Serveur d'exploration sur le cobalt au Maghreb

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Effect of partial substitution of co with Fe on the properties of LaNi3.55Mn0.4Al0.3Co0.75-xFex (x=0, 0.15, 0.55) alloys electrodes

Identifieur interne : 000075 ( PascalFrancis/Curation ); précédent : 000074; suivant : 000076

Effect of partial substitution of co with Fe on the properties of LaNi3.55Mn0.4Al0.3Co0.75-xFex (x=0, 0.15, 0.55) alloys electrodes

Auteurs : C. Khaldi [Tunisie] ; H. Mathlouthi [Tunisie] ; J. Lamloumi [Tunisie] ; A. Percheron-Guegan [France]

Source :

RBID : Pascal:03-0527740

Descripteurs français

English descriptors

Abstract

The effect of iron substitution on the electrochemical behaviour of LaNi3.55Mn0.4Al0.3Co0.75-xFex compounds (x=0, 0.15, 0.55) has been studied by chronopotentiometry and cyclic voltammetry techniques. The maximum capacity decreases linearly from 308 to 239 mAhg-1 when the iron content increases from 0 to 7.3 wt.% (x=0.55). This decrease can be explained by the corrosion of the alloy in the aqueous KOH electrolyte. In spite of this decrease and of the long time needed for the activation, a good stability of discharge capacity was observed in LaNi3.35Mn0.4Al0.3Co0.75-xFex compounds. The reversibility of the electrochemical redox reaction of LaNi3.55Mn0.4Al0.3Co0.75-xFex alloy electrodes has been observed in the alloys least rich in iron. The hydrogen diffusivity in LaNi3.55Mn0.4Al0.3Co0.75-xFex alloy electrodes decreases when increasing the iron content. The obtained values of the hydrogen diffusion coefficient DH, varies between 2.1×10-7 and 8.2×10-9 cm2s-1 depending on the iron content of the electrode.
pA  
A01 01  1    @0 0925-8388
A03   1    @0 J. alloys compd.
A05       @2 360
A08 01  1  ENG  @1 Effect of partial substitution of co with Fe on the properties of LaNi3.55Mn0.4Al0.3Co0.75-xFex (x=0, 0.15, 0.55) alloys electrodes
A11 01  1    @1 KHALDI (C.)
A11 02  1    @1 MATHLOUTHI (H.)
A11 03  1    @1 LAMLOUMI (J.)
A11 04  1    @1 PERCHERON-GUEGAN (A.)
A14 01      @1 L.M.M.P, ESSTT, 5 Avenue Taha Hussein @2 1008 Tunis @3 TUN @Z 1 aut. @Z 2 aut. @Z 3 aut.
A14 02      @1 L.C.M.T.R. G.L.T, CNRS, 2-8 Rue Henri Dunant @2 94320, Thiais @3 FRA @Z 4 aut.
A20       @1 266-271
A21       @1 2003
A23 01      @0 ENG
A43 01      @1 INIST @2 1151 @5 354000113392730450
A44       @0 0000 @1 © 2003 INIST-CNRS. All rights reserved.
A45       @0 12 ref.
A47 01  1    @0 03-0527740
A60       @1 P
A61       @0 A
A64 01  1    @0 Journal of alloys and compounds
A66 01      @0 CHE
