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Oxidation of mercaptans in light oil sweetening by cobalt(II) phthalocyanine-hydrotalcite catalysts

Identifieur interne : 000245 ( PascalFrancis/Corpus ); précédent : 000244; suivant : 000246

Oxidation of mercaptans in light oil sweetening by cobalt(II) phthalocyanine-hydrotalcite catalysts

Auteurs : I. Chatti ; A. Ghorbel ; P. Grange ; J. M. Colin

Source :

RBID : Pascal:02-0429724

Descripteurs français

English descriptors

Abstract

Three Mg-Al hydrotalcites containing cobalt(II) phthalocyanine were prepared by direct synthesis, anion exchange and structure reconstruction. Differences in physicochemical properties and mechanical resistance were observed. The results of the mercaptan oxidation reaction were compared to those obtained with an industrial non-basic impregnated active charcoal. An important activity difference in favor of the prepared catalysts was obtained, confirming that the adequate tuning of basic and oxidant properties lead to a promising catalyst.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0920-5861
A02 01      @0 CATTEA
A03   1    @0 Catal. today
A05       @2 75
A06       @2 1-4
A08 01  1  ENG  @1 Oxidation of mercaptans in light oil sweetening by cobalt(II) phthalocyanine-hydrotalcite catalysts
A09 01  1  ENG  @1 Environmental catalysis: a step forward
A11 01  1    @1 CHATTI (I.)
A11 02  1    @1 GHORBEL (A.)
A11 03  1    @1 GRANGE (P.)
A11 04  1    @1 COLIN (J. M.)
A12 01  1    @1 CENTI (Gabriele) @9 ed.
A12 02  1    @1 CIAMBELLI (Paolo) @9 ed.
A12 03  1    @1 PERATHONER (Siglinda) @9 ed.
A12 04  1    @1 RUSSO (Paola) @9 ed.
A14 01      @1 Laboratoire de Chimie des Matériaux et Catalyse, Département de chimie, Faculté des Sciences de Tunis @2 Tunis 1060 @3 TUN @Z 1 aut. @Z 2 aut.
A14 02      @1 Unité de Catalyse et Chimie des Matériaux Divisés, Université Catholique de Louvain @2 Louvain-La-Neuve @3 BEL @Z 3 aut.
A14 03      @1 Département de la Recherche Universitaire et Coopérative, Centre Européen de Recherche et de Technologie, Total Raffinage Distribution SA @2 Harfleur @3 FRA @Z 4 aut.
A15 01      @1 Dipartimento di Chimica Industriale ed Ingegneria dei Materiali, Università di Messina @2 98166 Messina @3 ITA @Z 1 aut. @Z 3 aut.
A15 02      @1 Dipartimento di Ingegneria Chimica e Alimentare, Università degli Studi di Salerno @2 84084 Fisciano @3 ITA @Z 2 aut. @Z 4 aut.
A20       @1 113-117
A21       @1 2002
A23 01      @0 ENG
A43 01      @1 INIST @2 21357 @5 354000101705390150
A44       @0 0000 @1 © 2002 INIST-CNRS. All rights reserved.
A45       @0 28 ref.
A47 01  1    @0 02-0429724
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Catalysis today
A66 01      @0 NLD
C01 01    ENG  @0 Three Mg-Al hydrotalcites containing cobalt(II) phthalocyanine were prepared by direct synthesis, anion exchange and structure reconstruction. Differences in physicochemical properties and mechanical resistance were observed. The results of the mercaptan oxidation reaction were compared to those obtained with an industrial non-basic impregnated active charcoal. An important activity difference in favor of the prepared catalysts was obtained, confirming that the adequate tuning of basic and oxidant properties lead to a promising catalyst.
C02 01  X    @0 001C01A03B
C03 01  X  FRE  @0 Etude expérimentale @5 01
C03 01  X  ENG  @0 Experimental study @5 01
C03 01  X  SPA  @0 Estudio experimental @5 01
C03 02  X  FRE  @0 Hydrotalcite @2 NK @2 FR @5 02
C03 02  X  ENG  @0 Hydrotalcite @2 NK @2 FR @5 02
C03 02  X  SPA  @0 Hidrotalcita @2 NK @2 FR @5 02
C03 03  X  FRE  @0 Cobalt complexe @1 ACT @5 04
C03 03  X  ENG  @0 Cobalt complex @1 ACT @5 04
C03 03  X  SPA  @0 Cobalto complejo @1 ACT @5 04
C03 04  X  FRE  @0 Coordinat organique @5 05
C03 04  X  ENG  @0 Organic ligand @5 05
C03 04  X  SPA  @0 Ligando orgánico @5 05
C03 05  X  FRE  @0 Phtalocyanine métallique @2 FC @5 06
C03 05  X  ENG  @0 Metallophthalocyanine @2 FC @5 06
C03 05  X  SPA  @0 Ftalocianina metálica @2 FC @5 06
C03 06  X  FRE  @0 Réaction catalytique @5 07
C03 06  X  ENG  @0 Catalytic reaction @5 07
C03 06  X  SPA  @0 Reacción catalítica @5 07
C03 07  X  FRE  @0 Oxydation @5 08
C03 07  X  ENG  @0 Oxidation @5 08
C03 07  X  SPA  @0 Oxidación @5 08
C03 08  X  FRE  @0 Thiol @1 ENT @5 09
C03 08  X  ENG  @0 Thiol @1 ENT @5 09
C03 08  X  SPA  @0 Tiol @1 ENT @5 09
C03 09  X  FRE  @0 Sulfure @2 NA @5 10
C03 09  X  ENG  @0 Sulfides @2 NA @5 10
C03 09  X  SPA  @0 Sulfuro @2 NA @5 10
C03 10  X  FRE  @0 Activité catalytique @5 13
C03 10  X  ENG  @0 Catalyst activity @5 13
C03 10  X  SPA  @0 Actividad catalítica @5 13
C03 11  X  FRE  @0 Composé insertion @5 14
C03 11  X  ENG  @0 Intercalation compound @5 14
C03 11  X  SPA  @0 Compuesto inserción @5 14
C03 12  X  FRE  @0 Catalyse hétérogène @5 15
C03 12  X  ENG  @0 Heterogeneous catalysis @5 15
C03 12  X  SPA  @0 Catálisis heterogénea @5 15
C03 13  X  FRE  @0 Disulfure @1 FIN @2 NK @4 INC @5 32
C07 01  X  FRE  @0 Métal transition Complexe @2 NC @2 NA @5 03
C07 01  X  ENG  @0 Transition metal Complexes @2 NC @2 NA @5 03
C07 01  X  SPA  @0 Metal transición Complejo @2 NC @2 NA @5 03
N21       @1 245
N82       @1 PSI
pR  
A30 01  1  ENG  @1 European Workshop on Environmental Catalysis @2 3 @3 Maiori ITA @4 2001-05-02

