CobaltMaghrebV1, PascalFrancis, Corpus, bibRecord, 000273

Preparation and structure of a series of cyclohexaphosphates : M(p-CH3C6H4NH3)4P6O18.8H2O (M = Cd, Co, Zn, and Cu)

Identifieur interne : 000273 ( PascalFrancis/Corpus ); précédent : 000272; suivant : 000274

Preparation and structure of a series of cyclohexaphosphates : M(p-CH3C6H4NH3)4P6O18.8H2O (M = Cd, Co, Zn, and Cu)

Auteurs : S. Abid ; M. Rzaigui ; M. Bagieu-Beucher

Source :

Materials research bulletin [ 0025-5408 ] ; 2000.

RBID : Pascal:01-0328109

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Préparation chimique, Diffraction RX, Structure cristalline, Cadmium phosphate, Cobalt phosphate, Zinc phosphate, Cuivre phosphate, Cation organique, Composé benzénique, Spectre IR, TGA, 6166F, 6166H, Ammonium(p-tolyl), Cyclohexaphosphate.

English descriptors

KwdEn :
- Benzenic compound, Cadmium phosphates, Chemical preparation, Cobalt phosphates, Copper phosphates, Crystal structure, Experimental study, Infrared spectra, Organic cation, TGA, XRD, Zinc phosphates.

