CobaltMaghrebV1, PascalFrancis, Corpus, bibRecord, 000260

Nuclear and magnetic structure of layered LiFe1-xCoxO2 (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction

Identifieur interne : 000260 ( PascalFrancis/Corpus ); précédent : 000259; suivant : 000261

Nuclear and magnetic structure of layered LiFe1-xCoxO2 (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction

Auteurs : N. Douakha ; M. Holzapfel ; E. Chappel ; G. Chouteau ; L. Croguennec ; A. Ott ; B. Ouladdiaf

Source :

Journal of solid state chemistry [ 0022-4596 ] ; 2002.

RBID : Pascal:02-0184369

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Lithium oxyde, Fer oxyde, Cobalt oxyde, Solution solide, Composition chimique, Diffraction neutron, Haute température, Basse température, Température ambiante, Structure cristalline, Structure lamellaire, Structure magnétique, Antiferromagnétisme, Moment magnétique, 6166F, 7525, LiFe1-xCoxO2, Co Fe Li O.

English descriptors

KwdEn :
- Ambient temperature, Antiferromagnetism, Chemical composition, Cobalt oxides, Crystal structure, Experimental study, High temperature, Iron oxides, Lamellar structure, Lithium oxides, Low temperature, Magnetic moments, Magnetic structure, Neutron diffraction, Solid solutions.

