CobaltMaghrebV1, PascalFrancis, Checkpoint, bibRecord, 000358

Crystal structures of isotypical diphosphates PbCo3(P2O7)2 and PbFe3(P2O7)2

Identifieur interne : 000358 ( PascalFrancis/Checkpoint ); précédent : 000357; suivant : 000359

Crystal structures of isotypical diphosphates PbCo3(P2O7)2 and PbFe3(P2O7)2

Auteurs : A. Elmarzouki [Maroc] ; A. Boukhari [Maroc] ; A. Berrada [Maroc] ; E. M. Holt

Source :

Journal of solid state chemistry [ 0022-4596 ] ; 1995.

RBID : Pascal:95-0489047

Descripteurs français

Pascal (Inist)
- Etude expérimentale, XRD, Structure cristalline, Composé quaternaire, Plomb phosphate, Cobalt phosphate, Fer phosphate, Plomb Diphosphate, Cobalt Diphosphate, Fer Diphosphate, 6166F, PbCo3(P2O7)2, Co O P Pb, PbFe3(P2O7)2, Fe O P Pb.

English descriptors

KwdEn :
- Cobalt Pyrophosphates, Cobalt phosphates, Crystal structure, Experimental study, Iron Pyrophosphates, Iron phosphates, Lead Pyrophosphates, Lead phosphates, Quaternary compounds, XRD.

Abstract

Single crystals of the mixed metal diphosphates PbCo₃(P₂O₇)₂ (1) and PbFe₃(P₂O₇)₂ (II) have been prepared by direct fusion and characterized by single-crystal X-ray diffraction, for PbCo₃(P₂O₇)₂ (I), a = 7.275(5), b = 7.725(11), c = 9.511(4)Å, β = 111.89(4)°, monoclinic space group P2₁/c, V = 509.3(5) Å³, d_calC = 4.768 g cm^-3, Z = 2, R/R_w = 3.9/5.1% for 1192 observed reflections. For PbFe₃(P₂O₇)₂ (II), a = 7.487(1), b = 7.739(1), c = 9.516(2) Å, β = 111.95(1)°, monoclinic space group P2₁/c, V = 511.4(2)Å³, d_calC = 4.693 g cm^-3, Z = 2, R/R_w = 4.13/4.87% for 1153 observed reflections. (I) and (II) are isotypical with PbNi₃(P₂O7)₂ and SrNi₃(P₂O₇)₂. The solid lattice is characterized by layers of P₂O^4-₇ groups, parallel to the crystallographic plane (001) and joined by Pb²⁺ and Co²⁺ ions in (I) and Pb²⁺ and Fe²⁺ ions in (II). Lead is seen surrounded by eight oxygen atoms whereas the transition elements are found in chains of linked trimers extending in the [010] direction [Co-Co 3.182(3) and 3.256(3) Å ; Fe-Fe, 3.186(3) and 3.264 (3) Å] with distorted octahedral geometry at each metal atom.

Affiliations:

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 000356
to stream PascalFrancis, to step Curation: 000347