Abstract

Four new cyclohexaphosphates with the general formula M(p-CH₃C₆H₄NH₃)₄P₆O₁₈.8H₂O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH₃C₆H₄NH₃)₄P₆O₁₈.8H₂O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β=91.93(1), γ = 93.45(1)°, Z = 1, P========Imacr;, V = 1193.9(6) Å³, and D_x = 1.618 g.cm^-3. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P₆O₁₈^6- ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0025-5408`
A02	`01`			`@0 MRBUAC`
A03		`1`		`@0 Mater. res. bull.`
A05				`@2 35`
A06				`@2 12`
A08	`01`	`1`	`ENG`	`@1 Preparation and structure of a series of cyclohexaphosphates : M(p-CH₃C₆H₄NH₃)₄P₆O₁₈.8H₂O (M = Cd, Co, Zn, and Cu)`
A11	`01`	`1`		`@1 ABID (S.)`
A11	`02`	`1`		`@1 RZAIGUI (M.)`
A11	`03`	`1`		`@1 BAGIEU-BEUCHER (M.)`
A14	`01`			`@1 Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte @2 7021 Zarzouna @3 TUN @Z 1 aut. @Z 2 aut.`
A14	`02`			`@1 Laboratoire de Cristallographie associé à l'Université J. Fourier, C.N.R.S., BP. 166 @2 38042 Grenoble @3 FRA @Z 3 aut.`
A20				`@1 1933-1944`
A21				`@1 2000`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 13343 @5 354000097534020050`
A44				`@0 0000 @1 © 2001 INIST-CNRS. All rights reserved.`
A45				`@0 7 ref.`
A47	`01`	`1`		`@0 01-0328109`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Materials research bulletin`
A66	`01`			`@0 USA`
C01	`01`		`ENG`	@0 Four new cyclohexaphosphates with the general formula M(p-CH₃C₆H₄NH₃)₄P₆O₁₈.8H₂O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH₃C₆H₄NH₃)₄P₆O₁₈.8H₂O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β=91.93(1), γ = 93.45(1)°, Z = 1, P========Imacr;, V = 1193.9(6) Å³, and D_x = 1.618 g.cm^-3. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P₆O₁₈^6- ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.
C02	`01`	`3`		`@0 001B60A66F4`
C02	`02`	`3`		`@0 001B60A66H2`
C03	`01`	`3`	`FRE`	`@0 Etude expérimentale @5 01`
C03	`01`	`3`	`ENG`	`@0 Experimental study @5 01`
C03	`02`	`3`	`FRE`	`@0 Préparation chimique @5 02`
C03	`02`	`3`	`ENG`	`@0 Chemical preparation @5 02`
C03	`03`	`3`	`FRE`	`@0 Diffraction RX @5 03`
C03	`03`	`3`	`ENG`	`@0 XRD @5 03`
C03	`04`	`3`	`FRE`	`@0 Structure cristalline @5 04`
C03	`04`	`3`	`ENG`	`@0 Crystal structure @5 04`
C03	`05`	`3`	`FRE`	`@0 Cadmium phosphate @2 NK @5 07`
C03	`05`	`3`	`ENG`	`@0 Cadmium phosphates @2 NK @5 07`
C03	`06`	`3`	`FRE`	`@0 Cobalt phosphate @2 NK @5 08`
C03	`06`	`3`	`ENG`	`@0 Cobalt phosphates @2 NK @5 08`
C03	`07`	`3`	`FRE`	`@0 Zinc phosphate @2 NK @5 09`
C03	`07`	`3`	`ENG`	`@0 Zinc phosphates @2 NK @5 09`
C03	`08`	`3`	`FRE`	`@0 Cuivre phosphate @2 NK @5 10`
C03	`08`	`3`	`ENG`	`@0 Copper phosphates @2 NK @5 10`
C03	`09`	`X`	`FRE`	`@0 Cation organique @5 13`
C03	`09`	`X`	`ENG`	`@0 Organic cation @5 13`
C03	`09`	`X`	`SPA`	`@0 Catión orgánico @5 13`
C03	`10`	`X`	`FRE`	`@0 Composé benzénique @5 15`
C03	`10`	`X`	`ENG`	`@0 Benzenic compound @5 15`
C03	`10`	`X`	`SPA`	`@0 Compuesto bencénico @5 15`
C03	`11`	`3`	`FRE`	`@0 Spectre IR @5 16`
C03	`11`	`3`	`ENG`	`@0 Infrared spectra @5 16`