Abstract

Mixed lithium-transition metal oxides LiFe_1-xCo_xO₂ (0 ≤ x ≤ 1) have been studied by powder neutron diffraction in the temperature range 1.5-100 K and at room temperature. The low-temperature data analysis of the high-flux neutron diffraction patterns reveals an antiferromagnetic arrangement with a propagation vector k = [001/2]. The value obtained for the magnetic moment of Fe³⁺ ions at 1.5 K, μ_Fe3+ = 3.9 μ_B, is in good agreement with the value deduced from magnetization data and is also consistent with the high spin state of Fe³⁺ ion. The crystallographic structure was determined by both X-ray and high-resolution neutron diffraction measurements.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0022-4596`
A02	`01`			`@0 JSSCBI`
A03		`1`		`@0 J. solid state chem.`
A05				`@2 163`
A06				`@2 2`
A08	`01`	`1`	`ENG`	`@1 Nuclear and magnetic structure of layered LiFe_1-xCo_xO₂ (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction`
A11	`01`	`1`		`@1 DOUAKHA (N.)`
A11	`02`	`1`		`@1 HOLZAPFEL (M.)`
A11	`03`	`1`		`@1 CHAPPEL (E.)`
A11	`04`	`1`		`@1 CHOUTEAU (G.)`
A11	`05`	`1`		`@1 CROGUENNEC (L.)`
A11	`06`	`1`		`@1 OTT (A.)`
A11	`07`	`1`		`@1 OULADDIAF (B.)`
A14	`01`			`@1 Grenoble High Magnetic Field Laboratory, CNRS/MPI-FKF, 25, Avenue des Martyrs, BP 166 @2 38042 Grenoble @3 FRA @Z 1 aut. @Z 3 aut. @Z 4 aut.`
A14	`02`			`@1 LPG, BP 401 @2 Guelma 24000 @3 DZA @Z 1 aut.`
A14	`03`			`@1 Laboratoire d'Electrochimie et de Physicochimie des Matériaux et des Interfaces, LEPMI-INPG, 1130 rue de la piscine, BP 75 @2 38402 St. Martin d'Hères @3 FRA @Z 2 aut.`
A14	`04`			`@1 Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18 @2 72076 Tübingen @3 DEU @Z 2 aut. @Z 6 aut.`
A14	`05`			`@1 ICMCB-CNRS and ENSCPB, 87 Avenue du Dr A. Schweitzer @2 33608 Pessac @3 FRA @Z 5 aut.`
A14	`06`			`@1 Institut Laue Langevin, BP 156 @2 38042 Grenoble @3 FRA @Z 7 aut.`
A20				`@1 406-411`
A21				`@1 2002`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 14677 @5 354000102738200080`
A44				`@0 0000 @1 © 2002 INIST-CNRS. All rights reserved.`
A45				`@0 24 ref.`
A47	`01`	`1`		`@0 02-0184369`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of solid state chemistry`
A66	`01`			`@0 USA`
C01	`01`		`ENG`	@0 Mixed lithium-transition metal oxides LiFe_1-xCo_xO₂ (0 ≤ x ≤ 1) have been studied by powder neutron diffraction in the temperature range 1.5-100 K and at room temperature. The low-temperature data analysis of the high-flux neutron diffraction patterns reveals an antiferromagnetic arrangement with a propagation vector k = [001/2]. The value obtained for the magnetic moment of Fe³⁺ ions at 1.5 K, μ_Fe3+ = 3.9 μ_B, is in good agreement with the value deduced from magnetization data and is also consistent with the high spin state of Fe³⁺ ion. The crystallographic structure was determined by both X-ray and high-resolution neutron diffraction measurements.
C02	`01`	`3`		`@0 001B60A66F1`
C02	`02`	`3`		`@0 001B70E25`
C03	`01`	`3`	`FRE`	`@0 Etude expérimentale @5 01`
C03	`01`	`3`	`ENG`	`@0 Experimental study @5 01`
C03	`02`	`3`	`FRE`	`@0 Lithium oxyde @2 NK @5 02`
C03	`02`	`3`	`ENG`	`@0 Lithium oxides @2 NK @5 02`
C03	`03`	`3`	`FRE`	`@0 Fer oxyde @2 NK @5 03`
C03	`03`	`3`	`ENG`	`@0 Iron oxides @2 NK @5 03`
C03	`04`	`3`	`FRE`	`@0 Cobalt oxyde @2 NK @5 04`
C03	`04`	`3`	`ENG`	`@0 Cobalt oxides @2 NK @5 04`
C03	`05`	`3`	`FRE`	`@0 Solution solide @5 05`
C03	`05`	`3`	`ENG`	`@0 Solid solutions @5 05`
C03	`06`	`3`	`FRE`	`@0 Composition chimique @5 06`
C03	`06`	`3`	`ENG`	`@0 Chemical composition @5 06`
C03	`07`	`3`	`FRE`	`@0 Diffraction neutron @5 07`
C03	`07`	`3`	`ENG`	`@0 Neutron diffraction @5 07`
C03	`08`	`X`	`FRE`	`@0 Haute température @5 08`
C03	`08`	`X`	`ENG`	`@0 High temperature @5 08`
C03	`08`	`X`	`SPA`	`@0 Alta temperatura @5 08`
C03	`09`	`X`	`FRE`	`@0 Basse température @5 09`
C03	`09`	`X`	`ENG`	`@0 Low temperature @5 09`
C03	`09`	`X`	`SPA`	`@0 Baja temperatura @5 09`
C03	`10`	`3`	`FRE`	`@0 Température ambiante @5 10`
C03	`10`	`3`	`ENG`	`@0 Ambient temperature @5 10`
C03	`11`	`3`	`FRE`	`@0 Structure cristalline @5 11`
C03	`11`	`3`	`ENG`	`@0 Crystal structure @5 11`
C03	`12`	`X`	`FRE`	`@0 Structure lamellaire @5 12`
C03	`12`	`X`	`ENG`	`@0 Lamellar structure @5 12`
C03	`12`	`X`	`SPA`	`@0 Estructura lamelar @5 12`
C03	`13`	`3`	`FRE`	`@0 Structure magnétique @5 14`
C03	`13`	`3`	`ENG`	`@0 Magnetic structure @5 14`
C03	`14`	`3`	`FRE`	`@0 Antiferromagnétisme @5 15`
C03	`14`	`3`	`ENG`	`@0 Antiferromagnetism @5 15`
C03	`15`	`3`	`FRE`	`@0 Moment magnétique @5 16`
C03	`15`	`3`	`ENG`	`@0 Magnetic moments @5 16`
C03	`16`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C03	`17`	`3`	`FRE`	`@0 7525 @2 PAC @4 INC @5 57`
C03	`18`	`3`	`FRE`	`@0 LiFe1-xCoxO2 @4 INC @5 92`
C03	`19`	`3`	`FRE`	`@0 Co Fe Li O @4 INC @5 93`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 17`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 17`
C07	`02`	`3`	`FRE`	`@0 Métal transition composé @5 18`
C07	`02`	`3`	`ENG`	`@0 Transition element compounds @5 18`
N21				`@1 105`
N82				`@1 PSI`

Format Inist (serveur)

