Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds
Identifieur interne :
000110 ( PascalFrancis/Curation );
précédent :
000109;
suivant :
000111
Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds
Auteurs : N. Amdouni [
France,
Tunisie] ;
H. Zarrouk [
Tunisie] ;
F. Soulette [
France] ;
C. Julien [
France]
Source :
-
Proceedings - Electrochemical society [ 0161-6374 ] ; 2003.
RBID : Pascal:05-0330155
Descripteurs français
English descriptors
Abstract
We present the electrochemical features behavior of LiAlyCo1-yO2 (0.0≤y≤0.3) electrodes prepared by "chimie douce" using the citrate route. The phase evolution was studied as a function of the aluminum substitution and the modification on the intercalation and deintercalation of Li ions. The overall electrochemical capacity of the LiAlyCo1-yO2 oxides have been reduced due to the sp metal substitution, however, a more stable charge-discharge cycling performances have been observed when electrodes are charged up to 4.3 V as compared to the performance of the native oxide. For such a cut-off voltage, the charge capacity of the Li//LiAl0.2Co0.8O2 cell is ca. 118 mAh/g. Kinetics characterized by the GITT method show enhancement of the chemical diffusion coefficients upon Al substitution in the LiAlyCo1-yO2 matrix.
pA |
A01 | 01 | 1 | | @0 0161-6374 |
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A05 | | | | @2 20 |
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A08 | 01 | 1 | ENG | @1 Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds |
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A09 | 01 | 1 | ENG | @1 New trends in intercalation compounds for energy storage conversion : Paris, 30 April - 2 May 2003 |
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A11 | 01 | 1 | | @1 AMDOUNI (N.) |
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A11 | 02 | 1 | | @1 ZARROUK (H.) |
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A11 | 03 | 1 | | @1 SOULETTE (F.) |
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A11 | 04 | 1 | | @1 JULIEN (C.) |
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A12 | 01 | 1 | | @1 ZAGHIB (K.) @9 ed. |
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A12 | 02 | 1 | | @1 JULIEN (C.M.) @9 ed. |
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A12 | 03 | 1 | | @1 PRAKASH (J.) @9 ed. |
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A14 | 01 | | | @1 LMDH, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86 @2 75252 Paris @3 FRA @Z 1 aut. @Z 3 aut. @Z 4 aut. |
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A14 | 02 | | | @1 LCM, Université de Tunis El Manar, Campus Universitaire @2 2092 El Manar II @3 TUN @Z 1 aut. @Z 2 aut. |
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A18 | 01 | 1 | | @1 Electrochemical Society. Battery Division @2 Pennington NJ @3 USA @9 patr. |
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A18 | 02 | 1 | | @1 Electrochemical Society. Energy Technology Division @2 Pennington NJ @3 USA @9 patr. |
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A20 | | | | @1 363-368 |
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A21 | | | | @1 2003 |
---|
A23 | 01 | | | @0 ENG |
---|
A26 | 01 | | | @0 1-56677-403-9 |
---|
A43 | 01 | | | @1 INIST @2 22195 @5 354000124436780440 |
---|
A44 | | | | @0 0000 @1 © 2005 INIST-CNRS. All rights reserved. |
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A45 | | | | @0 18 ref. |
---|
A47 | 01 | 1 | | @0 05-0330155 |
---|
A60 | | | | @1 P @2 C |
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A61 | | | | @0 A |
---|
A64 | 01 | 1 | | @0 Proceedings - Electrochemical society |
---|
A66 | 01 | | | @0 USA |
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C01 | 01 | | ENG | @0 We present the electrochemical features behavior of LiAlyCo1-yO2 (0.0≤y≤0.3) electrodes prepared by "chimie douce" using the citrate route. The phase evolution was studied as a function of the aluminum substitution and the modification on the intercalation and deintercalation of Li ions. The overall electrochemical capacity of the LiAlyCo1-yO2 oxides have been reduced due to the sp metal substitution, however, a more stable charge-discharge cycling performances have been observed when electrodes are charged up to 4.3 V as compared to the performance of the native oxide. For such a cut-off voltage, the charge capacity of the Li//LiAl0.2Co0.8O2 cell is ca. 118 mAh/g. Kinetics characterized by the GITT method show enhancement of the chemical diffusion coefficients upon Al substitution in the LiAlyCo1-yO2 matrix. |
---|
C02 | 01 | X | | @0 001D05I03E |
---|
C03 | 01 | 3 | FRE | @0 Batterie électrique @5 05 |
---|
C03 | 01 | 3 | ENG | @0 Electric batteries @5 05 |
---|
C03 | 02 | X | FRE | @0 Lithium ion @5 06 |
---|
C03 | 02 | X | ENG | @0 Lithium ion @5 06 |
---|
C03 | 02 | X | SPA | @0 Litio ión @5 06 |
---|
C03 | 03 | X | FRE | @0 Composé insertion @5 07 |
---|
C03 | 03 | X | ENG | @0 Intercalation compound @5 07 |
---|
C03 | 03 | X | SPA | @0 Compuesto inserción @5 07 |
---|
C03 | 04 | X | FRE | @0 Propriété électrochimique @5 08 |
---|
C03 | 04 | X | ENG | @0 Electrochemical properties @5 08 |
---|
C03 | 04 | X | SPA | @0 Propiedad electroquímica @5 08 |
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C03 | 05 | X | FRE | @0 Cathode @5 09 |
---|
C03 | 05 | X | ENG | @0 Cathode @5 09 |
---|
C03 | 05 | X | SPA | @0 Cátodo @5 09 |
---|
C03 | 06 | X | FRE | @0 Matériau électrode @5 10 |
---|
C03 | 06 | X | ENG | @0 Electrode material @5 10 |
---|
C03 | 06 | X | SPA | @0 Material electrodo @5 10 |
---|
C03 | 07 | X | FRE | @0 Lithium oxyde @5 11 |
---|
C03 | 07 | X | ENG | @0 Lithium oxide @5 11 |
---|
C03 | 07 | X | SPA | @0 Litio óxido @5 11 |
---|
C03 | 08 | X | FRE | @0 Aluminium oxyde @5 12 |
