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Titania-supported cobalt and cobalt-phosphorus catalysts : Characterization and performances in ethane oxidative dehydrogenation

Identifieur interne : 000027 ( PascalFrancis/Curation ); précédent : 000026; suivant : 000028

Titania-supported cobalt and cobalt-phosphorus catalysts : Characterization and performances in ethane oxidative dehydrogenation

Auteurs : Younes Brik [Maroc, France] ; Mohamed Kacimi [Maroc] ; Mahfoud Ziyad [Maroc] ; Francois Bozon-Verduraz [France]

Source :

RBID : Pascal:01-0481834

Descripteurs français

English descriptors

Abstract

TiO2-supported Cobalt and cobalt-phosphorus catalysts prepared by impregnation are characterized by XRD, XPS, Laser Raman Spectroscopy (LRS), and Diffuse Reflectance Spectroscopy (DRS) and investigated in ethane oxidative dehydrogenation (ODH). At low cobalt loadings, the carrier is essentially covered by octahedral Co2+ ions, whereas at concentrations superior to 3.7 wt% formation of the Co3O4 spinel is observed. The best performance in ethane ODH is achieved at 550°C with the sample containing 7.6 wt% Co. The reaction begins with a conversion of 33% and a selectivity around 75%, then it decreases to reach after 150 min on stream a stationary state at 22% of conversion and 60% selectivity. This loss of 30% of the initial activity may be associated with a decrease of the specific surface area and the concomitant formation of CoTiO3 and Co2TiO4, as revealed by LRS, in situ DRS, and XPS analysis. The activity in ethane ODH seems to be mainly related to the presence of Co2+ ions octahedral sites. Addition of phosphorus to Co(7.6)/TiO2 catalysts results in the reduction of Co3+ ions and a growth of amorphous cobalt-phosphorus compounds which provoke a severe decrease of the catalyst performance.
pA  
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A06       @2 1
A08 01  1  ENG  @1 Titania-supported cobalt and cobalt-phosphorus catalysts : Characterization and performances in ethane oxidative dehydrogenation
A11 01  1    @1 BRIK (Younes)
A11 02  1    @1 KACIMI (Mohamed)
A11 03  1    @1 ZIYAD (Mahfoud)
A11 04  1    @1 BOZON-VERDURAZ (Francois)
A14 01      @1 Faculté des Sciences, Département de Chimie, Laboratoire de Physico-chimie des Matériaux et Catalyse, Avenue Ibn Battouta, B.P. 1017 @2 Rabat @3 MAR @Z 1 aut. @Z 2 aut. @Z 3 aut.
A14 02      @1 Laboratoire de Chimie des Matériaux Divisés et Catalyse, Université Paris 7-Denis Diderot, 2, place Jussieu @2 75251 Paris @3 FRA @Z 1 aut. @Z 4 aut.
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A21       @1 2001
A23 01      @0 ENG
A43 01      @1 INIST @2 9623 @5 354000099437060120
A44       @0 0000 @1 © 2001 INIST-CNRS. All rights reserved.
A45       @0 38 ref.
A47 01  1    @0 01-0481834
A60       @1 P
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A66 01      @0 USA
C01 01    ENG  @0 TiO2-supported Cobalt and cobalt-phosphorus catalysts prepared by impregnation are characterized by XRD, XPS, Laser Raman Spectroscopy (LRS), and Diffuse Reflectance Spectroscopy (DRS) and investigated in ethane oxidative dehydrogenation (ODH). At low cobalt loadings, the carrier is essentially covered by octahedral Co2+ ions, whereas at concentrations superior to 3.7 wt% formation of the Co3O4 spinel is observed. The best performance in ethane ODH is achieved at 550°C with the sample containing 7.6 wt% Co. The reaction begins with a conversion of 