Format Inist (serveur)

NO : PASCAL 02-0429724 INIST
ET : Oxidation of mercaptans in light oil sweetening by cobalt(II) phthalocyanine-hydrotalcite catalysts
AU : CHATTI (I.); GHORBEL (A.); GRANGE (P.); COLIN (J. M.); CENTI (Gabriele); CIAMBELLI (Paolo); PERATHONER (Siglinda); RUSSO (Paola)
AF : Laboratoire de Chimie des Matériaux et Catalyse, Département de chimie, Faculté des Sciences de Tunis/Tunis 1060/Tunisie (1 aut., 2 aut.); Unité de Catalyse et Chimie des Matériaux Divisés, Université Catholique de Louvain/Louvain-La-Neuve/Belgique (3 aut.); Département de la Recherche Universitaire et Coopérative, Centre Européen de Recherche et de Technologie, Total Raffinage Distribution SA/Harfleur/France (4 aut.); Dipartimento di Chimica Industriale ed Ingegneria dei Materiali, Università di Messina/98166 Messina/Italie (1 aut., 3 aut.); Dipartimento di Ingegneria Chimica e Alimentare, Università degli Studi di Salerno/84084 Fisciano/Italie (2 aut., 4 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Catalysis today; ISSN 0920-5861; Coden CATTEA; Pays-Bas; Da. 2002; Vol. 75; No. 1-4; Pp. 113-117; Bibl. 28 ref.
LA : Anglais
EA : Three Mg-Al hydrotalcites containing cobalt(II) phthalocyanine were prepared by direct synthesis, anion exchange and structure reconstruction. Differences in physicochemical properties and mechanical resistance were observed. The results of the mercaptan oxidation reaction were compared to those obtained with an industrial non-basic impregnated active charcoal. An important activity difference in favor of the prepared catalysts was obtained, confirming that the adequate tuning of basic and oxidant properties lead to a promising catalyst.
CC : 001C01A03B
FD : Etude expérimentale; Hydrotalcite; Cobalt complexe; Coordinat organique; Phtalocyanine métallique; Réaction catalytique; Oxydation; Thiol; Sulfure; Activité catalytique; Composé insertion; Catalyse hétérogène; Disulfure
FG : Métal transition Complexe
ED : Experimental study; Hydrotalcite; Cobalt complex; Organic ligand; Metallophthalocyanine; Catalytic reaction; Oxidation; Thiol; Sulfides; Catalyst activity; Intercalation compound; Heterogeneous catalysis
EG : Transition metal Complexes
SD : Estudio experimental; Hidrotalcita; Cobalto complejo; Ligando orgánico; Ftalocianina metálica; Reacción catalítica; Oxidación; Tiol; Sulfuro; Actividad catalítica; Compuesto inserción; Catálisis heterogénea
LO : INIST-21357.354000101705390150
ID : 02-0429724

