Study of the structural, thermodynamic and electrochemical properties of LaNi3.55Mn0.4Al0.3 (Co1-xFex)0.75 (0 ≤ x ≤ 1) compounds used as negative electrode in Ni-MH batteries
Identifieur interne : 000169 ( PascalFrancis/Corpus ); précédent : 000168; suivant : 000170Study of the structural, thermodynamic and electrochemical properties of LaNi3.55Mn0.4Al0.3 (Co1-xFex)0.75 (0 ≤ x ≤ 1) compounds used as negative electrode in Ni-MH batteries
Auteurs : M. Ayari ; V. Paul-Boncour ; J. Lamloumi ; H. Mathlouthi ; A. Percheron-GueganSource :
- Journal of alloys and compounds [ 0925-8388 ] ; 2006.
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- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
This study concerns the influence of iron for cobalt substitution on the structural, thermodynamic and electrochemical properties of the hydrides of poly-substituted LaNi3.55Mn0.4Al0.3(Co1-xFex)0.75(0 ≤ x ≤ 1) alloys used as material for negative electrode in Ni-MH batteries. The Fe substitution leads to an increase of the cell parameter, this increase is linear according to the rate of substitution, and a decrease of the equilibrium pressure in agreement with the geometric law. Nevertheless, it is observed that the Fe substitution leads to a deviation from the linear variation between the logarithm of the pressure and the cell volume observed for Co, Mn and Al for Ni substitution. The Fe for Co substitution leads also to a decrease of the solid-gas and electrochemical capacity.
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Format Inist (serveur)
NO : | PASCAL 06-0357007 INIST |
---|---|
ET : | Study of the structural, thermodynamic and electrochemical properties of LaNi3.55Mn0.4Al0.3 (Co1-xFex)0.75 (0 ≤ x ≤ 1) compounds used as negative electrode in Ni-MH batteries |
AU : | AYARI (M.); PAUL-BONCOUR (V.); LAMLOUMI (J.); MATHLOUTHI (H.); PERCHERON-GUEGAN (A.) |
AF : | Laboratoire de Mécanique, Matériaux et Procédés. ESSTT, 5 Avenue Taha Hussein/1008 Tunis/Tunisie (1 aut., 3 aut., 4 aut.); Laboratoire de Chimie Métallurgique des Terres Rares, GLVT, CNRS, 2-8 Rue Henri Dunant/94320 Thiais/France (2 aut., 5 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Journal of alloys and compounds; ISSN 0925-8388; Suisse; Da. 2006; Vol. 420; No. 1-2; Pp. 251-255; Bibl. 16 ref. |
LA : | Anglais |
EA : | This study concerns the influence of iron for cobalt substitution on the structural, thermodynamic and electrochemical properties of the hydrides of poly-substituted LaNi3.55Mn0.4Al 0.3(Co1-xFex)0.75(0 ≤ x ≤ 1) alloys used as material for negative electrode in Ni-MH batteries. The Fe substitution leads to an increase of the cell parameter, this increase is linear according to the rate of substitution, and a decrease of the equilibrium pressure in agreement with the geometric law. Nevertheless, it is observed that the Fe substitution leads to a deviation from the linear variation between the logarithm of the pressure and the cell volume observed for Co, Mn and Al for Ni substitution. The Fe for Co substitution leads also to a decrease of the solid-gas and electrochemical capacity. |
CC : | 001D06D05; 230 |
FD : | Propriété thermodynamique; Propriété électrochimique; Composition chimique; Paramètre cristallin; Voltammétrie cyclique; Batterie nickel hydrogène; Matériau électrode; Composé intermétallique |
ED : | Thermodynamic properties; Electrochemical properties; Chemical composition; Lattice parameters; Cyclic voltammetry; Nickel hydrogen batteries; Electrode material; Intermetallic compound |
SD : | Propiedad termodinámica; Propiedad electroquímica; Composición química; Parámetro cristalino; Voltametría cíclica; Material electrodo; Compuesto intermetálico |
LO : | INIST-1151.354000139000310440 |
ID : | 06-0357007 |
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Pascal:06-0357007Le document en format XML
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Mn<sub>0.4</sub>
Al<sub>0.3</sub>
(Co<sub>1-x</sub>
Fe<sub>x</sub>
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(0 ≤ x ≤ 1) compounds used as negative electrode in Ni-MH batteries</title>
