Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate
Identifieur interne : 000342 ( PascalFrancis/Corpus ); précédent : 000341; suivant : 000343Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate
Auteurs : F. Erragh ; A. Boukhari ; E. M. HoltSource :
- Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 1996.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
Isotypic lithium dicobalt triphosphate, LiCo2P3O10, and lithium dinickel triphosphate, LiNi2P3O10, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P3O5-10 groups are situated on a mirror plane, with successive PO3 moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co2+ and Ni2+ ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.
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Pour connaître la documentation sur le format Inist Standard.
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Format Inist (serveur)
NO : | PASCAL 96-0410568 INIST |
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ET : | Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate |
AU : | ERRAGH (F.); BOUKHARI (A.); HOLT (E. M.) |
AF : | Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta/Rabat/Maroc (1 aut., 2 aut.); Laboratoire de Chimie Physique de Matériaux, Département de Chimie, Faculté des Sciences/El Jadida/Maroc (1 aut.); Department of Chemistry, Oklahoma State University/Stillwater, Oklahoma 74078/Etats-Unis (3 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Danemark; Da. 1996; Vol. 52; No. p.8; Pp. 1867-1869; Bibl. 15 ref. |
LA : | Anglais |
EA : | Isotypic lithium dicobalt triphosphate, LiCo2P3O10, and lithium dinickel triphosphate, LiNi2P3O10, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P3O5-10 groups are situated on a mirror plane, with successive PO3 moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co2+ and Ni2+ ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms. |
CC : | 001B60A66F4 |
FD : | Etude expérimentale; XRD; Structure cristalline; Composé quaternaire; Lithium Triphosphate; Cobalt Triphosphate; Nickel Triphosphate; Li Ni O P; 6166F; LiCo2P3O10; Cio Li O P; LiNi2P3O10 |
FG : | Métal transition composé; Composé minéral |
ED : | Experimental study; XRD; Crystal structure; Quaternary compounds; Lithium Triphosphates; Cobalt Triphosphates; Nickel Triphosphates |
EG : | Transition element compounds; Inorganic compounds |
SD : | Trifosfato; Trifosfato; Trifosfato |
LO : | INIST-5160C.354000064047280040 |
ID : | 96-0410568 |
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Pascal:96-0410568Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate</title>
<author><name sortKey="Erragh, F" sort="Erragh, F" uniqKey="Erragh F" first="F." last="Erragh">F. Erragh</name>
<affiliation><inist:fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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</affiliation>
<affiliation><inist:fA14 i1="02"><s1>Laboratoire de Chimie Physique de Matériaux, Département de Chimie, Faculté des Sciences</s1>
<s2>El Jadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
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<author><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
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<author><name sortKey="Holt, E M" sort="Holt, E M" uniqKey="Holt E" first="E. M." last="Holt">E. M. Holt</name>
<affiliation><inist:fA14 i1="03"><s1>Department of Chemistry, Oklahoma State University</s1>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate</title>
<author><name sortKey="Erragh, F" sort="Erragh, F" uniqKey="Erragh F" first="F." last="Erragh">F. Erragh</name>
<affiliation><inist:fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
<affiliation><inist:fA14 i1="02"><s1>Laboratoire de Chimie Physique de Matériaux, Département de Chimie, Faculté des Sciences</s1>
<s2>El Jadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
<affiliation><inist:fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta</s1>
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<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<author><name sortKey="Holt, E M" sort="Holt, E M" uniqKey="Holt E" first="E. M." last="Holt">E. M. Holt</name>
<affiliation><inist:fA14 i1="03"><s1>Department of Chemistry, Oklahoma State University</s1>
<s2>Stillwater, Oklahoma 74078</s2>
<s3>USA</s3>
<sZ>3 aut.</sZ>
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<series><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
<imprint><date when="1996">1996</date>
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<seriesStmt><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
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<idno type="ISSN">0108-2701</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt Triphosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Lithium Triphosphates</term>
<term>Nickel Triphosphates</term>
<term>Quaternary compounds</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>XRD</term>
<term>Structure cristalline</term>
<term>Composé quaternaire</term>
<term>Lithium Triphosphate</term>
<term>Cobalt Triphosphate</term>
<term>Nickel Triphosphate</term>
<term>Li Ni O P</term>
<term>6166F</term>
<term>LiCo2P3O10</term>
<term>Cio Li O P</term>
<term>LiNi2P3O10</term>
</keywords>
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<front><div type="abstract" xml:lang="en">Isotypic lithium dicobalt triphosphate, LiCo<sub>2</sub>
P<sub>3</sub>
O<sub>10</sub>
