Oxidative dehydrogenation of ethane and propane over Ca-Co-P catalysts
Identifieur interne :
000182 ( PascalFrancis/Corpus );
précédent :
000181;
suivant :
000183
Oxidative dehydrogenation of ethane and propane over Ca-Co-P catalysts
Auteurs : A. Aaddane ;
M. Kacimi ;
M. ZiyadSource :
-
Journal de physique. IV [ 1155-4339 ] ; 2005.
RBID : Pascal:05-0362649
Descripteurs français
- Pascal (Inist)
- Oxydation,
Déshydrogénation,
Ethane,
Propane,
Alcane,
Hydrocarbure,
Calcium Phosphate,
Cobalt Phosphate,
Composé quaternaire,
Métal transition Composé,
Catalyse hétérogène.
English descriptors
- KwdEn :
- Alkane,
Calcium Phosphates,
Cobalt Phosphates,
Dehydrogenation,
Ethane,
Heterogeneous catalysis,
Hydrocarbon,
Oxidation,
Propane,
Quaternary compound,
Transition metal Compounds.
Abstract
Different compositions of calcium-cobalt phosphate Ca3-xCox(PO4)2 (0≤x≤3) were synthesized by the precipitation method. The X-ray diffraction patterns showed that in the range 0 ≤x≤0.3 the solid displays a whitlockite-type structure which belongs to rhombohedral symmetry with the space group R3c (Z = 6). U.V-visible investigations showed that Co2+ ions occupy the M(5) sites of the phosphate. The same technique revealed that all cobalt cations exist under the +II oxidation state. Pure tricalcium phosphate β-Ca3(PO4)2 was found inactive in the ODH reactions of ethane and propane. An increase of Co2+ concentration in the catalysts improved the performances.
Notice en format standard (ISO 2709)
Pour connaître la documentation sur le format Inist Standard.
pA |
A01 | 01 | 1 | | @0 1155-4339 |
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A03 | | 1 | | @0 J. phys., IV |
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A05 | | | | @2 123 |
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A08 | 01 | 1 | ENG | @1 Oxidative dehydrogenation of ethane and propane over Ca-Co-P catalysts |
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A09 | 01 | 1 | ENG | @1 REMCES IX: Proceedings of the 9th International Seminar on the Physical Chemistry of Solid State Materials |
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A11 | 01 | 1 | | @1 AADDANE (A.) |
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A11 | 02 | 1 | | @1 KACIMI (M.) |
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A11 | 03 | 1 | | @1 ZIYAD (M.) |
---|
A12 | 01 | 1 | | @1 BENLHACHEMI (Abdeljalil) @9 ed. |
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A12 | 02 | 1 | | @1 BENYAICH (H.) @9 ed. |
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A12 | 03 | 1 | | @1 BOUABID (Khalid) @9 ed. |
---|
A12 | 04 | 1 | | @1 BOUKHARI (A.) @9 ed. |
---|
A12 | 05 | 1 | | @1 ELAATMANI (M.) @9 ed. |
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A12 | 06 | 1 | | @1 ES-SAKHI (B.) @9 ed. |
---|
A12 | 07 | 1 | | @1 IHLAL (A.) @9 ed. |
---|
A12 | 08 | 1 | | @1 KHAIROUNE (S.) @9 ed. |
---|
A12 | 09 | 1 | | @1 MANSOURI (I.) @9 ed. |
---|
A12 | 10 | 1 | | @1 NOUNAH (Abderrahman) @9 ed. |
---|
A12 | 11 | 1 | | @1 TAHA (Mohamed) @9 ed. |
---|
A12 | 12 | 1 | | @1 ZAHIDI (E.) @9 ed. |
---|
A14 | 01 | | | @1 Faculté des Sciences, Département de Chimie, Laboratoire de Physico-Chimie des Matériaux et Catalyse, Avenue Ibn Battouta, BP. 1014 @2 Rabat @3 MAR @Z 1 aut. @Z 2 aut. @Z 3 aut. |
---|
A15 | 01 | | | @1 Faculté des Sciences, Cité Dakhla @2 Agadir @3 MAR @Z 1 aut. @Z 3 aut. @Z 11 aut. |
---|
A15 | 02 | | | @1 Ecole Supérieure de Technologie @2 Salé Médina @3 MAR @Z 10 aut. |