C03	`12`	`3`	`FRE`	`@0 TGA @5 17`
C03	`12`	`3`	`ENG`	`@0 TGA @5 17`
C03	`13`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C03	`14`	`3`	`FRE`	`@0 6166H @2 PAC @4 INC @5 57`
C03	`15`	`3`	`FRE`	`@0 Ammonium(p-tolyl) @2 NK @4 INC @5 92`
C03	`16`	`3`	`FRE`	`@0 Cyclohexaphosphate @2 NA @4 INC @5 93`
C07	`01`	`3`	`FRE`	`@0 Métal transition composé @5 05`
C07	`01`	`3`	`ENG`	`@0 Transition element compounds @5 05`
C07	`02`	`X`	`FRE`	`@0 Métal divalent Composé @2 NC @2 NA @5 06`
C07	`02`	`X`	`ENG`	`@0 Divalent metal Compounds @2 NC @2 NA @5 06`
C07	`02`	`X`	`SPA`	`@0 Metal divalente Compuesto @2 NC @2 NA @5 06`
C07	`03`	`X`	`FRE`	`@0 Phosphate cyclique @5 11`
C07	`03`	`X`	`ENG`	`@0 Cyclophosphate @5 11`
C07	`03`	`X`	`SPA`	`@0 Ciclofosfato @5 11`
C07	`04`	`X`	`FRE`	`@0 Polyphosphate @2 NA @5 12`
C07	`04`	`X`	`ENG`	`@0 Polyphosphates @2 NA @5 12`
C07	`04`	`X`	`SPA`	`@0 Polifosfato @2 NA @5 12`
C07	`05`	`X`	`FRE`	`@0 Ammonium Composé organique @2 NC @2 NA @5 14`
C07	`05`	`X`	`ENG`	`@0 Ammonium Organic compounds @2 NC @2 NA @5 14`
C07	`05`	`X`	`SPA`	`@0 Amonio Compuesto orgánico @2 NC @2 NA @5 14`
N21				`@1 225`

Format Inist (serveur)

NO :	PASCAL 01-0328109 INIST
ET :	Preparation and structure of a series of cyclohexaphosphates : M(p-CH₃C₆H₄NH₃)₄ P₆O₁₈.8H₂O (M = Cd, Co, Zn, and Cu)
AU :	ABID (S.); RZAIGUI (M.); BAGIEU-BEUCHER (M.)
AF :	Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte/7021 Zarzouna/Tunisie (1 aut., 2 aut.); Laboratoire de Cristallographie associé à l'Université J. Fourier, C.N.R.S., BP. 166/38042 Grenoble/France (3 aut.)
DT :	Publication en série; Niveau analytique
SO :	Materials research bulletin; ISSN 0025-5408; Coden MRBUAC; Etats-Unis; Da. 2000; Vol. 35; No. 12; Pp. 1933-1944; Bibl. 7 ref.
LA :	Anglais
EA :	Four new cyclohexaphosphates with the general formula M(p-CH₃C₆H₄NH₃)₄ P₆O₁₈.8H₂O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH₃C₆H₄NH₃)₄P₆O₁₈.8H₂O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β=91.93(1), γ = 93.45(1)°, Z = 1, P========Imacr;, V = 1193.9(6) Å³, and D_x = 1.618 g.cm^-3. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P₆O₁₈^6- ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.
CC :	001B60A66F4; 001B60A66H2
FD :	Etude expérimentale; Préparation chimique; Diffraction RX; Structure cristalline; Cadmium phosphate; Cobalt phosphate; Zinc phosphate; Cuivre phosphate; Cation organique; Composé benzénique; Spectre IR; TGA; 6166F; 6166H; Ammonium(p-tolyl); Cyclohexaphosphate
FG :	Métal transition composé; Métal divalent Composé; Phosphate cyclique; Polyphosphate; Ammonium Composé organique
ED :	Experimental study; Chemical preparation; XRD; Crystal structure; Cadmium phosphates; Cobalt phosphates; Zinc phosphates; Copper phosphates; Organic cation; Benzenic compound; Infrared spectra; TGA
EG :	Transition element compounds; Divalent metal Compounds; Cyclophosphate; Polyphosphates; Ammonium Organic compounds
SD :	Catión orgánico; Compuesto bencénico
LO :	INIST-13343.354000097534020050
ID :	01-0328109