33% and a selectivity around 75%, then it decreases to reach after 150 min on stream a stationary state at 22% of conversion and 60% selectivity. This loss of 30% of the initial activity may be associated with a decrease of the specific surface area and the concomitant formation of CoTiO3 and Co2TiO4, as revealed by LRS, in situ DRS, and XPS analysis. The activity in ethane ODH seems to be mainly related to the presence of Co2+ ions octahedral sites. Addition of phosphorus to Co(7.6)/TiO2 catalysts results in the reduction of Co3+ ions and a growth of amorphous cobalt-phosphorus compounds which provoke a severe decrease of the catalyst performance.
C02 01  X    @0 001C01A03B
C03 01  X  FRE  @0 Réflexion diffuse @5 01
C03 01  X  ENG  @0 Diffuse reflection @5 01
C03 01  X  SPA  @0 Reflexión difusa @5 01
C03 02  X  FRE  @0 Spectre Raman @5 02
C03 02  X  ENG  @0 Raman spectrum @5 02
C03 02  X  SPA  @0 Espectro Raman @5 02
C03 03  X  FRE  @0 Diffraction RX @5 03
C03 03  X  ENG  @0 X ray diffraction @5 03
C03 03  X  SPA  @0 Difracción RX @5 03
C03 04  X  FRE  @0 Spectrométrie photoélectron @5 04
C03 04  X  ENG  @0 Photoelectron spectrometry @5 04
C03 04  X  SPA  @0 Espectrometría fotoelectrón @5 04
C03 05  X  FRE  @0 Imprégnation @5 09
C03 05  X  ENG  @0 Impregnation @5 09
C03 05  X  SPA  @0 Impregnación @5 09
C03 06  X  FRE  @0 Calcination @5 15
C03 06  X  ENG  @0 Calcining @5 15
C03 06  X  SPA  @0 Calcinación @5 15
C03 07  X  FRE  @0 Etude expérimentale @5 16
C03 07  X  ENG  @0 Experimental study @5 16
C03 07  X  SPA  @0 Estudio experimental @5 16
C03 08  X  FRE  @0 Catalyseur sur support @5 17
C03 08  X  ENG  @0 Supported catalyst @5 17
C03 08  X  SPA  @0 Catalizador sobre soporte @5 17
C03 09  X  FRE  @0 Cobalt @1 ACT @2 NC @5 19
C03 09  X  ENG  @0 Cobalt @1 ACT @2 NC @5 19
C03 09  X  SPA  @0 Cobalto @1 ACT @2 NC @5 19
C03 10  X  FRE  @0 Cobalt Phosphore @1 ACT @2 NC @5 20
C03 10  X  ENG  @0 Cobalt Phosphorus @1 ACT @2 NC @5 20
C03 10  X  SPA  @0 Cobalto Fósforo @1 ACT @2 NC @5 20
C03 11  X  FRE  @0 Préparation @5 21
C03 11  X  ENG  @0 Preparation @5 21
C03 11  X  SPA  @0 Preparación @5 21
C03 12  X  FRE  @0 Titane Oxyde @1 SUB @2 NC @2 NA @5 22
C03 12  X  ENG  @0 Titanium Oxides @1 SUB @2 NC @2 NA @5 22
C03 12  X  SPA  @0 Titanio Óxido @1 SUB @2 NC @2 NA @5 22
C03 13  X  FRE  @0 Réaction catalytique @5 23
C03 13  X  ENG  @0 Catalytic reaction @5 23
C03 13  X  SPA  @0 Reacción catalítica @5 23
C03 14  X  FRE  @0 Déshydrogénation @5 24
C03 14  X  ENG  @0 Dehydrogenation @5 24
C03 14  X  SPA  @0 Deshidrogenación @5 24
C03 15  X  FRE  @0 Oxydation @5 25
C03 15  X  ENG  @0 Oxidation @5 25
C03 15  X  SPA  @0 Oxidación @5 25
C03 16  X  FRE  @0 Ethane @1 ENT @2 NK @5 26
C03 16  X  ENG  @0 Ethane @1 ENT @2 NK @5 26
C03 16  X  SPA  @0 Etano @1 ENT @2 NK @5 26
C03 17  X  FRE  @0 Alcane @5 27
C03 17  X  ENG  @0 Alkane @5 27
C03 17  X  SPA  @0 Alcano @5 27
C03 18  X  FRE  @0 Hydrocarbure @2 FX @5 28
C03 18  X  ENG  @0 Hydrocarbon @2 FX @5 28
C03 18  X  SPA  @0 Hidrocarburo @2 FX @5 28
C03 19  X  FRE  @0 Activité catalytique @5 29
C03 19  X  ENG  @0 Catalyst activity @5 29
C03 19  X  SPA  @0 Actividad catalítica @5 29
C03 20  X  FRE  @0 Catalyse hétérogène @5 30
C03 20  X  ENG  @0 Heterogeneous catalysis @5 30
C03 20  X  SPA  @0 Catálisis heterogénea @5 30
C07 01  X  FRE  @0 Métal transition @2 NC @5 18
C07 01  X  ENG  @0 Transition metal @2 NC @5 18
C07 01  X  SPA  @0 Metal transición @2 NC @5 18
N21       @1 344

