille - UST Lille, BP 90108</s1>
<s2>59652 Villeneuve d'Ascq</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
</affiliation>
</author>
<author><name sortKey="Welter, Richard" sort="Welter, Richard" uniqKey="Welter R" first="Richard" last="Welter">Richard Welter</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>UMR CNRS 7177, laboratoire DECOMET, universite de Strasbourg, 4, rue Blaise-Pascal</s1>
<s2>67070 Strasbourg</s2>
<s3>FRA</s3>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Comptes rendus. Chimie</title>
<idno type="ISSN">1631-0748</idno>
<imprint><date when="2011">2011</date>
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<idno type="ISSN">1631-0748</idno>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Azides</term>
<term>Bipyridines</term>
<term>Cobalt II</term>
<term>Cobalt complex</term>
<term>Copper II</term>
<term>Copper complex</term>
<term>Crystalline structure</term>
<term>Differential thermal analysis</term>
<term>Hydrogen bond</term>
<term>Infrared spectrometry</term>
<term>Manganese II</term>
<term>Manganese complex</term>
<term>Molecular structure</term>
<term>Organic ligand</term>
<term>Single crystal</term>
<term>Synthesis</term>
<term>Thermal analysis</term>
<term>Thermal decomposition</term>
<term>Thermogravimetry</term>
<term>Transition element complexes</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Synthèse</term>
<term>Structure cristalline</term>
<term>Coordinat organique</term>
<term>Décomposition thermique</term>
<term>Azoture</term>
<term>Bipyridyle</term>
<term>Thermogravimétrie</term>
<term>Cuivre II</term>
<term>Cobalt II</term>
<term>Manganèse II</term>
<term>Analyse thermique</term>
<term>Analyse thermique différentielle</term>
<term>Spectrométrie IR</term>
<term>Monocristal</term>
<term>Diffraction RX</term>
<term>Structure moléculaire</term>
<term>Liaison hydrogène</term>
<term>Complexe de métal de transition</term>
<term>Complexe de cobalt</term>
<term>Complexe de cuivre</term>
<term>Complexe de manganèse</term>
<term>Acide cystéique</term>
<term>2,2p-Bipyridyle(4,4p-diméthyl)</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Three new transition metal complexes, [Cu(L-cyst)(dmbpy)(H<sub>2</sub>
O)] (1), [Mn(dmbpy)<sub>2</sub>
 (N<sub>3</sub>
)(Cl)] (2) and [Co(dmbpy)<sub>3</sub>
].[CoCl<sub>4</sub>
].Cl.7H<sub>2</sub>
O (3) with (L-cyst=L-cysteic acid, dmbpy = 4,4'-dimethyl-2,2'-bipyridine, N<sub>3</sub>
 = azide) have been synthesized and characterized by elemental analysis, thermal analysis (DTA/TGA), IR spectroscopy and single crystal X-ray diffraction (XRD). In the complex 1, the copper atoms are five-coordinated in a distorted square pyramidal site. It forms monomeric species, which are further connected into a three-dimensional supramolecular network through hydrogen bonding interactions. In the complex 2, the manganese atoms have a distorted octahedral environment with four nitrogen atoms of the two dmbpy, one nitrogen atom provided from azide ligand, the coordination sphere being completed by a chlorine atom. (2) is also a monomeric complex and the molecular structure of compound 2 is stabilized by non standard weak C-H...Cl hydrogen-bonds. The asymmetric unit of the complex 3 is built of two cobalt-containing fragments: the cationic [Co<sup>II</sup>
(dmbpy)<sub>3</sub>
]<sup>+2</sup>
 and the anionic (Co<sup>II</sup>
Cl<sub>4</sub>
)<sup>-2</sup>
groups. The molecular structure of compound 3 is stabilized by hydrogen bonds via O-H...O, O-H...Cl and C-H...Cl interactions. The thermal decompositions for 1 and 3 in the temperature range 30-1000 °C has revealed that the Cu complex decomposes in three steps whereas Co complex decomposes in four steps and transforms into the corresponding metal oxide.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4'-dimethyl-2,2'-bipyridine and azide</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>LEHLEH (Asma)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>BEGHIDJA (Adel)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>BEGHIDJA (Chahrazed)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>MENTRE (Olivier)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>WELTER (Richard)</s1>
</fA11>
<fA14 i1="01"><s1>Unité de recherche de chimie de l'environnement et moléculaire structurale (CHEMS), université Mentouri de Constantine, route Aïnelbey</s1>
<s2>25000 Constantine</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Unité de catalyse et de chimie du solide, CNRS UMR 8181, université Lille Nord de France, ENSC Lille - UST Lille, BP 90108</s1>
<s2>59652 Villeneuve d'Ascq</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>UMR CNRS 7177, laboratoire DECOMET, universite de Strasbourg, 4, rue Blaise-Pascal</s1>
<s2>67070 Strasbourg</s2>
<s3>FRA</s3>
<sZ>5 aut.</sZ>
</fA14>
<fA20><s1>462-470</s1>
</fA20>
<fA21><s1>2011</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>116BC1B</s2>
<s5>354000500141180070</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2011 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>61 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>11-0403162</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="2"><s0>Comptes rendus. Chimie</s0>
</fA64>
<fA66 i1="01"><s0>FRA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Three new transition metal complexes, [Cu(L-cyst)(dmbpy)(H<sub>2</sub>
O)] (1), [Mn(dmbpy)<sub>2</sub>
 (N<sub>3</sub>
)(Cl)] (2) and [Co(dmbpy)<sub>3</sub>
].[CoCl<sub>4</sub>
].Cl.7H<sub>2</sub>
O (3) with (L-cyst=L-cysteic acid, dmbpy = 4,4'-dimethyl-2,2'-bipyridine, N<sub>3</sub>
 = azide) have been synthesized and characterized by elemental analysis, thermal analysis (DTA/TGA), IR spectroscopy and single crystal X-ray diffraction (XRD). In the complex 1, the copper atoms are five-coordinated in a distorted square pyramidal site. It forms monomeric species, which are further connected into a three-dimensional supramolecular network through hydrogen bonding interactions. In the complex 2, the manganese atoms have a distorted octahedral environment with four nitrogen atoms of the two dmbpy, one nitrogen atom provided from azide ligand, the coordination sphere being completed by a chlorine atom. (2) is also a monomeric complex and the molecular structure of compound 2 is stabilized by non standard weak C-H...Cl hydrogen-bonds. The asymmetric unit of the complex 3 is built of two cobalt-containing fragments: the cationic [Co<sup>II</sup>
