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Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate

Identifieur interne : 000342 ( PascalFrancis/Corpus ); précédent : 000341; suivant : 000343

Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate

Auteurs : F. Erragh ; A. Boukhari ; E. M. Holt

Source :

RBID : Pascal:96-0410568

Descripteurs français

English descriptors

Abstract

Isotypic lithium dicobalt triphosphate, LiCo2P3O10, and lithium dinickel triphosphate, LiNi2P3O10, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P3O5-10 groups are situated on a mirror plane, with successive PO3 moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co2+ and Ni2+ ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0108-2701
A02 01      @0 ACSCEE
A03   1    @0 Acta crystallogr., Sect. C Cryst. struct. commun.
A05       @2 52
A06       @3 p.8
A08 01  1  ENG  @1 Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate
A11 01  1    @1 ERRAGH (F.)
A11 02  1    @1 BOUKHARI (A.)
A11 03  1    @1 HOLT (E. M.)
A14 01      @1 Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta @2 Rabat @3 MAR @Z 1 aut. @Z 2 aut.
A14 02      @1 Laboratoire de Chimie Physique de Matériaux, Département de Chimie, Faculté des Sciences @2 El Jadida @3 MAR @Z 1 aut.
A14 03      @1 Department of Chemistry, Oklahoma State University @2 Stillwater, Oklahoma 74078 @3 USA @Z 3 aut.
A20       @1 1867-1869
A21       @1 1996
A23 01      @0 ENG
A43 01      @1 INIST @2 5160C @5 354000064047280040
A44       @0 0000 @1 © 1996 INIST-CNRS. All rights reserved.
A45       @0 15 ref.
A47 01  1    @0 96-0410568
A60       @1 P
A61       @0 A
A64 01  1    @0 Acta crystallographica. Section C, Crystal structure communications
A66 01      @0 DNK
C01 01    ENG  @0 Isotypic lithium dicobalt triphosphate, LiCo2P3O10, and lithium dinickel triphosphate, LiNi2P3O10, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P3O5-10 groups are situated on a mirror plane, with successive PO3 moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co2+ and Ni2+ ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.
C02 01  3    @0 001B60A66F4
C03 01  3  FRE  @0 Etude expérimentale @5 01
C03 01  3  ENG  @0 Experimental study @5 01
C03 02  3  FRE  @0 XRD @5 02
C03 02  3  ENG  @0 XRD @5 02
C03 03  3  FRE  @0 Structure cristalline @5 03
C03 03  3  ENG  @0 Crystal structure @5 03
C03 04  3  FRE  @0 Composé quaternaire @5 04
C03 04  3  ENG  @0 Quaternary compounds @5 04
C03 05  X  FRE  @0 Lithium Triphosphate @2 NC @2 NA @5 05
C03 05  X  ENG  @0 Lithium Triphosphates @2 NC @2 NA @5 05
C03 05  X  SPA  @0 Trifosfato @2 NC @2 NA @5 05
C03 06  X  FRE  @0 Cobalt Triphosphate @2 NC @2 NA @5 06
C03 06  X  ENG  @0 Cobalt Triphosphates @2 NC @2 NA @5 06
C03 06  X  SPA  @0 Trifosfato @2 NC @2 NA @5 06
C03 07  X  FRE  @0 Nickel Triphosphate @2 NC @2 NA @5 07
C03 07  X  ENG  @0 Nickel Triphosphates @2 NC @2 NA @5 07
C03 07  X  SPA  @0 Trifosfato @2 NC @2 NA @5 07
C03 08  3  FRE  @0 Li Ni O P @4 INC @5 52
C03 09  3  FRE  @0 6166F @2 PAC @4 INC @5 56
C03 10  3  FRE  @0 LiCo2P3O10 @4 INC @5 93
C03 11  3  FRE  @0 Cio Li O P @4 INC @5 94
C03 12  3  FRE  @0 LiNi2P3O10 @4 INC @5 95
C07 01  3  FRE  @0 Métal transition composé @5 16
C07 01  3  ENG  @0 Transition element compounds @5 16
C07 02  3  FRE  @0 Composé minéral @5 17
C07 02  3  ENG  @0 Inorganic compounds @5 17
N21       @1 281

Format Inist (serveur)

NO : PASCAL 96-0410568 INIST
ET : Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate
AU : ERRAGH (F.); BOUKHARI (A.); HOLT (E. M.)
AF : Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta/Rabat/Maroc (1 aut., 2 aut.); Laboratoire de Chimie Physique de Matériaux, Département de Chimie, Faculté des Sciences/El Jadida/Maroc (1 aut.); Department of Chemistry, Oklahoma State University/Stillwater, Oklahoma 74078/Etats-Unis (3 aut.)
DT : Publication en série; Niveau analytique
SO : Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Danemark; Da. 1996; Vol. 52; No. p.8; Pp. 1867-1869; Bibl. 15 ref.
LA : Anglais
EA : Isotypic lithium dicobalt triphosphate, LiCo2P3O10, and lithium dinickel triphosphate, LiNi2P3O10, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P3O5-10 groups are situated on a mirror plane, with successive PO3 moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co2+ and Ni2+ ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.
CC : 001B60A66F4
FD : Etude expérimentale; XRD; Structure cristalline; Composé quaternaire; Lithium Triphosphate; Cobalt Triphosphate; Nickel Triphosphate; Li Ni O P; 6166F; LiCo2P3O10; Cio Li O P; LiNi2P3O10
FG : Métal transition composé; Composé minéral
ED : Experimental study; XRD; Crystal structure; Quaternary compounds; Lithium Triphosphates; Cobalt Triphosphates; Nickel Triphosphates
EG : Transition element compounds; Inorganic compounds
SD : Trifosfato; Trifosfato; Trifosfato
LO : INIST-5160C.354000064047280040
ID : 96-0410568