, and lithium dinickel triphosphate, LiNi<sub>2</sub>
P<sub>3</sub>
O<sub>10</sub>
, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P<sub>3</sub>
O<sup>5-</sup>
<sub>10</sub>
groups are situated on a mirror plane, with successive PO<sub>3</sub>
moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co<sup>2+</sup>
and Ni<sup>2+</sup>
ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.</div>
</front>
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<fA05><s2>52</s2>
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<fA06><s3>p.8</s3>
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<fA08 i1="01" i2="1" l="ENG"><s1>Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate</s1>
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<fA11 i1="01" i2="1"><s1>ERRAGH (F.)</s1>
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<fA11 i1="02" i2="1"><s1>BOUKHARI (A.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>HOLT (E. M.)</s1>
</fA11>
<fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire de Chimie Physique de Matériaux, Département de Chimie, Faculté des Sciences</s1>
<s2>El Jadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Department of Chemistry, Oklahoma State University</s1>
<s2>Stillwater, Oklahoma 74078</s2>
<s3>USA</s3>
<sZ>3 aut.</sZ>
</fA14>
<fA20><s1>1867-1869</s1>
</fA20>
<fA21><s1>1996</s1>
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<fA23 i1="01"><s0>ENG</s0>
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<fA43 i1="01"><s1>INIST</s1>
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<fA44><s0>0000</s0>
<s1>© 1996 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>15 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>96-0410568</s0>
</fA47>
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</fA60>
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</fA64>
<fA66 i1="01"><s0>DNK</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Isotypic lithium dicobalt triphosphate, LiCo<sub>2</sub>
P<sub>3</sub>
O<sub>10</sub>
, and lithium dinickel triphosphate, LiNi<sub>2</sub>
P<sub>3</sub>
O<sub>10</sub>
, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P<sub>3</sub>
O<sup>5-</sup>
<sub>10</sub>
groups are situated on a mirror plane, with successive PO<sub>3</sub>
moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co<sup>2+</sup>
and Ni<sup>2+</sup>
ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F4</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Composé quaternaire</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Quaternary compounds</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Lithium Triphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Lithium Triphosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Trifosfato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Cobalt Triphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Cobalt Triphosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Trifosfato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Nickel Triphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Nickel Triphosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Trifosfato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Li Ni O P</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>LiCo2P3O10</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Cio Li O P</s0>
<s4>INC</s4>
<s5>94</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>LiNi2P3O10</s0>
<s4>INC</s4>
<s5>95</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>16</s5>
</fC07>
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<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>17</s5>
</fC07>
<fN21><s1>281</s1>
</fN21>
</pA>
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<server><NO>PASCAL 96-0410568 INIST</NO>
<ET>Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate</ET>
<AU>ERRAGH (F.); BOUKHARI (A.); HOLT (E. M.)</AU>
<AF>Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta/Rabat/Maroc (1 aut., 2 aut.); Laboratoire de Chimie Physique de Matériaux, Département de Chimie, Faculté des Sciences/El Jadida/Maroc (1 aut.); Department of Chemistry, Oklahoma State University/Stillwater, Oklahoma 74078/Etats-Unis (3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Danemark; Da. 1996; Vol. 52; No. p.8; Pp. 1867-1869; Bibl. 15 ref.</SO>
<LA>Anglais</LA>
<EA>Isotypic lithium dicobalt triphosphate, LiCo<sub>2</sub>
P<sub>3</sub>
O<sub>10</sub>
, and lithium dinickel triphosphate, LiNi<sub>2</sub>
P<sub>3</sub>
O<sub>10</sub>
, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P<sub>3</sub>
O<sup>5-</sup>
<sub>10</sub>
groups are situated on a mirror plane, with successive PO<sub>3</sub>
moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co<sup>2+</sup>
and Ni<sup>2+</sup>
ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.</EA>
<CC>001B60A66F4</CC>
<FD>Etude expérimentale; XRD; Structure cristalline; Composé quaternaire; Lithium Triphosphate; Cobalt Triphosphate; Nickel Triphosphate; Li Ni O P; 6166F; LiCo2P3O10; Cio Li O P; LiNi2P3O10</FD>
<FG>Métal transition composé; Composé minéral</FG>
<ED>Experimental study; XRD; Crystal structure; Quaternary compounds; Lithium Triphosphates; Cobalt Triphosphates; Nickel Triphosphates</ED>
<EG>Transition element compounds; Inorganic compounds</EG>
<SD>Trifosfato; Trifosfato; Trifosfato</SD>
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<ID>96-0410568</ID>
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