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Mn<sub>0.4</sub>
Al<sub>0.3</sub>
(Co<sub>1-x</sub>
Fe<sub>x</sub>
)<sub>0.75</sub>
(0 ≤ x ≤ 1) compounds used as negative electrode in Ni-MH batteries</title>
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<front><div type="abstract" xml:lang="en">This study concerns the influence of iron for cobalt substitution on the structural, thermodynamic and electrochemical properties of the hydrides of poly-substituted LaNi<sub>3.55</sub>
Mn<sub>0.4</sub>
Al<sub>0.3</sub>
(Co<sub>1-x</sub>
Fe<sub>x</sub>
)<sub>0.75</sub>
(0 ≤ x ≤ 1) alloys used as material for negative electrode in Ni-MH batteries. The Fe substitution leads to an increase of the cell parameter, this increase is linear according to the rate of substitution, and a decrease of the equilibrium pressure in agreement with the geometric law. Nevertheless, it is observed that the Fe substitution leads to a deviation from the linear variation between the logarithm of the pressure and the cell volume observed for Co, Mn and Al for Ni substitution. The Fe for Co substitution leads also to a decrease of the solid-gas and electrochemical capacity.</div>
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Al<sub>0.3</sub>
(Co<sub>1-x</sub>
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Mn<sub>0.4</sub>
Al<sub>0.3</sub>
(Co<sub>1-x</sub>
Fe<sub>x</sub>
)<sub>0.75</sub>
(0 ≤ x ≤ 1) alloys used as material for negative electrode in Ni-MH batteries. The Fe substitution leads to an increase of the cell parameter, this increase is linear according to the rate of substitution, and a decrease of the equilibrium pressure in agreement with the geometric law. Nevertheless, it is observed that the Fe substitution leads to a deviation from the linear variation between the logarithm of the pressure and the cell volume observed for Co, Mn and Al for Ni substitution. The Fe for Co substitution leads also to a decrease of the solid-gas and electrochemical capacity.</s0>
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<server><NO>PASCAL 06-0357007 INIST</NO>
<ET>Study of the structural, thermodynamic and electrochemical properties of LaNi<sub>3.55</sub>
Mn<sub>0.4</sub>
Al<sub>0.3</sub>
(Co<sub>1-x</sub>
Fe<sub>x</sub>
)<sub>0.75</sub>
(0 ≤ x ≤ 1) compounds used as negative electrode in Ni-MH batteries</ET>
<AU>AYARI (M.); PAUL-BONCOUR (V.); LAMLOUMI (J.); MATHLOUTHI (H.); PERCHERON-GUEGAN (A.)</AU>
<AF>Laboratoire de Mécanique, Matériaux et Procédés. ESSTT, 5 Avenue Taha Hussein/1008 Tunis/Tunisie (1 aut., 3 aut., 4 aut.); Laboratoire de Chimie Métallurgique des Terres Rares, GLVT, CNRS, 2-8 Rue Henri Dunant/94320 Thiais/France (2 aut., 5 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of alloys and compounds; ISSN 0925-8388; Suisse; Da. 2006; Vol. 420; No. 1-2; Pp. 251-255; Bibl. 16 ref.</SO>
<LA>Anglais</LA>
<EA>This study concerns the influence of iron for cobalt substitution on the structural, thermodynamic and electrochemical properties of the hydrides of poly-substituted LaNi<sub>3.55</sub>
Mn<sub>0.4</sub>
Al<sub> 0.3</sub>
(Co<sub>1-x</sub>
Fe<sub>x</sub>
)<sub>0.75</sub>
(0 ≤ x ≤ 1) alloys used as material for negative electrode in Ni-MH batteries. The Fe substitution leads to an increase of the cell parameter, this increase is linear according to the rate of substitution, and a decrease of the equilibrium pressure in agreement with the geometric law. Nevertheless, it is observed that the Fe substitution leads to a deviation from the linear variation between the logarithm of the pressure and the cell volume observed for Co, Mn and Al for Ni substitution. The Fe for Co substitution leads also to a decrease of the solid-gas and electrochemical capacity.</EA>
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<ED>Thermodynamic properties; Electrochemical properties; Chemical composition; Lattice parameters; Cyclic voltammetry; Nickel hydrogen batteries; Electrode material; Intermetallic compound</ED>
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