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Electrochemical kinetic parameters of a metal hydride battery electrode

Identifieur interne : 000149 ( PascalFrancis/Curation ); précédent : 000148; suivant : 000150

Electrochemical kinetic parameters of a metal hydride battery electrode

Auteurs : M. Tliha [Tunisie] ; H. Mathlouthi [Tunisie] ; J. Lamloumi [Tunisie] ; A. Percheron-Guegan [France]

Source :

RBID : Pascal:07-0305978

Descripteurs français

English descriptors

Abstract

The electrochemical properties of the LaNi3.55Mn0.4Al0.3Co0.4Fe0.35 electrode were investigated using the micropolarization measurements. The exchange current density, the polarization resistance, and the equilibrium potential were determined as a function of the state of charge (SOC) in the electrode. The micropolarization measurements indicated that the electrochemical kinetic property was improved with increasing SOC, due to the increase of the electrocatalytic activation of the surface and the increase of the hydrogen diffusivity in the alloy bulk.
pA  
A01 01  1    @0 0360-3199
A02 01      @0 IJHEDX
A03   1    @0 Int. j. hydrogen energy
A05       @2 32
A06       @2 5
A08 01  1  ENG  @1 Electrochemical kinetic parameters of a metal hydride battery electrode
A11 01  1    @1 TLIHA (M.)
A11 02  1    @1 MATHLOUTHI (H.)
A11 03  1    @1 LAMLOUMI (J.)
A11 04  1    @1 PERCHERON-GUEGAN (A.)
A14 01      @1 Laboratoire de Mécanique, Matériaux et Procédés, ESSTT, 5 Avenue Taha Hussein @2 1008 Tunis @3 TUN @Z 1 aut. @Z 2 aut. @Z 3 aut.
A14 02      @1 Laboratoire de Chimie Métallurgique des Terres Rares, GLVT, CNRS, 2-8 Rue Henri Dunant @2 94320 Thiais @3 FRA @Z 4 aut.
A20       @1 611-614
A21       @1 2007
A23 01      @0 ENG
A43 01      @1 INIST @2 17522 @5 354000145633900140
A44       @0 0000 @1 © 2007 INIST-CNRS. All rights reserved.
A45       @0 24 ref.
A47 01  1    @0 07-0305978
A60       @1 P
A61       @0 A
A64 01  1    @0 International journal of hydrogen energy
A66 01      @0 GBR
C01 01    ENG  @0 The electrochemical properties of the LaNi3.55Mn0.4Al0.3Co0.4Fe0.35 electrode were investigated using the micropolarization measurements. The exchange current density, the polarization resistance, and the equilibrium potential were determined as a function of the state of charge (SOC) in the electrode. The micropolarization measurements indicated that the electrochemical kinetic property was improved with increasing SOC, due to the increase of the electrocatalytic activation of the surface and the increase of the hydrogen diffusivity in the alloy bulk.
C02 01  X    @0 001D05I03E
C03 01  3  FRE  @0 Batterie électrique @5 05
C03 01  3  ENG  @0 Electric batteries @5 05
C03 02  X  FRE  @0 Métal Hydrure @2 NC @2 NA @5 06
C03 02  X  ENG  @0 Metal Hydrides @2 NC @2 NA @5 06
C03 02  X  SPA  @0 Metal Hidruro @2 NC @2 NA @5 06
C03 03  X  FRE  @0 Lanthane Nickel Manganèse Aluminium Cobalt Fer Hydrure @2 NC @2 FX @2 FR @2 NA @5 07
C03 03  X  ENG  @0 Lanthanum Nickel Manganese Aluminium Cobalt Iron Hydrides @2 NC @2 FX @2 FR @2 NA @5 07
C03 03  X  SPA  @0 Lantano Niquel Manganeso Aluminio Cobalto Hierro Hidruro @2 NC @2 FX @2 FR @2 NA @5 07
C03 04  X  FRE  @0 Propriété électrochimique @5 08
C03 04  X  ENG  @0 Electrochemical properties @5 08
C03 04  X  SPA  @0 Propiedad electroquímica @5 08
C03 05  X  FRE  @0 Mesure @5 09
C03 05  X  ENG  @0 Measurement @5 09
C03 05  X  SPA  @0 Medida @5 09
C03 06  X  FRE  @0 Densité courant @5 10
C03 06  X  ENG  @0 Current density @5 10
C03 06  X  SPA  @0 Densidad corriente @5 10
C03 07  X  FRE  @0 Potentiel équilibre @5 11
C03 07  X  ENG  @0 Equilibrium potential @5 11
C03 07  X  SPA  @0 Potencial equilibrio @5 11
C03 08  X  FRE  @0 Activation @5 12
C03 08  X  ENG  @0 Activation @5 12
C03 08  X  SPA  @0 Activación @5 12
C03 09  X  FRE  @0 Hydrogène @2 NC @5 13
C03 09  X  ENG  @0 Hydrogen @2 NC @5 13
C03 09  X  SPA  @0 Hidrógeno @2 NC @5 13
C03 10  X  FRE  @0 Etat charge @5 14
C03 10  X  ENG  @0 State of charge @5 14
C03 10  X  SPA  @0 Estado carga @5 14
C03 11  3  FRE  @0 Stockage hydrogène @5 15
C03 11  3  ENG  @0 Hydrogen storage @5 15
N21       @1 197

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<term>Hydrogen</term>
<term>Hydrogen storage</term>
<term>Lanthanum Nickel Manganese Aluminium Cobalt Iron Hydrides</term>
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<div type="abstract" xml:lang="en">The electrochemical properties of the LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.4</sub>
Fe
<sub>0.35</sub>
electrode were investigated using the micropolarization measurements. The exchange current density, the polarization resistance, and the equilibrium potential were determined as a function of the state of charge (SOC) in the electrode. The micropolarization measurements indicated that the electrochemical kinetic property was improved with increasing SOC, due to the increase of the electrocatalytic activation of the surface and the increase of the hydrogen diffusivity in the alloy bulk.</div>
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<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.4</sub>
Fe
<sub>0.35</sub>
electrode were investigated using the micropolarization measurements. The exchange current density, the polarization resistance, and the equilibrium potential were determined as a function of the state of charge (SOC) in the electrode. The micropolarization measurements indicated that the electrochemical kinetic property was improved with increasing SOC, due to the increase of the electrocatalytic activation of the surface and the increase of the hydrogen diffusivity in the alloy bulk.</s0>
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<s2>FX</s2>
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<s5>07</s5>
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<s2>FX</s2>
<s2>FR</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
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<s5>08</s5>
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<s5>10</s5>
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<s5>10</s5>
</fC03>
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<s0>Densidad corriente</s0>
<s5>10</s5>
</fC03>
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<s5>11</s5>
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<s5>11</s5>
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<s5>12</s5>
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<s0>Activation</s0>
<s5>12</s5>
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<s5>12</s5>
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<s5>13</s5>
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<s0>Hydrogen</s0>
<s2>NC</s2>
<s5>13</s5>
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<fC03 i1="09" i2="X" l="SPA">
<s0>Hidrógeno</s0>
<s2>NC</s2>
<s5>13</s5>
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<s0>Etat charge</s0>
<s5>14</s5>
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<s5>14</s5>
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<s5>14</s5>
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<s5>15</s5>
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