CobaltMaghrebV1, PascalFrancis, Curation, bibRecord, 000160

Effects of support and metal loading on the characteristics of Co based catalysts for selective hydrogenation of citral

Identifieur interne : 000160 ( PascalFrancis/Curation ); précédent : 000159; suivant : 000161

Effects of support and metal loading on the characteristics of Co based catalysts for selective hydrogenation of citral

Auteurs : K. Kouachi [France, Algérie] ; G. Lafaye [France] ; C. Especel [France] ; O. Cherifi [Algérie] ; P. Mardcota [France]

Source :

Journal of molecular catalysis. A, Chemical [ 1381-1169 ] ; 2008.

RBID : Pascal:08-0229737

Descripteurs français

Pascal (Inist)
- Support, Monoxyde de carbone, Catalyseur, Hydrogénation, Citral, Cobalt, Silice, Alumine, Oxyde de titane, Catalyseur sur support, Catalyse hétérogène, Aldéhyde.
Wicri :
- topic : Cobalt.

English descriptors

KwdEn :
- Aldehyde, Alumina, Carbon monoxide, Catalyst, Citral, Cobalt, Heterogeneous catalysis, Hydrogenation, Silica, Support, Supported catalyst, Titanium oxide.

Abstract

Silica-, alumina- and titania-supported Co catalysts with different metal loadings were tested for selective citral hydrogenation in liquid phase. Temperature programmed desorption of hydrogen (H₂-TPD) indicated that the catalysts with the highest unsaturated alcohols selectivities present particular H-Co species. Electron diffraction and XRD measurements revealed that these species would be linked to the presence of Co⁰ hexagonal phase. According to the results obtained by TEM and cyclohexane dehydrogenation, these two properties would be present on large Co particles.