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C03 | 08 | X | ENG | @0 Aluminium oxide @5 12 |
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C03 | 08 | X | SPA | @0 Aluminio óxido @5 12 |
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C03 | 09 | X | FRE | @0 Cobalt oxyde @5 13 |
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C03 | 09 | X | ENG | @0 Cobalt oxide @5 13 |
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C03 | 09 | X | SPA | @0 Cobalto óxido @5 13 |
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N21 | | | | @1 234 |
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|
pR |
A30 | 01 | 1 | ENG | @1 International symposium on new trends in intercalation compounds for energy storage and conversion @3 Paris FRA @4 2003-04-30 |
---|
|
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Co<sub>1+y</sub>
O<sub>2</sub>
nano-structured intercalation compounds</title>
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<front><div type="abstract" xml:lang="en">We present the electrochemical features behavior of LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
(0.0≤y≤0.3) electrodes prepared by "chimie douce" using the citrate route. The phase evolution was studied as a function of the aluminum substitution and the modification on the intercalation and deintercalation of Li ions. The overall electrochemical capacity of the LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
oxides have been reduced due to the sp metal substitution, however, a more stable charge-discharge cycling performances have been observed when electrodes are charged up to 4.3 V as compared to the performance of the native oxide. For such a cut-off voltage, the charge capacity of the Li//LiAl<sub>0.2</sub>
Co<sub>0.8</sub>
O<sub>2</sub>
cell is ca. 118 mAh/g. Kinetics characterized by the GITT method show enhancement of the chemical diffusion coefficients upon Al substitution in the LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
matrix.</div>
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Co<sub>1+y</sub>
O<sub>2</sub>
nano-structured intercalation compounds</s1>
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<fA11 i1="02" i2="1"><s1>ZARROUK (H.)</s1>
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<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>We present the electrochemical features behavior of LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
(0.0≤y≤0.3) electrodes prepared by "chimie douce" using the citrate route. The phase evolution was studied as a function of the aluminum substitution and the modification on the intercalation and deintercalation of Li ions. The overall electrochemical capacity of the LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
oxides have been reduced due to the sp metal substitution, however, a more stable charge-discharge cycling performances have been observed when electrodes are charged up to 4.3 V as compared to the performance of the native oxide. For such a cut-off voltage, the charge capacity of the Li//LiAl<sub>0.2</sub>
Co<sub>0.8</sub>
O<sub>2</sub>
cell is ca. 118 mAh/g. Kinetics characterized by the GITT method show enhancement of the chemical diffusion coefficients upon Al substitution in the LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
matrix.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D05I03E</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Batterie électrique</s0>
<s5>05</s5>
</fC03>
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<s5>05</s5>
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<s5>06</s5>
</fC03>
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<s5>06</s5>
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<fC03 i1="02" i2="X" l="SPA"><s0>Litio ión</s0>
<s5>06</s5>
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<s5>07</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Intercalation compound</s0>
<s5>07</s5>
</fC03>
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<s5>07</s5>
</fC03>
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<s5>08</s5>
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<s5>08</s5>
</fC03>
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<s5>08</s5>
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<fC03 i1="05" i2="X" l="FRE"><s0>Cathode</s0>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Cathode</s0>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Cátodo</s0>
<s5>09</s5>
</fC03>
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<s5>10</s5>
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<s5>10</s5>
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<s5>10</s5>
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<s5>11</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Lithium oxide</s0>
<s5>11</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Litio óxido</s0>
<s5>11</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Aluminium oxyde</s0>
<s5>12</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Aluminium oxide</s0>
<s5>12</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Aluminio óxido</s0>
<s5>12</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Cobalt oxyde</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Cobalt oxide</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Cobalto óxido</s0>
<s5>13</s5>
</fC03>
<fN21><s1>234</s1>
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<pR><fA30 i1="01" i2="1" l="ENG"><s1>International symposium on new trends in intercalation compounds for energy storage and conversion</s1>
<s3>Paris FRA</s3>
<s4>2003-04-30</s4>
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|texte= Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds
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