C01 01    ENG  @0 The effect of iron substitution on the electrochemical behaviour of LaNi3.55Mn0.4Al0.3Co0.75-xFex compounds (x=0, 0.15, 0.55) has been studied by chronopotentiometry and cyclic voltammetry techniques. The maximum capacity decreases linearly from 308 to 239 mAhg-1 when the iron content increases from 0 to 7.3 wt.% (x=0.55). This decrease can be explained by the corrosion of the alloy in the aqueous KOH electrolyte. In spite of this decrease and of the long time needed for the activation, a good stability of discharge capacity was observed in LaNi3.35Mn0.4Al0.3Co0.75-xFex compounds. The reversibility of the electrochemical redox reaction of LaNi3.55Mn0.4Al0.3Co0.75-xFex alloy electrodes has been observed in the alloys least rich in iron. The hydrogen diffusivity in LaNi3.55Mn0.4Al0.3Co0.75-xFex alloy electrodes decreases when increasing the iron content. The obtained values of the hydrogen diffusion coefficient DH, varies between 2.1×10-7 and 8.2×10-9 cm2s-1 depending on the iron content of the electrode.
C02 01  X    @0 001C01H02
C02 02  X    @0 001C01H05
C03 01  X  FRE  @0 Voltammétrie cyclique @5 02
C03 01  X  ENG  @0 Cyclic voltammetry @5 02
C03 01  X  SPA  @0 Voltametría cíclica @5 02
C03 02  X  FRE  @0 Corrosion @5 03
C03 02  X  ENG  @0 Corrosion @5 03
C03 02  X  SPA  @0 Corrosión @5 03
C03 03  3  FRE  @0 Processus réversible @5 04
C03 03  3  ENG  @0 Reversible processes @5 04
C03 04  X  FRE  @0 Oxydoréduction @5 05
C03 04  X  ENG  @0 Oxidation reduction @5 05
C03 04  X  SPA  @0 Oxidación reducción @5 05
C03 05  X  FRE  @0 Etude expérimentale @5 06
C03 05  X  ENG  @0 Experimental study @5 06
C03 05  X  SPA  @0 Estudio experimental @5 06
C03 06  X  FRE  @0 Diffusivité @5 07
C03 06  X  ENG  @0 Diffusivity @5 07
C03 06  X  SPA  @0 Difusibilidad @5 07
C03 07  X  FRE  @0 Coefficient diffusion @5 08
C03 07  X  ENG  @0 Diffusion coefficient @5 08
C03 07  X  SPA  @0 Coeficiente difusión @5 08
C03 08  X  FRE  @0 Fer alliage @5 15
C03 08  X  ENG  @0 Iron alloy @5 15
C03 08  X  SPA  @0 Hierro aleación @5 15
C03 09  X  FRE  @0 Matériau électrode @5 16
C03 09  X  ENG  @0 Electrode material @5 16
C03 09  X  SPA  @0 Material electrodo @5 16
C03 10  X  FRE  @0 Cobalt alliage @5 17
C03 10  X  ENG  @0 Cobalt alloy @5 17
C03 10  X  SPA  @0 Cobalto aleación @5 17
C03 11  X  FRE  @0 Aluminium alliage @5 18
C03 11  X  ENG  @0 Aluminium alloy @5 18
C03 11  X  SPA  @0 Aluminio aleación @5 18
C03 12  X  FRE  @0 Manganèse alliage @5 19
C03 12  X  ENG  @0 Manganèse alloy @5 19
C03 12  X  SPA  @0 Manganeso aleación @5 19
C03 13  X  FRE  @0 Lanthane alliage @5 20
C03 13  X  ENG  @0 Lanthanum alloy @5 20
C03 13  X  SPA  @0 Lantano aleación @5 20
C03 14  X  FRE  @0 Nickel alliage @5 21
C03 14  X  ENG  @0 Nickel alloy @5 21
C03 14  X  SPA  @0 Níquel aleación @5 21
C03 15  X  FRE  @0 Alliage LaNiMnAlCoFe @4 INC @5 52
C03 16  X  FRE  @0 Al Co Fe La Mn Ni @4 INC @5 53
C03 17  X  FRE  @0 8245F @2 PAC @4 INC @5 56
C03 18  X  FRE  @0 8245A @2 PAC @4 INC @5 57
C07 01  X  FRE  @0 Composé minéral @5 48
C07 01  X  ENG  @0 Inorganic compound @5 48
C07 01  X  SPA  @0 Compuesto inorgánico @5 48
C07 02  X  FRE  @0 Métal transition alliage @5 49
C07 02  X  ENG  @0 Transition metal alloy @5 49
C07 02  X  SPA  @0 Metal transición aleación @5 49
C07 03  X  FRE  @0 Lanthanide alliage @5 50
C07 03  X  ENG  @0 Rare earth metal alloy @5 50
C07 03  X  SPA  @0 Lantánido aleación @5 50
N21       @1 349
N82       @1 PSI