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Pascal:96-0410568

Le document en format XML

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<term>Cobalt Triphosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Lithium Triphosphates</term>
<term>Nickel Triphosphates</term>
<term>Quaternary compounds</term>
<term>XRD</term>
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<term>Etude expérimentale</term>
<term>XRD</term>
<term>Structure cristalline</term>
<term>Composé quaternaire</term>
<term>Lithium Triphosphate</term>
<term>Cobalt Triphosphate</term>
<term>Nickel Triphosphate</term>
<term>Li Ni O P</term>
<term>6166F</term>
<term>LiCo2P3O10</term>
<term>Cio Li O P</term>
<term>LiNi2P3O10</term>
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<front>
<div type="abstract" xml:lang="en">Isotypic lithium dicobalt triphosphate, LiCo
<sub>2</sub>
P
<sub>3</sub>
O
<sub>10</sub>
, and lithium dinickel triphosphate, LiNi
<sub>2</sub>
P
<sub>3</sub>
O
<sub>10</sub>
, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P
<sub>3</sub>
O
<sup>5-</sup>
<sub>10</sub>
groups are situated on a mirror plane, with successive PO
<sub>3</sub>
moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co
<sup>2+</sup>
and Ni
<sup>2+</sup>
ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.</div>
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<s3>MAR</s3>
<sZ>1 aut.</sZ>
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<s2>El Jadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
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<s0>Isotypic lithium dicobalt triphosphate, LiCo
<sub>2</sub>
P
<sub>3</sub>
O
<sub>10</sub>
, and lithium dinickel triphosphate, LiNi
<sub>2</sub>
P
<sub>3</sub>
O
<sub>10</sub>
, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P
<sub>3</sub>
O
<sup>5-</sup>
<sub>10</sub>
groups are situated on a mirror plane, with successive PO
<sub>3</sub>
moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co
<sup>2+</sup>
and Ni
<sup>2+</sup>
ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.</s0>
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<s5>01</s5>
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<s5>02</s5>
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<s5>03</s5>
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<s0>Crystal structure</s0>
<s5>03</s5>
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<s5>04</s5>
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<s0>Quaternary compounds</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Lithium Triphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Lithium Triphosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
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<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Cobalt Triphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
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<s0>Cobalt Triphosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
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<s0>Trifosfato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Nickel Triphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Nickel Triphosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
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<fC03 i1="07" i2="X" l="SPA">
<s0>Trifosfato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
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<fC03 i1="08" i2="3" l="FRE">
<s0>Li Ni O P</s0>
<s4>INC</s4>
<s5>52</s5>
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<s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
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<fC03 i1="10" i2="3" l="FRE">
<s0>LiCo2P3O10</s0>
<s4>INC</s4>
<s5>93</s5>
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<fC03 i1="11" i2="3" l="FRE">
<s0>Cio Li O P</s0>
<s4>INC</s4>
<s5>94</s5>
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<s0>LiNi2P3O10</s0>
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<s5>95</s5>
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<ET>Lithium dicobalt tripolyphosphate and lithium dinickel tripolyphosphate</ET>
<AU>ERRAGH (F.); BOUKHARI (A.); HOLT (E. M.)</AU>
<AF>Laboratoire de Chimie du Solide Appliquée, Département de Chimie, Faculté des Sciences, Université Mohammed V, Avenue Ibn Batouta/Rabat/Maroc (1 aut., 2 aut.); Laboratoire de Chimie Physique de Matériaux, Département de Chimie, Faculté des Sciences/El Jadida/Maroc (1 aut.); Department of Chemistry, Oklahoma State University/Stillwater, Oklahoma 74078/Etats-Unis (3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Danemark; Da. 1996; Vol. 52; No. p.8; Pp. 1867-1869; Bibl. 15 ref.</SO>
<LA>Anglais</LA>
<EA>Isotypic lithium dicobalt triphosphate, LiCo
<sub>2</sub>
P
<sub>3</sub>
O
<sub>10</sub>
, and lithium dinickel triphosphate, LiNi
<sub>2</sub>
P
<sub>3</sub>
O
<sub>10</sub>
, have been synthesized and characterized by single-crystal X-ray diffraction. These are the first observations of non-hydrated mixed-metal tripolyphosphates. The P
<sub>3</sub>
O
<sup>5-</sup>
<sub>10</sub>
groups are situated on a mirror plane, with successive PO
<sub>3</sub>
moieties displaying both staggered and eclipsed conformations. Octahedrally coordinated Co
<sup>2+</sup>
and Ni
<sup>2+</sup>
ions form a staggered chain [Co...Co 3.286(1) and 3.133(1)Å, Ni...Ni 3.201(1) and 3.023(1)Å], with successive metal ions bridged by two O atoms.</EA>
<CC>001B60A66F4</CC>
<FD>Etude expérimentale; XRD; Structure cristalline; Composé quaternaire; Lithium Triphosphate; Cobalt Triphosphate; Nickel Triphosphate; Li Ni O P; 6166F; LiCo2P3O10; Cio Li O P; LiNi2P3O10</FD>
<FG>Métal transition composé; Composé minéral</FG>
<ED>Experimental study; XRD; Crystal structure; Quaternary compounds; Lithium Triphosphates; Cobalt Triphosphates; Nickel Triphosphates</ED>
<EG>Transition element compounds; Inorganic compounds</EG>
<SD>Trifosfato; Trifosfato; Trifosfato</SD>
<LO>INIST-5160C.354000064047280040</LO>
<ID>96-0410568</ID>
</server>
</inist>
</record>

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