NO :	PASCAL 02-0184369 INIST
ET :	Nuclear and magnetic structure of layered LiFe_1-xCo_xO₂ (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction
AU :	DOUAKHA (N.); HOLZAPFEL (M.); CHAPPEL (E.); CHOUTEAU (G.); CROGUENNEC (L.); OTT (A.); OULADDIAF (B.)
AF :	Grenoble High Magnetic Field Laboratory, CNRS/MPI-FKF, 25, Avenue des Martyrs, BP 166/38042 Grenoble/France (1 aut., 3 aut., 4 aut.); LPG, BP 401/Guelma 24000/Algérie (1 aut.); Laboratoire d'Electrochimie et de Physicochimie des Matériaux et des Interfaces, LEPMI-INPG, 1130 rue de la piscine, BP 75/38402 St. Martin d'Hères/France (2 aut.); Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18/72076 Tübingen/Allemagne (2 aut., 6 aut.); ICMCB-CNRS and ENSCPB, 87 Avenue du Dr A. Schweitzer/33608 Pessac/France (5 aut.); Institut Laue Langevin, BP 156/38042 Grenoble/France (7 aut.)
DT :	Publication en série; Niveau analytique
SO :	Journal of solid state chemistry; ISSN 0022-4596; Coden JSSCBI; Etats-Unis; Da. 2002; Vol. 163; No. 2; Pp. 406-411; Bibl. 24 ref.
LA :	Anglais
EA :	Mixed lithium-transition metal oxides LiFe_1-xCo_xO₂ (0 ≤ x ≤ 1) have been studied by powder neutron diffraction in the temperature range 1.5-100 K and at room temperature. The low-temperature data analysis of the high-flux neutron diffraction patterns reveals an antiferromagnetic arrangement with a propagation vector k = [001/2]. The value obtained for the magnetic moment of Fe³⁺ ions at 1.5 K, μ_Fe3+ = 3.9 μ_B, is in good agreement with the value deduced from magnetization data and is also consistent with the high spin state of Fe³⁺ ion. The crystallographic structure was determined by both X-ray and high-resolution neutron diffraction measurements.
CC :	001B60A66F1; 001B70E25
FD :	Etude expérimentale; Lithium oxyde; Fer oxyde; Cobalt oxyde; Solution solide; Composition chimique; Diffraction neutron; Haute température; Basse température; Température ambiante; Structure cristalline; Structure lamellaire; Structure magnétique; Antiferromagnétisme; Moment magnétique; 6166F; 7525; LiFe1-xCoxO2; Co Fe Li O
FG :	Composé minéral; Métal transition composé
ED :	Experimental study; Lithium oxides; Iron oxides; Cobalt oxides; Solid solutions; Chemical composition; Neutron diffraction; High temperature; Low temperature; Ambient temperature; Crystal structure; Lamellar structure; Magnetic structure; Antiferromagnetism; Magnetic moments
EG :	Inorganic compounds; Transition element compounds
SD :	Alta temperatura; Baja temperatura; Estructura lamelar
LO :	INIST-14677.354000102738200080
ID :	02-0184369