Links to Exploration step

Pascal:02-0429724

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<fC03 i1="05" i2="X" l="SPA">
<s0>Ftalocianina metálica</s0>
<s2>FC</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Réaction catalytique</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Catalytic reaction</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Reacción catalítica</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Oxydation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Oxidation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Oxidación</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Thiol</s0>
<s1>ENT</s1>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Thiol</s0>
<s1>ENT</s1>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Tiol</s0>
<s1>ENT</s1>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Sulfure</s0>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Sulfides</s0>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Sulfuro</s0>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Activité catalytique</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Catalyst activity</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Actividad catalítica</s0>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Composé insertion</s0>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Intercalation compound</s0>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Compuesto inserción</s0>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Catalyse hétérogène</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Heterogeneous catalysis</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Catálisis heterogénea</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Disulfure</s0>
<s1>FIN</s1>
<s2>NK</s2>
<s4>INC</s4>
<s5>32</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Métal transition Complexe</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>03</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Transition metal Complexes</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>03</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Metal transición Complejo</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>03</s5>
</fC07>
<fN21>
<s1>245</s1>
</fN21>
<fN82>
<s1>PSI</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>European Workshop on Environmental Catalysis</s1>
<s2>3</s2>
<s3>Maiori ITA</s3>
<s4>2001-05-02</s4>
</fA30>
</pR>
</standard>
<server>
<NO>PASCAL 02-0429724 INIST</NO>
<ET>Oxidation of mercaptans in light oil sweetening by cobalt(II) phthalocyanine-hydrotalcite catalysts</ET>
<AU>CHATTI (I.); GHORBEL (A.); GRANGE (P.); COLIN (J. M.); CENTI (Gabriele); CIAMBELLI (Paolo); PERATHONER (Siglinda); RUSSO (Paola)</AU>
<AF>Laboratoire de Chimie des Matériaux et Catalyse, Département de chimie, Faculté des Sciences de Tunis/Tunis 1060/Tunisie (1 aut., 2 aut.); Unité de Catalyse et Chimie des Matériaux Divisés, Université Catholique de Louvain/Louvain-La-Neuve/Belgique (3 aut.); Département de la Recherche Universitaire et Coopérative, Centre Européen de Recherche et de Technologie, Total Raffinage Distribution SA/Harfleur/France (4 aut.); Dipartimento di Chimica Industriale ed Ingegneria dei Materiali, Università di Messina/98166 Messina/Italie (1 aut., 3 aut.); Dipartimento di Ingegneria Chimica e Alimentare, Università degli Studi di Salerno/84084 Fisciano/Italie (2 aut., 4 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Catalysis today; ISSN 0920-5861; Coden CATTEA; Pays-Bas; Da. 2002; Vol. 75; No. 1-4; Pp. 113-117; Bibl. 28 ref.</SO>
<LA>Anglais</LA>
<EA>Three Mg-Al hydrotalcites containing cobalt(II) phthalocyanine were prepared by direct synthesis, anion exchange and structure reconstruction. Differences in physicochemical properties and mechanical resistance were observed. The results of the mercaptan oxidation reaction were compared to those obtained with an industrial non-basic impregnated active charcoal. An important activity difference in favor of the prepared catalysts was obtained, confirming that the adequate tuning of basic and oxidant properties lead to a promising catalyst.</EA>
<CC>001C01A03B</CC>
<FD>Etude expérimentale; Hydrotalcite; Cobalt complexe; Coordinat organique; Phtalocyanine métallique; Réaction catalytique; Oxydation; Thiol; Sulfure; Activité catalytique; Composé insertion; Catalyse hétérogène; Disulfure</FD>
<FG>Métal transition Complexe</FG>
<ED>Experimental study; Hydrotalcite; Cobalt complex; Organic ligand; Metallophthalocyanine; Catalytic reaction; Oxidation; Thiol; Sulfides; Catalyst activity; Intercalation compound; Heterogeneous catalysis</ED>
<EG>Transition metal Complexes</EG>
<SD>Estudio experimental; Hidrotalcita; Cobalto complejo; Ligando orgánico; Ftalocianina metálica; Reacción catalítica; Oxidación; Tiol; Sulfuro; Actividad catalítica; Compuesto inserción; Catálisis heterogénea</SD>
<LO>INIST-21357.354000101705390150</LO>
<ID>02-0429724</ID>
</server>
</inist>
</record>

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