Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N202 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde
Identifieur interne : 000090 ( PascalFrancis/Corpus ); précédent : 000089; suivant : 000091Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N202 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde
Auteurs : Lakhdar Sibous ; Embarek Bentouhami ; Amor Maïza ; Gilles M. Bouet ; MUSTAYEEN AHMED KHANSource :
- Journal of solution chemistry [ 0095-9782 ] ; 2010.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
The condensation of 2-hydroxybenzaldehyde or 2,4-dihydroxybenzaldehyde with 4,4'-diaminobiphenyl in absolute EtOH in a molar ratio 2:1 gave, respectively, the Schiff base ligands H2L1 or H2L2. The bases served as tetradentate ligands to coordinate CoII, NiII and CoII chlorides, leading to complexes where the metal:ligand ratio is 2:1. All of the compounds were characterized by elemental analysis, infrared, electronic and mass spectroscopy, 1H-n.m.r. and d.s.c. The cyclic voltammograms of the ligands and their complexes in DMF are discussed.
Notice en format standard (ISO 2709)
Pour connaître la documentation sur le format Inist Standard.
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Format Inist (serveur)
NO : | PASCAL 10-0289681 INIST |
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ET : | Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N202 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde |
AU : | SIBOUS (Lakhdar); BENTOUHAMI (Embarek); MAÏZA (Amor); BOUET (Gilles M.); MUSTAYEEN AHMED KHAN |
AF : | Département de Génie des Procédés, Faculté des Sciences de l'Ingénieur, Université Ferhat Abbas/Sétif 19000/Algérie (1 aut., 2 aut., 3 aut.); Chimie de Coordination, Faculté de Pharmacie, Université d'Angers, 16 Boulevard Daviers/49045 Angers/France (4 aut., 5 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Journal of solution chemistry; ISSN 0095-9782; Coden JSLCAG; Allemagne; Da. 2010; Vol. 39; No. 4; Pp. 511-521; Bibl. 48 ref. |
LA : | Anglais |
EA : | The condensation of 2-hydroxybenzaldehyde or 2,4-dihydroxybenzaldehyde with 4,4'-diaminobiphenyl in absolute EtOH in a molar ratio 2:1 gave, respectively, the Schiff base ligands H2L1 or H2L2. The bases served as tetradentate ligands to coordinate CoII, NiII and CoII chlorides, leading to complexes where the metal:ligand ratio is 2:1. All of the compounds were characterized by elemental analysis, infrared, electronic and mass spectroscopy, 1H-n.m.r. and d.s.c. The cyclic voltammograms of the ligands and their complexes in DMF are discussed. |
CC : | 001C01B; 001C01H |
FD : | Synthèse; Caractérisation; Electrochimie; Complexe de cobalt; Cobalt II; Complexe de nickel; Nickel II; Complexe de cadmium; Cadmium II; Voltammétrie cyclique; Condensation; Base Schiff; Chlorure |
ED : | Synthesis; Characterization; Electrochemistry; Cobalt complex; Cobalt II; Nickel complex; Nickel II; Cadmium complex; Cadmium II; Cyclic voltammetry; Condensation; Schiff base; Chlorides |
SD : | Síntesis; Caracterización; Electroquímica; Cobalto complejo; Cobalto II; Níquel complejo; Niquel II; Cadmio complejo; Cadmio II; Voltametría cíclica; Condensación; Base Schiff; Cloruro |
LO : | INIST-15610.354000181181000060 |
ID : | 10-0289681 |
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Pascal:10-0289681Le document en format XML
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, Ni<sup>II</sup>
and Cd<sup>II</sup>
Complexes with N<sub>2</sub>
0<sub>2</sub>
Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, Characterization and Electrochemical Behavior of Co<sup>II</sup>
, Ni<sup>II</sup>
and Cd<sup>II</sup>
Complexes with N<sub>2</sub>
0<sub>2</sub>
Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde</title>
<author><name sortKey="Sibous, Lakhdar" sort="Sibous, Lakhdar" uniqKey="Sibous L" first="Lakhdar" last="Sibous">Lakhdar Sibous</name>
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<series><title level="j" type="main">Journal of solution chemistry</title>
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<term>Cobalt II</term>
<term>Cobalt complex</term>
<term>Condensation</term>
<term>Cyclic voltammetry</term>
<term>Electrochemistry</term>
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<term>Complexe de cobalt</term>
<term>Cobalt II</term>
<term>Complexe de nickel</term>
<term>Nickel II</term>
<term>Complexe de cadmium</term>
<term>Cadmium II</term>
<term>Voltammétrie cyclique</term>
<term>Condensation</term>
<term>Base Schiff</term>
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<front><div type="abstract" xml:lang="en">The condensation of 2-hydroxybenzaldehyde or 2,4-dihydroxybenzaldehyde with 4,4'-diaminobiphenyl in absolute EtOH in a molar ratio 2:1 gave, respectively, the Schiff base ligands H<sub>2</sub>
L1 or H<sub>2</sub>
L2. The bases served as tetradentate ligands to coordinate Co<sup>II</sup>
, Ni<sup>II</sup>
and Co<sup>II</sup>
chlorides, leading to complexes where the metal:ligand ratio is 2:1. All of the compounds were characterized by elemental analysis, infrared, electronic and mass spectroscopy, <sup>1</sup>
H-n.m.r. and d.s.c. The cyclic voltammograms of the ligands and their complexes in DMF are discussed.</div>
</front>
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Complexes with N<sub>2</sub>
0<sub>2</sub>
Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde</s1>
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<fA14 i1="01"><s1>Département de Génie des Procédés, Faculté des Sciences de l'Ingénieur, Université Ferhat Abbas</s1>