---|
A18 | 01 | 1 | | @1 IBN ZOHR University. Faculty of Sciences @2 Agadir @3 MAR @9 patr. |
---|
A20 | | | | @1 151-154 |
---|
A21 | | | | @1 2005 |
---|
A23 | 01 | | | @0 ENG |
---|
A43 | 01 | | | @1 INIST @2 125C @5 354000126872900250 |
---|
A44 | | | | @0 0000 @1 © 2005 INIST-CNRS. All rights reserved. |
---|
A45 | | | | @0 13 ref. |
---|
A47 | 01 | 1 | | @0 05-0362649 |
---|
A60 | | | | @1 P @2 C |
---|
A61 | | | | @0 A |
---|
A64 | 01 | 1 | | @0 Journal de physique. IV |
---|
A66 | 01 | | | @0 FRA |
---|
C01 | 01 | | ENG | @0 Different compositions of calcium-cobalt phosphate Ca3-xCox(PO4)2 (0≤x≤3) were synthesized by the precipitation method. The X-ray diffraction patterns showed that in the range 0 ≤x≤0.3 the solid displays a whitlockite-type structure which belongs to rhombohedral symmetry with the space group R3c (Z = 6). U.V-visible investigations showed that Co2+ ions occupy the M(5) sites of the phosphate. The same technique revealed that all cobalt cations exist under the +II oxidation state. Pure tricalcium phosphate β-Ca3(PO4)2 was found inactive in the ODH reactions of ethane and propane. An increase of Co2+ concentration in the catalysts improved the performances. |
---|
C02 | 01 | X | | @0 001C01A03 |
---|
C03 | 01 | X | FRE | @0 Oxydation @5 01 |
---|
C03 | 01 | X | ENG | @0 Oxidation @5 01 |
---|
C03 | 01 | X | SPA | @0 Oxidación @5 01 |
---|
C03 | 02 | X | FRE | @0 Déshydrogénation @5 02 |
---|
C03 | 02 | X | ENG | @0 Dehydrogenation @5 02 |
---|
C03 | 02 | X | SPA | @0 Deshidrogenación @5 02 |
---|
C03 | 03 | X | FRE | @0 Ethane @2 NK @5 03 |
---|
C03 | 03 | X | ENG | @0 Ethane @2 NK @5 03 |
---|
C03 | 03 | X | SPA | @0 Etano @2 NK @5 03 |
---|
C03 | 04 | X | FRE | @0 Propane @2 NK @2 FX @5 04 |
---|
C03 | 04 | X | ENG | @0 Propane @2 NK @2 FX @5 04 |
---|
C03 | 04 | X | SPA | @0 Propano @2 NK @2 FX @5 04 |
---|
C03 | 05 | X | FRE | @0 Alcane @5 05 |
---|
C03 | 05 | X | ENG | @0 Alkane @5 05 |
---|
C03 | 05 | X | SPA | @0 Alcano @5 05 |
---|
C03 | 06 | X | FRE | @0 Hydrocarbure @2 FX @5 06 |
---|
C03 | 06 | X | ENG | @0 Hydrocarbon @2 FX @5 06 |
---|
C03 | 06 | X | SPA | @0 Hidrocarburo @2 FX @5 06 |
---|
C03 | 07 | X | FRE | @0 Calcium Phosphate @2 NC @2 FR @2 NA @5 07 |
---|
C03 | 07 | X | ENG | @0 Calcium Phosphates @2 NC @2 FR @2 NA @5 07 |
---|
C03 | 07 | X | SPA | @0 Calcio Fosfato @2 NC @2 FR @2 NA @5 07 |
---|
C03 | 08 | X | FRE | @0 Cobalt Phosphate @2 NC @2 NA @5 08 |
---|
C03 | 08 | X | ENG | @0 Cobalt Phosphates @2 NC @2 NA @5 08 |
---|
C03 | 08 | X | SPA | @0 Cobalto Fosfato @2 NC @2 NA @5 08 |
---|
C03 | 09 | X | FRE | @0 Composé quaternaire @5 09 |
---|
C03 | 09 | X | ENG | @0 Quaternary compound @5 09 |
---|
C03 | 09 | X | SPA | @0 Compuesto cuaternario @5 09 |
---|
C03 | 10 | X | FRE | @0 Métal transition Composé @2 NC @2 NA @5 10 |
---|
C03 | 10 | X | ENG | @0 Transition metal Compounds @2 NC @2 NA @5 10 |
---|
C03 | 10 | X | SPA | @0 Metal transición Compuesto @2 NC @2 NA @5 10 |
---|
C03 | 11 | X | FRE | @0 Catalyse hétérogène @5 11 |
---|
C03 | 11 | X | ENG | @0 Heterogeneous catalysis @5 11 |
---|
C03 | 11 | X | SPA | @0 Catálisis heterogénea @5 11 |
---|
N21 | | | | @1 255 |
---|
|
pR |
A30 | 01 | 1 | ENG | @1 REMCES International Seminar on the Physical Chemistry of Solid State Materials @2 9 @3 Agadir MAR @4 2002-10-30 |
---|
|
Format Inist (serveur)
NO : | PASCAL 05-0362649 INIST |
ET : | Oxidative dehydrogenation of ethane and propane over Ca-Co-P catalysts |