A01	`01`	`1`		`@0 1381-1169`
A03		`1`		`@0 J. mol. catal., A Chem.`
A05				`@2 280`
A06				`@2 1-2`
A08	`01`	`1`	`ENG`	`@1 Effects of support and metal loading on the characteristics of Co based catalysts for selective hydrogenation of citral`
A11	`01`	`1`		`@1 KOUACHI (K.)`
A11	`02`	`1`		`@1 LAFAYE (G.)`
A11	`03`	`1`		`@1 ESPECEL (C.)`
A11	`04`	`1`		`@1 CHERIFI (O.)`
A11	`05`	`1`		`@1 MARDCOTA (P.)`
A14	`01`			`@1 Université de Poitiers, Laboratoire de Catalyse en Chimie Organique, UMR 6503 @2 86022 Poitiers @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 5 aut.`
A14	`02`			`@1 Laboratoire de Chimie de Gaz Naturel, Faculté de Chimie, USTHB, BP 32 @2 16111 El Alia, Bab Ezzouar @3 DZA @Z 1 aut. @Z 4 aut.`
A20				`@1 52-60`
A21				`@1 2008`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 17107A @5 354000174594710090`
A44				`@0 0000 @1 © 2008 INIST-CNRS. All rights reserved.`
A45				`@0 58 ref.`
A47	`01`	`1`		`@0 08-0229737`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of molecular catalysis. A, Chemical`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 Silica-, alumina- and titania-supported Co catalysts with different metal loadings were tested for selective citral hydrogenation in liquid phase. Temperature programmed desorption of hydrogen (H₂-TPD) indicated that the catalysts with the highest unsaturated alcohols selectivities present particular H-Co species. Electron diffraction and XRD measurements revealed that these species would be linked to the presence of Co⁰ hexagonal phase. According to the results obtained by TEM and cyclohexane dehydrogenation, these two properties would be present on large Co particles.
C02	`01`	`X`		`@0 001C01A03`
C03	`01`	`X`	`FRE`	`@0 Support @5 01`
C03	`01`	`X`	`ENG`	`@0 Support @5 01`
C03	`01`	`X`	`SPA`	`@0 Soporte @5 01`
C03	`02`	`X`	`FRE`	`@0 Monoxyde de carbone @2 NK @2 FX @5 02`
C03	`02`	`X`	`ENG`	`@0 Carbon monoxide @2 NK @2 FX @5 02`
C03	`02`	`X`	`SPA`	`@0 Carbono monóxido @2 NK @2 FX @5 02`
C03	`03`	`X`	`FRE`	`@0 Catalyseur @5 03`
C03	`03`	`X`	`ENG`	`@0 Catalyst @5 03`
C03	`03`	`X`	`SPA`	`@0 Catalizador @5 03`
C03	`04`	`X`	`FRE`	`@0 Hydrogénation @5 04`
C03	`04`	`X`	`ENG`	`@0 Hydrogenation @5 04`
C03	`04`	`X`	`SPA`	`@0 Hidrogenación @5 04`
C03	`05`	`X`	`FRE`	`@0 Citral @2 NK @2 FR @5 05`
C03	`05`	`X`	`ENG`	`@0 Citral @2 NK @2 FR @5 05`
C03	`06`	`X`	`FRE`	`@0 Cobalt @2 NC @5 06`
C03	`06`	`X`	`ENG`	`@0 Cobalt @2 NC @5 06`
C03	`06`	`X`	`SPA`	`@0 Cobalto @2 NC @5 06`
C03	`07`	`X`	`FRE`	`@0 Silice @2 NK @2 FX @5 08`
C03	`07`	`X`	`ENG`	`@0 Silica @2 NK @2 FX @5 08`
C03	`07`	`X`	`SPA`	`@0 Sílice @2 NK @2 FX @5 08`
C03	`08`	`X`	`FRE`	`@0 Alumine @2 NK @5 09`
C03	`08`	`X`	`ENG`	`@0 Alumina @2 NK @5 09`
C03	`08`	`X`	`SPA`	`@0 Alúmina @2 NK @5 09`
C03	`09`	`X`	`FRE`	`@0 Oxyde de titane @5 10`
C03	`09`	`X`	`ENG`	`@0 Titanium oxide @5 10`
C03	`09`	`X`	`SPA`	`@0 Titanio óxido @5 10`
C03	`10`	`X`	`FRE`	`@0 Catalyseur sur support @5 11`
C03	`10`	`X`	`ENG`	`@0 Supported catalyst @5 11`
C03	`10`	`X`	`SPA`	`@0 Catalizador sobre soporte @5 11`
C03	`11`	`X`	`FRE`	`@0 Catalyse hétérogène @5 12`
C03	`11`	`X`	`ENG`	`@0 Heterogeneous catalysis @5 12`
C03	`11`	`X`	`SPA`	`@0 Catálisis heterogénea @5 12`
C03	`12`	`X`	`FRE`	`@0 Aldéhyde @5 13`
C03	`12`	`X`	`ENG`	`@0 Aldehyde @5 13`
C03	`12`	`X`	`SPA`	`@0 Aldehído @5 13`
C07	`01`	`X`	`FRE`	`@0 Métal transition @2 NC @5 07`
C07	`01`	`X`	`ENG`	`@0 Transition metal @2 NC @5 07`
C07	`01`	`X`	`SPA`	`@0 Metal transición @2 NC @5 07`
N21				`@1 147`