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Pascal:01-0328109

Le document en format XML

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C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M = Cd, Co, Zn, and Cu)</title>
<author><name sortKey="Abid, S" sort="Abid, S" uniqKey="Abid S" first="S." last="Abid">S. Abid</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Preparation and structure of a series of cyclohexaphosphates : M(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M = Cd, Co, Zn, and Cu)</title>
<author><name sortKey="Abid, S" sort="Abid, S" uniqKey="Abid S" first="S." last="Abid">S. Abid</name>
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<author><name sortKey="Bagieu Beucher, M" sort="Bagieu Beucher, M" uniqKey="Bagieu Beucher M" first="M." last="Bagieu-Beucher">M. Bagieu-Beucher</name>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Benzenic compound</term>
<term>Cadmium phosphates</term>
<term>Chemical preparation</term>
<term>Cobalt phosphates</term>
<term>Copper phosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Infrared spectra</term>
<term>Organic cation</term>
<term>TGA</term>
<term>XRD</term>
<term>Zinc phosphates</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Préparation chimique</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Cadmium phosphate</term>
<term>Cobalt phosphate</term>
<term>Zinc phosphate</term>
<term>Cuivre phosphate</term>
<term>Cation organique</term>
<term>Composé benzénique</term>
<term>Spectre IR</term>
<term>TGA</term>
<term>6166F</term>
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<front><div type="abstract" xml:lang="en">Four new cyclohexaphosphates with the general formula M(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β=91.93(1), γ = 93.45(1)°, Z = 1, P========Imacr;, V = 1193.9(6) Å<sup>3</sup>
, and D<sub>x</sub>
 = 1.618 g.cm<sup>-3</sup>
. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P<sub>6</sub>
O<sub>18</sub>
<sup>6-</sup>
 ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Preparation and structure of a series of cyclohexaphosphates : M(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
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.8H<sub>2</sub>
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<fA14 i1="01"><s1>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte</s1>
<s2>7021 Zarzouna</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire de Cristallographie associé à l'Université J. Fourier, C.N.R.S., BP. 166</s1>
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<s3>FRA</s3>
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<fA60><s1>P</s1>
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<fC01 i1="01" l="ENG"><s0>Four new cyclohexaphosphates with the general formula M(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β=91.93(1), γ = 93.45(1)°, Z = 1, P========Imacr;, V = 1193.9(6) Å<sup>3</sup>
, and D<sub>x</sub>
 = 1.618 g.cm<sup>-3</sup>
. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P<sub>6</sub>
O<sub>18</sub>
<sup>6-</sup>
 ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F4</s0>
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<fC02 i1="02" i2="3"><s0>001B60A66H2</s0>
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<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
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<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Préparation chimique</s0>
<s5>02</s5>
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<fC03 i1="02" i2="3" l="ENG"><s0>Chemical preparation</s0>
<s5>02</s5>
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<fC03 i1="03" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>03</s5>
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<fC03 i1="03" i2="3" l="ENG"><s0>XRD</s0>
<s5>03</s5>
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<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Cadmium phosphate</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Cadmium phosphates</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Cobalt phosphate</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Cobalt phosphates</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Zinc phosphate</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Zinc phosphates</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Cuivre phosphate</s0>
<s2>NK</s2>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Copper phosphates</s0>
<s2>NK</s2>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Cation organique</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Organic cation</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Catión orgánico</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Composé benzénique</s0>
<s5>15</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Benzenic compound</s0>
<s5>15</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Compuesto bencénico</s0>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Spectre IR</s0>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Infrared spectra</s0>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>TGA</s0>
<s5>17</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG"><s0>TGA</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>6166H</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Ammonium(p-tolyl)</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>Cyclohexaphosphate</s0>
<s2>NA</s2>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>05</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>05</s5>
</fC07>
<fC07 i1="02" i2="X" l="FRE"><s0>Métal divalent Composé</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC07>
<fC07 i1="02" i2="X" l="ENG"><s0>Divalent metal Compounds</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC07>
<fC07 i1="02" i2="X" l="SPA"><s0>Metal divalente Compuesto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC07>
<fC07 i1="03" i2="X" l="FRE"><s0>Phosphate cyclique</s0>
<s5>11</s5>
</fC07>
<fC07 i1="03" i2="X" l="ENG"><s0>Cyclophosphate</s0>
<s5>11</s5>
</fC07>
<fC07 i1="03" i2="X" l="SPA"><s0>Ciclofosfato</s0>
<s5>11</s5>
</fC07>
<fC07 i1="04" i2="X" l="FRE"><s0>Polyphosphate</s0>
<s2>NA</s2>
<s5>12</s5>
</fC07>
<fC07 i1="04" i2="X" l="ENG"><s0>Polyphosphates</s0>
<s2>NA</s2>
<s5>12</s5>
</fC07>
<fC07 i1="04" i2="X" l="SPA"><s0>Polifosfato</s0>
<s2>NA</s2>
<s5>12</s5>
</fC07>
<fC07 i1="05" i2="X" l="FRE"><s0>Ammonium Composé organique</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>14</s5>
</fC07>
<fC07 i1="05" i2="X" l="ENG"><s0>Ammonium Organic compounds</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>14</s5>
</fC07>
<fC07 i1="05" i2="X" l="SPA"><s0>Amonio Compuesto orgánico</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>14</s5>
</fC07>
<fN21><s1>225</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 01-0328109 INIST</NO>
<ET>Preparation and structure of a series of cyclohexaphosphates : M(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
 P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M = Cd, Co, Zn, and Cu)</ET>
<AU>ABID (S.); RZAIGUI (M.); BAGIEU-BEUCHER (M.)</AU>
<AF>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte/7021 Zarzouna/Tunisie (1 aut., 2 aut.); Laboratoire de Cristallographie associé à l'Université J. Fourier, C.N.R.S., BP. 166/38042 Grenoble/France (3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Materials research bulletin; ISSN 0025-5408; Coden MRBUAC; Etats-Unis; Da. 2000; Vol. 35; No. 12; Pp. 1933-1944; Bibl. 7 ref.</SO>
<LA>Anglais</LA>
<EA>Four new cyclohexaphosphates with the general formula M(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
 P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β=91.93(1), γ = 93.45(1)°, Z = 1, P========Imacr;, V = 1193.9(6) Å<sup>3</sup>
, and D<sub>x</sub>
 = 1.618 g.cm<sup>-3</sup>
. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P<sub>6</sub>
O<sub>18</sub>
<sup>6-</sup>
 ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.</EA>
<CC>001B60A66F4; 001B60A66H2</CC>
<FD>Etude expérimentale; Préparation chimique; Diffraction RX; Structure cristalline; Cadmium phosphate; Cobalt phosphate; Zinc phosphate; Cuivre phosphate; Cation organique; Composé benzénique; Spectre IR; TGA; 6166F; 6166H; Ammonium(p-tolyl); Cyclohexaphosphate</FD>
<FG>Métal transition composé; Métal divalent Composé; Phosphate cyclique; Polyphosphate; Ammonium Composé organique</FG>
<ED>Experimental study; Chemical preparation; XRD; Crystal structure; Cadmium phosphates; Cobalt phosphates; Zinc phosphates; Copper phosphates; Organic cation; Benzenic compound; Infrared spectra; TGA</ED>
<EG>Transition element compounds; Divalent metal Compounds; Cyclophosphate; Polyphosphates; Ammonium Organic compounds</EG>
<SD>Catión orgánico; Compuesto bencénico</SD>
<LO>INIST-13343.354000097534020050</LO>
<ID>01-0328109</ID>
</server>
</inist>
</record>

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Preparation and structure of a series of cyclohexaphosphates : M(p-CH3C6H4NH3)4P6O18.8H2O (M = Cd, Co, Zn, and Cu)

Preparation and structure of a series of cyclohexaphosphates : M(p-CH3C6H4NH3)4P6O18.8H2O (M = Cd, Co, Zn, and Cu)

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