AU : | AADDANE (A.); KACIMI (M.); ZIYAD (M.); BENLHACHEMI (Abdeljalil); BENYAICH (H.); BOUABID (Khalid); BOUKHARI (A.); ELAATMANI (M.); ES-SAKHI (B.); IHLAL (A.); KHAIROUNE (S.); MANSOURI (I.); NOUNAH (Abderrahman); TAHA (Mohamed); ZAHIDI (E.) |
AF : | Faculté des Sciences, Département de Chimie, Laboratoire de Physico-Chimie des Matériaux et Catalyse, Avenue Ibn Battouta, BP. 1014/Rabat/Maroc (1 aut., 2 aut., 3 aut.); Faculté des Sciences, Cité Dakhla/Agadir/Maroc (1 aut., 3 aut., 11 aut.); Ecole Supérieure de Technologie/Salé Médina/Maroc (10 aut.) |
DT : | Publication en série; Congrès; Niveau analytique |
SO : | Journal de physique. IV; ISSN 1155-4339; France; Da. 2005; Vol. 123; Pp. 151-154; Bibl. 13 ref. |
LA : | Anglais |
EA : | Different compositions of calcium-cobalt phosphate Ca3-xCox(PO4)2 (0≤x≤3) were synthesized by the precipitation method. The X-ray diffraction patterns showed that in the range 0 ≤x≤0.3 the solid displays a whitlockite-type structure which belongs to rhombohedral symmetry with the space group R3c (Z = 6). U.V-visible investigations showed that Co2+ ions occupy the M(5) sites of the phosphate. The same technique revealed that all cobalt cations exist under the +II oxidation state. Pure tricalcium phosphate β-Ca3(PO4)2 was found inactive in the ODH reactions of ethane and propane. An increase of Co2+ concentration in the catalysts improved the performances. |
CC : | 001C01A03 |
FD : | Oxydation; Déshydrogénation; Ethane; Propane; Alcane; Hydrocarbure; Calcium Phosphate; Cobalt Phosphate; Composé quaternaire; Métal transition Composé; Catalyse hétérogène |
ED : | Oxidation; Dehydrogenation; Ethane; Propane; Alkane; Hydrocarbon; Calcium Phosphates; Cobalt Phosphates; Quaternary compound; Transition metal Compounds; Heterogeneous catalysis |
SD : | Oxidación; Deshidrogenación; Etano; Propano; Alcano; Hidrocarburo; Calcio Fosfato; Cobalto Fosfato; Compuesto cuaternario; Metal transición Compuesto; Catálisis heterogénea |
LO : | INIST-125C.354000126872900250 |
ID : | 05-0362649 |
Links to Exploration step
Pascal:05-0362649
Le document en format XML
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<series><title level="j" type="main">Journal de physique. IV</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alkane</term>
<term>Calcium Phosphates</term>
<term>Cobalt Phosphates</term>
<term>Dehydrogenation</term>
<term>Ethane</term>
<term>Heterogeneous catalysis</term>
<term>Hydrocarbon</term>
<term>Oxidation</term>
<term>Propane</term>
<term>Quaternary compound</term>
<term>Transition metal Compounds</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Oxydation</term>
<term>Déshydrogénation</term>
<term>Ethane</term>
<term>Propane</term>
<term>Alcane</term>
<term>Hydrocarbure</term>
<term>Calcium Phosphate</term>
<term>Cobalt Phosphate</term>
<term>Composé quaternaire</term>
<term>Métal transition Composé</term>
<term>Catalyse hétérogène</term>
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<front><div type="abstract" xml:lang="en">Different compositions of calcium-cobalt phosphate Ca<sub>3-x</sub>
Co<sub>x</sub>
(PO<sub>4</sub>
)<sub>2</sub>
(0≤x≤3) were synthesized by the precipitation method. The X-ray diffraction patterns showed that in the range 0 ≤x≤0.3 the solid displays a whitlockite-type structure which belongs to rhombohedral symmetry with the space group R3c (Z = 6). U.V-visible investigations showed that Co<sup>2+</sup>