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Pascal:03-0527740

Le document en format XML

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<title xml:lang="en" level="a">Effect of partial substitution of co with Fe on the properties of LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
(x=0, 0.15, 0.55) alloys electrodes</title>
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<term>Aluminium alloy</term>
<term>Cobalt alloy</term>
<term>Corrosion</term>
<term>Cyclic voltammetry</term>
<term>Diffusion coefficient</term>
<term>Diffusivity</term>
<term>Electrode material</term>
<term>Experimental study</term>
<term>Iron alloy</term>
<term>Lanthanum alloy</term>
<term>Manganèse alloy</term>
<term>Nickel alloy</term>
<term>Oxidation reduction</term>
<term>Reversible processes</term>
</keywords>
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<term>Voltammétrie cyclique</term>
<term>Corrosion</term>
<term>Processus réversible</term>
<term>Oxydoréduction</term>
<term>Etude expérimentale</term>
<term>Diffusivité</term>
<term>Coefficient diffusion</term>
<term>Fer alliage</term>
<term>Matériau électrode</term>
<term>Cobalt alliage</term>
<term>Aluminium alliage</term>
<term>Manganèse alliage</term>
<term>Lanthane alliage</term>
<term>Nickel alliage</term>
<term>Alliage LaNiMnAlCoFe</term>
<term>Al Co Fe La Mn Ni</term>
<term>8245F</term>
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<div type="abstract" xml:lang="en">The effect of iron substitution on the electrochemical behaviour of LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
compounds (x=0, 0.15, 0.55) has been studied by chronopotentiometry and cyclic voltammetry techniques. The maximum capacity decreases linearly from 308 to 239 mAhg
<sup>-1</sup>
when the iron content increases from 0 to 7.3 wt.% (x=0.55). This decrease can be explained by the corrosion of the alloy in the aqueous KOH electrolyte. In spite of this decrease and of the long time needed for the activation, a good stability of discharge capacity was observed in LaNi
<sub>3.35</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
compounds. The reversibility of the electrochemical redox reaction of LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
alloy electrodes has been observed in the alloys least rich in iron. The hydrogen diffusivity in LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
alloy electrodes decreases when increasing the iron content. The obtained values of the hydrogen diffusion coefficient D
<sub>H</sub>
, varies between 2.1×10
<sup>-7</sup>
and 8.2×10
<sup>-9</sup>
cm
<sup>2</sup>
s
<sup>-1</sup>
depending on the iron content of the electrode.</div>
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Mn
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Al
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<s0>The effect of iron substitution on the electrochemical behaviour of LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
compounds (x=0, 0.15, 0.55) has been studied by chronopotentiometry and cyclic voltammetry techniques. The maximum capacity decreases linearly from 308 to 239 mAhg
<sup>-1</sup>
when the iron content increases from 0 to 7.3 wt.% (x=0.55). This decrease can be explained by the corrosion of the alloy in the aqueous KOH electrolyte. In spite of this decrease and of the long time needed for the activation, a good stability of discharge capacity was observed in LaNi
<sub>3.35</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
compounds. The reversibility of the electrochemical redox reaction of LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
alloy electrodes has been observed in the alloys least rich in iron. The hydrogen diffusivity in LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.75-x</sub>
Fe
<sub>x</sub>
alloy electrodes decreases when increasing the iron content. The obtained values of the hydrogen diffusion coefficient D
<sub>H</sub>
, varies between 2.1×10
<sup>-7</sup>
and 8.2×10
<sup>-9</sup>
cm
<sup>2</sup>
s
<sup>-1</sup>
depending on the iron content of the electrode.</s0>
</fC01>
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<s5>02</s5>
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<s0>Cyclic voltammetry</s0>
<s5>02</s5>
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<s0>Voltametría cíclica</s0>
<s5>02</s5>
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<s0>Corrosion</s0>
<s5>03</s5>
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<s0>Corrosion</s0>
<s5>03</s5>
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<s0>Corrosión</s0>
<s5>03</s5>
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<s0>Processus réversible</s0>
<s5>04</s5>
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<s0>Reversible processes</s0>
<s5>04</s5>
</fC03>
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<s0>Oxydoréduction</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Oxidation reduction</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Oxidación reducción</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Etude expérimentale</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Experimental study</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Estudio experimental</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Diffusivité</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Diffusivity</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Difusibilidad</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Coefficient diffusion</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Diffusion coefficient</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Coeficiente difusión</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Fer alliage</s0>
<s5>15</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Iron alloy</s0>
<s5>15</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Hierro aleación</s0>
<s5>15</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Matériau électrode</s0>
<s5>16</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Electrode material</s0>
<s5>16</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Material electrodo</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Cobalt alliage</s0>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Cobalt alloy</s0>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Cobalto aleación</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Aluminium alliage</s0>
<s5>18</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Aluminium alloy</s0>
<s5>18</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Aluminio aleación</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Manganèse alliage</s0>
<s5>19</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Manganèse alloy</s0>
<s5>19</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Manganeso aleación</s0>
<s5>19</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Lanthane alliage</s0>
<s5>20</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Lanthanum alloy</s0>
<s5>20</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Lantano aleación</s0>
<s5>20</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Nickel alliage</s0>
<s5>21</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Nickel alloy</s0>
<s5>21</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Níquel aleación</s0>
<s5>21</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Alliage LaNiMnAlCoFe</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Al Co Fe La Mn Ni</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>8245F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>8245A</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Composé minéral</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Inorganic compound</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Compuesto inorgánico</s0>
<s5>48</s5>
</fC07>
<fC07 i1="02" i2="X" l="FRE">
<s0>Métal transition alliage</s0>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="X" l="ENG">
<s0>Transition metal alloy</s0>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="X" l="SPA">
<s0>Metal transición aleación</s0>
<s5>49</s5>
</fC07>
<fC07 i1="03" i2="X" l="FRE">
<s0>Lanthanide alliage</s0>
<s5>50</s5>
</fC07>
<fC07 i1="03" i2="X" l="ENG">
<s0>Rare earth metal alloy</s0>
<s5>50</s5>
</fC07>
<fC07 i1="03" i2="X" l="SPA">
<s0>Lantánido aleación</s0>
<s5>50</s5>
</fC07>
<fN21>
<s1>349</s1>
</fN21>
<fN82>
<s1>PSI</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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   |texte=   Effect of partial substitution of co with Fe on the properties of LaNi3.55Mn0.4Al0.3Co0.75-xFex (x=0, 0.15, 0.55) alloys electrodes
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