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Le document en format XML

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<sZ>1 aut.</sZ>
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<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de Chimie de Gaz Naturel, Faculté de Chimie, USTHB, BP 32</s1>
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<s3>DZA</s3>
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<author><name sortKey="Lafaye, G" sort="Lafaye, G" uniqKey="Lafaye G" first="G." last="Lafaye">G. Lafaye</name>
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<s3>FRA</s3>
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<country>France</country>
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</author>
<author><name sortKey="Especel, C" sort="Especel, C" uniqKey="Especel C" first="C." last="Especel">C. Especel</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Université de Poitiers, Laboratoire de Catalyse en Chimie Organique, UMR 6503</s1>
<s2>86022 Poitiers</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
</affiliation>
</author>
<author><name sortKey="Cherifi, O" sort="Cherifi, O" uniqKey="Cherifi O" first="O." last="Cherifi">O. Cherifi</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de Chimie de Gaz Naturel, Faculté de Chimie, USTHB, BP 32</s1>
<s2>16111 El Alia, Bab Ezzouar</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Algérie</country>
</affiliation>
</author>
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<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
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<series><title level="j" type="main">Journal of molecular catalysis. A, Chemical</title>
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<imprint><date when="2008">2008</date>
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</biblStruct>
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<seriesStmt><title level="j" type="main">Journal of molecular catalysis. A, Chemical</title>
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<idno type="ISSN">1381-1169</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aldehyde</term>
<term>Alumina</term>
<term>Carbon monoxide</term>
<term>Catalyst</term>
<term>Citral</term>
<term>Cobalt</term>
<term>Heterogeneous catalysis</term>
<term>Hydrogenation</term>
<term>Silica</term>
<term>Support</term>
<term>Supported catalyst</term>
<term>Titanium oxide</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Support</term>
<term>Monoxyde de carbone</term>
<term>Catalyseur</term>
<term>Hydrogénation</term>
<term>Citral</term>
<term>Cobalt</term>
<term>Silice</term>
<term>Alumine</term>
<term>Oxyde de titane</term>
<term>Catalyseur sur support</term>
<term>Catalyse hétérogène</term>
<term>Aldéhyde</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Cobalt</term>
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<front><div type="abstract" xml:lang="en">Silica-, alumina- and titania-supported Co catalysts with different metal loadings were tested for selective citral hydrogenation in liquid phase. Temperature programmed desorption of hydrogen (H<sub>2</sub>
-TPD) indicated that the catalysts with the highest unsaturated alcohols selectivities present particular H-Co species. Electron diffraction and XRD measurements revealed that these species would be linked to the presence of Co<sup>0</sup>
 hexagonal phase. According to the results obtained by TEM and cyclohexane dehydrogenation, these two properties would be present on large Co particles.</div>
</front>
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<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1381-1169</s0>
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<fA03 i2="1"><s0>J. mol. catal., A Chem.</s0>
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</fA05>
<fA06><s2>1-2</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Effects of support and metal loading on the characteristics of Co based catalysts for selective hydrogenation of citral</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>KOUACHI (K.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>LAFAYE (G.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>ESPECEL (C.)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>CHERIFI (O.)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>MARDCOTA (P.)</s1>
</fA11>
<fA14 i1="01"><s1>Université de Poitiers, Laboratoire de Catalyse en Chimie Organique, UMR 6503</s1>
<s2>86022 Poitiers</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire de Chimie de Gaz Naturel, Faculté de Chimie, USTHB, BP 32</s1>
<s2>16111 El Alia, Bab Ezzouar</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA20><s1>52-60</s1>
</fA20>
<fA21><s1>2008</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>17107A</s2>
<s5>354000174594710090</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2008 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>58 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>08-0229737</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
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</fA61>
<fA64 i1="01" i2="1"><s0>Journal of molecular catalysis. A, Chemical</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Silica-, alumina- and titania-supported Co catalysts with different metal loadings were tested for selective citral hydrogenation in liquid phase. Temperature programmed desorption of hydrogen (H<sub>2</sub>
-TPD) indicated that the catalysts with the highest unsaturated alcohols selectivities present particular H-Co species. Electron diffraction and XRD measurements revealed that these species would be linked to the presence of Co<sup>0</sup>
 hexagonal phase. According to the results obtained by TEM and cyclohexane dehydrogenation, these two properties would be present on large Co particles.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C01A03</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Support</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Support</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Soporte</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Monoxyde de carbone</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Carbon monoxide</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Carbono monóxido</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Catalyseur</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Catalyst</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Catalizador</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Hydrogénation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Hydrogenation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Hidrogenación</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Citral</s0>
<s2>NK</s2>
<s2>FR</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Citral</s0>
<s2>NK</s2>
<s2>FR</s2>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Cobalt</s0>
<s2>NC</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Cobalt</s0>
<s2>NC</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Cobalto</s0>
<s2>NC</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Silice</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Silica</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Sílice</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Alumine</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Alumina</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Alúmina</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Oxyde de titane</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Titanium oxide</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Titanio óxido</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Catalyseur sur support</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Supported catalyst</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Catalizador sobre soporte</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Catalyse hétérogène</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Heterogeneous catalysis</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Catálisis heterogénea</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Aldéhyde</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Aldehyde</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Aldehído</s0>
<s5>13</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Métal transition</s0>
<s2>NC</s2>
<s5>07</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Transition metal</s0>
<s2>NC</s2>
<s5>07</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Metal transición</s0>
<s2>NC</s2>
<s5>07</s5>
</fC07>
<fN21><s1>147</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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	Serveur d'exploration sur le cobalt au Maghreb
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Effects of support and metal loading on the characteristics of Co based catalysts for selective hydrogenation of citral

Effects of support and metal loading on the characteristics of Co based catalysts for selective hydrogenation of citral

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