ions occupy the M(5) sites of the phosphate. The same technique revealed that all cobalt cations exist under the +II oxidation state. Pure tricalcium phosphate β-Ca<sub>3</sub>
(PO<sub>4</sub>
)<sub>2</sub>
was found inactive in the ODH reactions of ethane and propane. An increase of Co<sup>2+</sup>
concentration in the catalysts improved the performances.</div>
</front>
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<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1155-4339</s0>
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<fA08 i1="01" i2="1" l="ENG"><s1>Oxidative dehydrogenation of ethane and propane over Ca-Co-P catalysts</s1>
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<fA09 i1="01" i2="1" l="ENG"><s1>REMCES IX: Proceedings of the 9th International Seminar on the Physical Chemistry of Solid State Materials</s1>
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<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<sZ>3 aut.</sZ>
<sZ>11 aut.</sZ>
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<fA60><s1>P</s1>
<s2>C</s2>
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<fA64 i1="01" i2="1"><s0>Journal de physique. IV</s0>
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<fA66 i1="01"><s0>FRA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Different compositions of calcium-cobalt phosphate Ca<sub>3-x</sub>
Co<sub>x</sub>
(PO<sub>4</sub>
)<sub>2</sub>
(0≤x≤3) were synthesized by the precipitation method. The X-ray diffraction patterns showed that in the range 0 ≤x≤0.3 the solid displays a whitlockite-type structure which belongs to rhombohedral symmetry with the space group R3c (Z = 6). U.V-visible investigations showed that Co<sup>2+</sup>
ions occupy the M(5) sites of the phosphate. The same technique revealed that all cobalt cations exist under the +II oxidation state. Pure tricalcium phosphate β-Ca<sub>3</sub>
(PO<sub>4</sub>
)<sub>2</sub>
was found inactive in the ODH reactions of ethane and propane. An increase of Co<sup>2+</sup>
concentration in the catalysts improved the performances.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C01A03</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Oxydation</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Oxidation</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Oxidación</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Déshydrogénation</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Dehydrogenation</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Deshidrogenación</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Ethane</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Ethane</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Etano</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Propane</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Propane</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Propano</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Alcane</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Alkane</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Alcano</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Hydrocarbure</s0>
<s2>FX</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Hydrocarbon</s0>
<s2>FX</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Hidrocarburo</s0>