Links to Exploration step

Pascal:02-0184369

Le document en format XML

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 (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Nuclear and magnetic structure of layered LiFe<sub>1-x</sub>
Co<sub>x</sub>
O<sub>2</sub>
 (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction</title>
<author><name sortKey="Douakha, N" sort="Douakha, N" uniqKey="Douakha N" first="N." last="Douakha">N. Douakha</name>
<affiliation><inist:fA14 i1="01"><s1>Grenoble High Magnetic Field Laboratory, CNRS/MPI-FKF, 25, Avenue des Martyrs, BP 166</s1>
<s2>38042 Grenoble</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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</affiliation>
<affiliation><inist:fA14 i1="02"><s1>LPG, BP 401</s1>
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<author><name sortKey="Holzapfel, M" sort="Holzapfel, M" uniqKey="Holzapfel M" first="M." last="Holzapfel">M. Holzapfel</name>
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<s2>38402 St. Martin d'Hères</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
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</affiliation>
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<s3>DEU</s3>
<sZ>2 aut.</sZ>
<sZ>6 aut.</sZ>
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<author><name sortKey="Chappel, E" sort="Chappel, E" uniqKey="Chappel E" first="E." last="Chappel">E. Chappel</name>
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<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
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</affiliation>
</author>
<author><name sortKey="Chouteau, G" sort="Chouteau, G" uniqKey="Chouteau G" first="G." last="Chouteau">G. Chouteau</name>
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<sZ>1 aut.</sZ>
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<author><name sortKey="Croguennec, L" sort="Croguennec, L" uniqKey="Croguennec L" first="L." last="Croguennec">L. Croguennec</name>
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<author><name sortKey="Ott, A" sort="Ott, A" uniqKey="Ott A" first="A." last="Ott">A. Ott</name>
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<s3>DEU</s3>
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<author><name sortKey="Ouladdiaf, B" sort="Ouladdiaf, B" uniqKey="Ouladdiaf B" first="B." last="Ouladdiaf">B. Ouladdiaf</name>
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<series><title level="j" type="main">Journal of solid state chemistry</title>
<title level="j" type="abbreviated">J. solid state chem.</title>
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</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Ambient temperature</term>
<term>Antiferromagnetism</term>
<term>Chemical composition</term>
<term>Cobalt oxides</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>High temperature</term>
<term>Iron oxides</term>
<term>Lamellar structure</term>
<term>Lithium oxides</term>
<term>Low temperature</term>
<term>Magnetic moments</term>
<term>Magnetic structure</term>
<term>Neutron diffraction</term>
<term>Solid solutions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Lithium oxyde</term>
<term>Fer oxyde</term>
<term>Cobalt oxyde</term>
<term>Solution solide</term>
<term>Composition chimique</term>
<term>Diffraction neutron</term>
<term>Haute température</term>
<term>Basse température</term>
<term>Température ambiante</term>
<term>Structure cristalline</term>
<term>Structure lamellaire</term>
<term>Structure magnétique</term>
<term>Antiferromagnétisme</term>
<term>Moment magnétique</term>
<term>6166F</term>
<term>7525</term>
<term>LiFe1-xCoxO2</term>
<term>Co Fe Li O</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Mixed lithium-transition metal oxides LiFe<sub>1-x</sub>
Co<sub>x</sub>
O<sub>2</sub>
 (0 ≤ x ≤ 1) have been studied by powder neutron diffraction in the temperature range 1.5-100 K and at room temperature. The low-temperature data analysis of the high-flux neutron diffraction patterns reveals an antiferromagnetic arrangement with a propagation vector k = [001/2]. The value obtained for the magnetic moment of Fe<sup>3+</sup>
 ions at 1.5 K, μ<sub>Fe3+</sub>
 = 3.9 μ<sub>B</sub>
, is in good agreement with the value deduced from magnetization data and is also consistent with the high spin state of Fe<sup>3+</sup>
 ion. The crystallographic structure was determined by both X-ray and high-resolution neutron diffraction measurements.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Nuclear and magnetic structure of layered LiFe<sub>1-x</sub>
Co<sub>x</sub>
O<sub>2</sub>
 (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>DOUAKHA (N.)</s1>
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<fA11 i1="02" i2="1"><s1>HOLZAPFEL (M.)</s1>
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<fA11 i1="04" i2="1"><s1>CHOUTEAU (G.)</s1>
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<fA11 i1="05" i2="1"><s1>CROGUENNEC (L.)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>OTT (A.)</s1>
</fA11>
<fA11 i1="07" i2="1"><s1>OULADDIAF (B.)</s1>
</fA11>
<fA14 i1="01"><s1>Grenoble High Magnetic Field Laboratory, CNRS/MPI-FKF, 25, Avenue des Martyrs, BP 166</s1>
<s2>38042 Grenoble</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>LPG, BP 401</s1>
<s2>Guelma 24000</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Laboratoire d'Electrochimie et de Physicochimie des Matériaux et des Interfaces, LEPMI-INPG, 1130 rue de la piscine, BP 75</s1>
<s2>38402 St. Martin d'Hères</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="04"><s1>Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18</s1>
<s2>72076 Tübingen</s2>
<s3>DEU</s3>
<sZ>2 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA14 i1="05"><s1>ICMCB-CNRS and ENSCPB, 87 Avenue du Dr A. Schweitzer</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="06"><s1>Institut Laue Langevin, BP 156</s1>
<s2>38042 Grenoble</s2>
<s3>FRA</s3>
<sZ>7 aut.</sZ>
</fA14>
<fA20><s1>406-411</s1>
</fA20>
<fA21><s1>2002</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>14677</s2>
<s5>354000102738200080</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2002 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>24 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>02-0184369</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of solid state chemistry</s0>
</fA64>
<fA66 i1="01"><s0>USA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Mixed lithium-transition metal oxides LiFe<sub>1-x</sub>
Co<sub>x</sub>
O<sub>2</sub>