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<name sortKey="Ziyad, Mahfoud" sort="Ziyad, Mahfoud" uniqKey="Ziyad M" first="Mahfoud" last="Ziyad">Mahfoud Ziyad</name>
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<term>Alkane</term>
<term>Calcining</term>
<term>Catalyst activity</term>
<term>Catalytic reaction</term>
<term>Cobalt</term>
<term>Cobalt Phosphorus</term>
<term>Dehydrogenation</term>
<term>Diffuse reflection</term>
<term>Ethane</term>
<term>Experimental study</term>
<term>Heterogeneous catalysis</term>
<term>Hydrocarbon</term>
<term>Impregnation</term>
<term>Oxidation</term>
<term>Photoelectron spectrometry</term>
<term>Preparation</term>
<term>Raman spectrum</term>
<term>Supported catalyst</term>
<term>Titanium Oxides</term>
<term>X ray diffraction</term>
</keywords>
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<term>Réflexion diffuse</term>
<term>Spectre Raman</term>
<term>Diffraction RX</term>
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<term>Imprégnation</term>
<term>Calcination</term>
<term>Etude expérimentale</term>
<term>Catalyseur sur support</term>
<term>Cobalt</term>
<term>Cobalt Phosphore</term>
<term>Préparation</term>
<term>Titane Oxyde</term>
<term>Réaction catalytique</term>
<term>Déshydrogénation</term>
<term>Oxydation</term>
<term>Ethane</term>
<term>Alcane</term>
<term>Hydrocarbure</term>
<term>Activité catalytique</term>
<term>Catalyse hétérogène</term>
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<front>
<div type="abstract" xml:lang="en">TiO
<sub>2</sub>
-supported Cobalt and cobalt-phosphorus catalysts prepared by impregnation are characterized by XRD, XPS, Laser Raman Spectroscopy (LRS), and Diffuse Reflectance Spectroscopy (DRS) and investigated in ethane oxidative dehydrogenation (ODH). At low cobalt loadings, the carrier is essentially covered by octahedral Co
<sup>2+</sup>
ions, whereas at concentrations superior to 3.7 wt% formation of the Co
<sub>3</sub>
O
<sub>4</sub>
spinel is observed. The best performance in ethane ODH is achieved at 550°C with the sample containing 7.6 wt% Co. The reaction begins with a conversion of 33% and a selectivity around 75%, then it decreases to reach after 150 min on stream a stationary state at 22% of conversion and 60% selectivity. This loss of 30% of the initial activity may be associated with a decrease of the specific surface area and the concomitant formation of CoTiO
<sub>3</sub>
and Co
<sub>2</sub>
TiO
<sub>4</sub>
, as revealed by LRS, in situ DRS, and XPS analysis. The activity in ethane ODH seems to be mainly related to the presence of Co
<sup>2+</sup>
ions octahedral sites. Addition of phosphorus to Co(7.6)/TiO
<sub>2</sub>
catalysts results in the reduction of Co
<sup>3+</sup>
ions and a growth of amorphous cobalt-phosphorus compounds which provoke a severe decrease of the catalyst performance.</div>
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<fC01 i1="01" l="ENG">
<s0>TiO
<sub>2</sub>
-supported Cobalt and cobalt-phosphorus catalysts prepared by impregnation are characterized by XRD, XPS, Laser Raman Spectroscopy (LRS), and Diffuse Reflectance Spectroscopy (DRS) and investigated in ethane oxidative dehydrogenation (ODH). At low cobalt loadings, the carrier is essentially covered by octahedral Co
<sup>2+</sup>
ions, whereas at concentrations superior to 3.7 wt% formation of the Co
<sub>3</sub>
O
<sub>4</sub>
spinel is observed. The best performance in ethane ODH is achieved at 550°C with the sample containing 7.6 wt% Co. The reaction begins with a conversion of 33% and a selectivity around 75%, then it decreases to reach after 150 min on stream a stationary state at 22% of conversion and 60% selectivity. This loss of 30% of the initial activity may be associated with a decrease of the specific surface area and the concomitant formation of CoTiO
<sub>3</sub>
and Co
<sub>2</sub>
TiO
<sub>4</sub>
, as revealed by LRS, in situ DRS, and XPS analysis. The activity in ethane ODH seems to be mainly related to the presence of Co
<sup>2+</sup>
ions octahedral sites. Addition of phosphorus to Co(7.6)/TiO
<sub>2</sub>
catalysts results in the reduction of Co
<sup>3+</sup>
ions and a growth of amorphous cobalt-phosphorus compounds which provoke a severe decrease of the catalyst performance.</s0>
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<fC03 i1="01" i2="X" l="SPA">
<s0>Reflexión difusa</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE">
<s0>Spectre Raman</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG">
<s0>Raman spectrum</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA">
<s0>Espectro Raman</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE">
<s0>Diffraction RX</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG">