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<sZ>1 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>The condensation of 2-hydroxybenzaldehyde or 2,4-dihydroxybenzaldehyde with 4,4'-diaminobiphenyl in absolute EtOH in a molar ratio 2:1 gave, respectively, the Schiff base ligands H<sub>2</sub>
L1 or H<sub>2</sub>
L2. The bases served as tetradentate ligands to coordinate Co<sup>II</sup>
, Ni<sup>II</sup>
and Co<sup>II</sup>
chlorides, leading to complexes where the metal:ligand ratio is 2:1. All of the compounds were characterized by elemental analysis, infrared, electronic and mass spectroscopy, <sup>1</sup>
H-n.m.r. and d.s.c. The cyclic voltammograms of the ligands and their complexes in DMF are discussed.</s0>
</fC01>
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<s5>02</s5>
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<s5>04</s5>
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<s5>04</s5>
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<fC03 i1="05" i2="X" l="FRE"><s0>Cobalt II</s0>
<s2>NC</s2>
<s5>05</s5>
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<fC03 i1="05" i2="X" l="ENG"><s0>Cobalt II</s0>
<s2>NC</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Cobalto II</s0>
<s2>NC</s2>
<s5>05</s5>
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<fC03 i1="06" i2="X" l="FRE"><s0>Complexe de nickel</s0>
<s5>06</s5>
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<s5>06</s5>
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<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Nickel II</s0>
<s2>NC</s2>
<s5>07</s5>
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<fC03 i1="07" i2="X" l="ENG"><s0>Nickel II</s0>
<s2>NC</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Niquel II</s0>
<s2>NC</s2>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Complexe de cadmium</s0>
<s5>08</s5>
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<s5>08</s5>
</fC03>
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<s5>08</s5>
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<fC03 i1="09" i2="X" l="FRE"><s0>Cadmium II</s0>
<s2>NC</s2>
<s5>09</s5>
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<fC03 i1="09" i2="X" l="ENG"><s0>Cadmium II</s0>
<s2>NC</s2>
<s5>09</s5>
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<s2>NC</s2>
<s5>09</s5>
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<fC03 i1="10" i2="X" l="FRE"><s0>Voltammétrie cyclique</s0>
<s5>10</s5>
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<s5>10</s5>
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<s5>10</s5>
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<s5>11</s5>
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<fC03 i1="11" i2="X" l="ENG"><s0>Condensation</s0>
<s5>11</s5>
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<s5>11</s5>
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<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Schiff base</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Base Schiff</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Chlorure</s0>
<s2>NA</s2>
<s5>13</s5>
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<s2>NA</s2>
<s5>13</s5>
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<fC03 i1="13" i2="X" l="SPA"><s0>Cloruro</s0>
<s2>NA</s2>
<s5>13</s5>
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<fN21><s1>186</s1>
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<fN44 i1="01"><s1>OTO</s1>
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<fN82><s1>OTO</s1>
</fN82>
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<server><NO>PASCAL 10-0289681 INIST</NO>
<ET>Synthesis, Characterization and Electrochemical Behavior of Co<sup>II</sup>
, Ni<sup>II</sup>
and Cd<sup>II</sup>
Complexes with N<sub>2</sub>
0<sub>2</sub>
Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde</ET>
<AU>SIBOUS (Lakhdar); BENTOUHAMI (Embarek); MAÏZA (Amor); BOUET (Gilles M.); MUSTAYEEN AHMED KHAN</AU>
<AF>Département de Génie des Procédés, Faculté des Sciences de l'Ingénieur, Université Ferhat Abbas/Sétif 19000/Algérie (1 aut., 2 aut., 3 aut.); Chimie de Coordination, Faculté de Pharmacie, Université d'Angers, 16 Boulevard Daviers/49045 Angers/France (4 aut., 5 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of solution chemistry; ISSN 0095-9782; Coden JSLCAG; Allemagne; Da. 2010; Vol. 39; No. 4; Pp. 511-521; Bibl. 48 ref.</SO>
<LA>Anglais</LA>
<EA>The condensation of 2-hydroxybenzaldehyde or 2,4-dihydroxybenzaldehyde with 4,4'-diaminobiphenyl in absolute EtOH in a molar ratio 2:1 gave, respectively, the Schiff base ligands H<sub>2</sub>
L1 or H<sub>2</sub>
L2. The bases served as tetradentate ligands to coordinate Co<sup>II</sup>
, Ni<sup>II</sup>
and Co<sup>II</sup>
chlorides, leading to complexes where the metal:ligand ratio is 2:1. All of the compounds were characterized by elemental analysis, infrared, electronic and mass spectroscopy, <sup>1</sup>
H-n.m.r. and d.s.c. The cyclic voltammograms of the ligands and their complexes in DMF are discussed.</EA>
<CC>001C01B; 001C01H</CC>
<FD>Synthèse; Caractérisation; Electrochimie; Complexe de cobalt; Cobalt II; Complexe de nickel; Nickel II; Complexe de cadmium; Cadmium II; Voltammétrie cyclique; Condensation; Base Schiff; Chlorure</FD>
<ED>Synthesis; Characterization; Electrochemistry; Cobalt complex; Cobalt II; Nickel complex; Nickel II; Cadmium complex; Cadmium II; Cyclic voltammetry; Condensation; Schiff base; Chlorides</ED>
<SD>Síntesis; Caracterización; Electroquímica; Cobalto complejo; Cobalto II; Níquel complejo; Niquel II; Cadmio complejo; Cadmio II; Voltametría cíclica; Condensación; Base Schiff; Cloruro</SD>
<LO>INIST-15610.354000181181000060</LO>
<ID>10-0289681</ID>
</server>
</inist>
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