 (0 ≤ x ≤ 1) have been studied by powder neutron diffraction in the temperature range 1.5-100 K and at room temperature. The low-temperature data analysis of the high-flux neutron diffraction patterns reveals an antiferromagnetic arrangement with a propagation vector k = [001/2]. The value obtained for the magnetic moment of Fe<sup>3+</sup>
 ions at 1.5 K, μ<sub>Fe3+</sub>
 = 3.9 μ<sub>B</sub>
, is in good agreement with the value deduced from magnetization data and is also consistent with the high spin state of Fe<sup>3+</sup>
 ion. The crystallographic structure was determined by both X-ray and high-resolution neutron diffraction measurements.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F1</s0>
</fC02>
<fC02 i1="02" i2="3"><s0>001B70E25</s0>
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<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
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<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
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<fC03 i1="02" i2="3" l="FRE"><s0>Lithium oxyde</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Lithium oxides</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Fer oxyde</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Iron oxides</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Cobalt oxyde</s0>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Cobalt oxides</s0>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Solution solide</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Solid solutions</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Composition chimique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Chemical composition</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Diffraction neutron</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Neutron diffraction</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Haute température</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>High temperature</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Alta temperatura</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Basse température</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Low temperature</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Baja temperatura</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Température ambiante</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Ambient temperature</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Structure lamellaire</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Lamellar structure</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Estructura lamelar</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Structure magnétique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>Magnetic structure</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Antiferromagnétisme</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Antiferromagnetism</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Moment magnétique</s0>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Magnetic moments</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>7525</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>LiFe1-xCoxO2</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>Co Fe Li O</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>17</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>18</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>18</s5>
</fC07>
<fN21><s1>105</s1>
</fN21>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
<server><NO>PASCAL 02-0184369 INIST</NO>
<ET>Nuclear and magnetic structure of layered LiFe<sub>1-x</sub>
Co<sub>x</sub>
O<sub>2</sub>
 (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction</ET>
<AU>DOUAKHA (N.); HOLZAPFEL (M.); CHAPPEL (E.); CHOUTEAU (G.); CROGUENNEC (L.); OTT (A.); OULADDIAF (B.)</AU>
<AF>Grenoble High Magnetic Field Laboratory, CNRS/MPI-FKF, 25, Avenue des Martyrs, BP 166/38042 Grenoble/France (1 aut., 3 aut., 4 aut.); LPG, BP 401/Guelma 24000/Algérie (1 aut.); Laboratoire d'Electrochimie et de Physicochimie des Matériaux et des Interfaces, LEPMI-INPG, 1130 rue de la piscine, BP 75/38402 St. Martin d'Hères/France (2 aut.); Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18/72076 Tübingen/Allemagne (2 aut., 6 aut.); ICMCB-CNRS and ENSCPB, 87 Avenue du Dr A. Schweitzer/33608 Pessac/France (5 aut.); Institut Laue Langevin, BP 156/38042 Grenoble/France (7 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of solid state chemistry; ISSN 0022-4596; Coden JSSCBI; Etats-Unis; Da. 2002; Vol. 163; No. 2; Pp. 406-411; Bibl. 24 ref.</SO>
<LA>Anglais</LA>
<EA>Mixed lithium-transition metal oxides LiFe<sub>1-x</sub>
Co<sub>x</sub>
O<sub>2</sub>
 (0 ≤ x ≤ 1) have been studied by powder neutron diffraction in the temperature range 1.5-100 K and at room temperature. The low-temperature data analysis of the high-flux neutron diffraction patterns reveals an antiferromagnetic arrangement with a propagation vector k = [001/2]. The value obtained for the magnetic moment of Fe<sup>3+</sup>
 ions at 1.5 K, μ<sub>Fe3+</sub>
 = 3.9 μ<sub>B</sub>
, is in good agreement with the value deduced from magnetization data and is also consistent with the high spin state of Fe<sup>3+</sup>
 ion. The crystallographic structure was determined by both X-ray and high-resolution neutron diffraction measurements.</EA>
<CC>001B60A66F1; 001B70E25</CC>
<FD>Etude expérimentale; Lithium oxyde; Fer oxyde; Cobalt oxyde; Solution solide; Composition chimique; Diffraction neutron; Haute température; Basse température; Température ambiante; Structure cristalline; Structure lamellaire; Structure magnétique; Antiferromagnétisme; Moment magnétique; 6166F; 7525; LiFe1-xCoxO2; Co Fe Li O</FD>
<FG>Composé minéral; Métal transition composé</FG>
<ED>Experimental study; Lithium oxides; Iron oxides; Cobalt oxides; Solid solutions; Chemical composition; Neutron diffraction; High temperature; Low temperature; Ambient temperature; Crystal structure; Lamellar structure; Magnetic structure; Antiferromagnetism; Magnetic moments</ED>
<EG>Inorganic compounds; Transition element compounds</EG>
<SD>Alta temperatura; Baja temperatura; Estructura lamelar</SD>
<LO>INIST-14677.354000102738200080</LO>
<ID>02-0184369</ID>
</server>
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Nuclear and magnetic structure of layered LiFe1-xCoxO2 (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction

Nuclear and magnetic structure of layered LiFe1-xCoxO2 (0 ≤ x ≤ 1) determined by high-resolution neutron diffraction

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