(dmbpy)<sub>3</sub>
]<sup>+2</sup>
 and the anionic (Co<sup>II</sup>
Cl<sub>4</sub>
)<sup>-2</sup>
groups. The molecular structure of compound 3 is stabilized by hydrogen bonds via O-H...O, O-H...Cl and C-H...Cl interactions. The thermal decompositions for 1 and 3 in the temperature range 30-1000 °C has revealed that the Cu complex decomposes in three steps whereas Co complex decomposes in four steps and transforms into the corresponding metal oxide.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C02B04</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Synthèse</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Synthesis</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Síntesis</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Structure cristalline</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Crystalline structure</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Estructura cristalina</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Coordinat organique</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Organic ligand</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Ligando orgánico</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Décomposition thermique</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Thermal decomposition</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Descomposición térmica</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Azoture</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Azides</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Azoturo</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Bipyridyle</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Bipyridines</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Thermogravimétrie</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Thermogravimetry</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Termogravimetría</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Cuivre II</s0>
<s2>NC</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Copper II</s0>
<s2>NC</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Cobre II</s0>
<s2>NC</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Cobalt II</s0>
<s2>NC</s2>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Cobalt II</s0>
<s2>NC</s2>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Cobalto II</s0>
<s2>NC</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Manganèse II</s0>
<s2>NC</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Manganese II</s0>
<s2>NC</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Manganeso II</s0>
<s2>NC</s2>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Analyse thermique</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Thermal analysis</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Análisis térmico</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Analyse thermique différentielle</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Differential thermal analysis</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Análisis térmico diferencial</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Spectrométrie IR</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Infrared spectrometry</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Espectrometría IR</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Monocristal</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Single crystal</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Monocristal</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Diffraction RX</s0>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>X ray diffraction</s0>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Difracción RX</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Structure moléculaire</s0>
<s5>22</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Molecular structure</s0>
<s5>22</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Estructura molecular</s0>
<s5>22</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Liaison hydrogène</s0>
<s5>23</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Hydrogen bond</s0>
<s5>23</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Enlace hidrógeno</s0>
<s5>23</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>Complexe de métal de transition</s0>
<s5>27</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG"><s0>Transition element complexes</s0>
<s5>27</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Complexe de cobalt</s0>
<s5>28</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Cobalt complex</s0>
<s5>28</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA"><s0>Cobalto complejo</s0>
<s5>28</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE"><s0>Complexe de cuivre</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG"><s0>Copper complex</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA"><s0>Cobre complejo</s0>
<s5>29</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE"><s0>Complexe de manganèse</s0>
<s5>30</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG"><s0>Manganese complex</s0>
<s5>30</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA"><s0>Manganeso complejo</s0>
<s5>30</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE"><s0>Acide cystéique</s0>
<s4>INC</s4>
<s5>32</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE"><s0>2,2p-Bipyridyle(4,4p-diméthyl)</s0>
<s4>INC</s4>
<s5>33</s5>
</fC03>
<fN21><s1>276</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4'-dimethyl-2,2'-bipyridine and azide

Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4'-dimethyl-2,2'-bipyridine and azide

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