<s2>FX</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Calcium Phosphate</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Calcium Phosphates</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Calcio Fosfato</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Cobalt Phosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Cobalt Phosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Cobalto Fosfato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Composé quaternaire</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Quaternary compound</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Compuesto cuaternario</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Métal transition Composé</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Transition metal Compounds</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Metal transición Compuesto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Catalyse hétérogène</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Heterogeneous catalysis</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Catálisis heterogénea</s0>
<s5>11</s5>
</fC03>
<fN21><s1>255</s1>
</fN21>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>REMCES International Seminar on the Physical Chemistry of Solid State Materials</s1>
<s2>9</s2>
<s3>Agadir MAR</s3>
<s4>2002-10-30</s4>
</fA30>
</pR>
</standard>
<server><NO>PASCAL 05-0362649 INIST</NO>
<ET>Oxidative dehydrogenation of ethane and propane over Ca-Co-P catalysts</ET>
<AU>AADDANE (A.); KACIMI (M.); ZIYAD (M.); BENLHACHEMI (Abdeljalil); BENYAICH (H.); BOUABID (Khalid); BOUKHARI (A.); ELAATMANI (M.); ES-SAKHI (B.); IHLAL (A.); KHAIROUNE (S.); MANSOURI (I.); NOUNAH (Abderrahman); TAHA (Mohamed); ZAHIDI (E.)</AU>
<AF>Faculté des Sciences, Département de Chimie, Laboratoire de Physico-Chimie des Matériaux et Catalyse, Avenue Ibn Battouta, BP. 1014/Rabat/Maroc (1 aut., 2 aut., 3 aut.); Faculté des Sciences, Cité Dakhla/Agadir/Maroc (1 aut., 3 aut., 11 aut.); Ecole Supérieure de Technologie/Salé Médina/Maroc (10 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Journal de physique. IV; ISSN 1155-4339; France; Da. 2005; Vol. 123; Pp. 151-154; Bibl. 13 ref.</SO>
<LA>Anglais</LA>
<EA>Different compositions of calcium-cobalt phosphate Ca<sub>3-x</sub>
Co<sub>x</sub>
(PO<sub>4</sub>
)<sub>2</sub>
(0≤x≤3) were synthesized by the precipitation method. The X-ray diffraction patterns showed that in the range 0 ≤x≤0.3 the solid displays a whitlockite-type structure which belongs to rhombohedral symmetry with the space group R3c (Z = 6). U.V-visible investigations showed that Co<sup>2+</sup>
ions occupy the M(5) sites of the phosphate. The same technique revealed that all cobalt cations exist under the +II oxidation state. Pure tricalcium phosphate β-Ca<sub>3</sub>
(PO<sub>4</sub>
)<sub>2</sub>
was found inactive in the ODH reactions of ethane and propane. An increase of Co<sup>2+</sup>
concentration in the catalysts improved the performances.</EA>
<CC>001C01A03</CC>
<FD>Oxydation; Déshydrogénation; Ethane; Propane; Alcane; Hydrocarbure; Calcium Phosphate; Cobalt Phosphate; Composé quaternaire; Métal transition Composé; Catalyse hétérogène</FD>
<ED>Oxidation; Dehydrogenation; Ethane; Propane; Alkane; Hydrocarbon; Calcium Phosphates; Cobalt Phosphates; Quaternary compound; Transition metal Compounds; Heterogeneous catalysis</ED>
<SD>Oxidación; Deshidrogenación; Etano; Propano; Alcano; Hidrocarburo; Calcio Fosfato; Cobalto Fosfato; Compuesto cuaternario; Metal transición Compuesto; Catálisis heterogénea</SD>
<LO>INIST-125C.354000126872900250</LO>
<ID>05-0362649</ID>
</server>
</inist>
</record>
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