<s0>X ray diffraction</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Difracción RX</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Spectrométrie photoélectron</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Photoelectron spectrometry</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Espectrometría fotoelectrón</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Imprégnation</s0>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Impregnation</s0>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Impregnación</s0>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Calcination</s0>
<s5>15</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Calcining</s0>
<s5>15</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Calcinación</s0>
<s5>15</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Etude expérimentale</s0>
<s5>16</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Experimental study</s0>
<s5>16</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Estudio experimental</s0>
<s5>16</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Catalyseur sur support</s0>
<s5>17</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Supported catalyst</s0>
<s5>17</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Catalizador sobre soporte</s0>
<s5>17</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Cobalt</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Cobalt</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Cobalto</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Cobalt Phosphore</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s5>20</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Cobalt Phosphorus</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s5>20</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Cobalto Fósforo</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s5>20</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Préparation</s0>
<s5>21</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Preparation</s0>
<s5>21</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Preparación</s0>
<s5>21</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Titane Oxyde</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>22</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Titanium Oxides</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>22</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Titanio Óxido</s0>
<s1>SUB</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>22</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Réaction catalytique</s0>
<s5>23</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Catalytic reaction</s0>
<s5>23</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Reacción catalítica</s0>
<s5>23</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Déshydrogénation</s0>
<s5>24</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Dehydrogenation</s0>
<s5>24</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Deshidrogenación</s0>
<s5>24</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Oxydation</s0>
<s5>25</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Oxidation</s0>
<s5>25</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>Oxidación</s0>
<s5>25</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Ethane</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s5>26</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Ethane</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s5>26</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Etano</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s5>26</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Alcane</s0>
<s5>27</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Alkane</s0>
<s5>27</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Alcano</s0>
<s5>27</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Hydrocarbure</s0>
<s2>FX</s2>
<s5>28</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG">
<s0>Hydrocarbon</s0>
<s2>FX</s2>
<s5>28</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA">
<s0>Hidrocarburo</s0>
<s2>FX</s2>
<s5>28</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Activité catalytique</s0>
<s5>29</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Catalyst activity</s0>
<s5>29</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Actividad catalítica</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Catalyse hétérogène</s0>
<s5>30</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Heterogeneous catalysis</s0>
<s5>30</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA">
<s0>Catálisis heterogénea</s0>
<s5>30</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Métal transition</s0>
<s2>NC</s2>
<s5>18</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Transition metal</s0>
<s2>NC</s2>
<s5>18</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Metal transición</s0>
<s2>NC</s2>
<s5>18</s5>
</fC07>
<fN21>
<s1>344</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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