Links to Exploration step

Pascal:95-0489047

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Crystal structures of isotypical diphosphates PbCo<sub>3</sub>
(P<sub>2O7</sub>
)<sub>2</sub>
 and PbFe<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
</title>
<author><name sortKey="Elmarzouki, A" sort="Elmarzouki, A" uniqKey="Elmarzouki A" first="A." last="Elmarzouki">A. Elmarzouki</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Berrada, A" sort="Berrada, A" uniqKey="Berrada A" first="A." last="Berrada">A. Berrada</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Holt, E M" sort="Holt, E M" uniqKey="Holt E" first="E. M." last="Holt">E. M. Holt</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">95-0489047</idno>
<date when="1995">1995</date>
<idno type="stanalyst">PASCAL 95-0489047 INIST</idno>
<idno type="RBID">Pascal:95-0489047</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000356</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000347</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000358</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000358</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Crystal structures of isotypical diphosphates PbCo<sub>3</sub>
(P<sub>2O7</sub>
)<sub>2</sub>
 and PbFe<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
</title>
<author><name sortKey="Elmarzouki, A" sort="Elmarzouki, A" uniqKey="Elmarzouki A" first="A." last="Elmarzouki">A. Elmarzouki</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Berrada, A" sort="Berrada, A" uniqKey="Berrada A" first="A." last="Berrada">A. Berrada</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Holt, E M" sort="Holt, E M" uniqKey="Holt E" first="E. M." last="Holt">E. M. Holt</name>
</author>
</analytic>
<series><title level="j" type="main">Journal of solid state chemistry</title>
<title level="j" type="abbreviated">J. solid state chem.</title>
<idno type="ISSN">0022-4596</idno>
<imprint><date when="1995">1995</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Journal of solid state chemistry</title>
<title level="j" type="abbreviated">J. solid state chem.</title>
<idno type="ISSN">0022-4596</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt Pyrophosphates</term>
<term>Cobalt phosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Iron Pyrophosphates</term>
<term>Iron phosphates</term>
<term>Lead Pyrophosphates</term>
<term>Lead phosphates</term>
<term>Quaternary compounds</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>XRD</term>
<term>Structure cristalline</term>
<term>Composé quaternaire</term>
<term>Plomb phosphate</term>
<term>Cobalt phosphate</term>
<term>Fer phosphate</term>
<term>Plomb Diphosphate</term>
<term>Cobalt Diphosphate</term>
<term>Fer Diphosphate</term>
<term>6166F</term>
<term>PbCo3(P2O7)2</term>
<term>Co O P Pb</term>
<term>PbFe3(P2O7)2</term>
<term>Fe O P Pb</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Single crystals of the mixed metal diphosphates PbCo<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 (1) and PbFe<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 (II) have been prepared by direct fusion and characterized by single-crystal X-ray diffraction, for PbCo<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 (I), a = 7.275(5), b = 7.725(11), c = 9.511(4)Å, β = 111.89(4)°, monoclinic space group P2<sub>1</sub>
/c, V = 509.3(5) Å<sup>3</sup>
, d<sub>calC</sub>
 = 4.768 g cm<sup>-3</sup>
, Z = 2, R/R<sub>w</sub>
 = 3.9/5.1% for 1192 observed reflections. For PbFe<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 (II), a = 7.487(1), b = 7.739(1), c = 9.516(2) Å, β = 111.95(1)°, monoclinic space group P2<sub>1</sub>
/c, V = 511.4(2)Å<sup>3</sup>
, d<sub>calC</sub>
 = 4.693 g cm<sup>-3</sup>
, Z = 2, R/R<sub>w</sub>
 = 4.13/4.87% for 1153 observed reflections. (I) and (II) are isotypical with PbNi<sub>3</sub>
(P<sub>2</sub>
O7)<sub>2</sub>
 and SrNi<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
. The solid lattice is characterized by layers of P<sub>2</sub>
O<sup>4-</sup>
<sub>7</sub>
 groups, parallel to the crystallographic plane (001) and joined by Pb<sup>2+</sup>
 and Co<sup>2+</sup>
 ions in (I) and Pb<sup>2+</sup>
 and Fe<sup>2+</sup>
 ions in (II). Lead is seen surrounded by eight oxygen atoms whereas the transition elements are found in chains of linked trimers extending in the [010] direction [Co-Co 3.182(3) and 3.256(3) Å ; Fe-Fe, 3.186(3) and 3.264 (3) Å] with distorted octahedral geometry at each metal atom.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0022-4596</s0>
</fA01>
<fA02 i1="01"><s0>JSSCBI</s0>
</fA02>
<fA03 i2="1"><s0>J. solid state chem.</s0>
</fA03>
<fA05><s2>118</s2>
</fA05>
<fA06><s2>1</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Crystal structures of isotypical diphosphates PbCo<sub>3</sub>
(P<sub>2O7</sub>
)<sub>2</sub>
 and PbFe<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>ELMARZOUKI (A.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>BOUKHARI (A.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>BERRADA (A.)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>HOLT (E. M.)</s1>
</fA11>
<fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA20><s1>202-205</s1>
</fA20>
<fA21><s1>1995</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>14677</s2>
<s5>354000053869590310</s5>
</fA43>
<fA44><s0>0000</s0>
</fA44>
<fA45><s0>20 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>95-0489047</s0>
</fA47>
<fA60><s1>P</s1>
<s3>CC</s3>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of solid state chemistry</s0>
</fA64>
<fA66 i1="01"><s0>USA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Single crystals of the mixed metal diphosphates PbCo<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 (1) and PbFe<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 (II) have been prepared by direct fusion and characterized by single-crystal X-ray diffraction, for PbCo<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 (I), a = 7.275(5), b = 7.725(11), c = 9.511(4)Å, β = 111.89(4)°, monoclinic space group P2<sub>1</sub>
/c, V = 509.3(5) Å<sup>3</sup>
, d<sub>calC</sub>
 = 4.768 g cm<sup>-3</sup>
, Z = 2, R/R<sub>w</sub>
 = 3.9/5.1% for 1192 observed reflections. For PbFe<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 (II), a = 7.487(1), b = 7.739(1), c = 9.516(2) Å, β = 111.95(1)°, monoclinic space group P2<sub>1</sub>
/c, V = 511.4(2)Å<sup>3</sup>
, d<sub>calC</sub>
 = 4.693 g cm<sup>-3</sup>
, Z = 2, R/R<sub>w</sub>
 = 4.13/4.87% for 1153 observed reflections. (I) and (II) are isotypical with PbNi<sub>3</sub>
(P<sub>2</sub>
O7)<sub>2</sub>
 and SrNi<sub>3</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
. The solid lattice is characterized by layers of P<sub>2</sub>
O<sup>4-</sup>
<sub>7</sub>
 groups, parallel to the crystallographic plane (001) and joined by Pb<sup>2+</sup>
 and Co<sup>2+</sup>
 ions in (I) and Pb<sup>2+</sup>
 and Fe<sup>2+</sup>
 ions in (II). Lead is seen surrounded by eight oxygen atoms whereas the transition elements are found in chains of linked trimers extending in the [010] direction [Co-Co 3.182(3) and 3.256(3) Å ; Fe-Fe, 3.186(3) and 3.264 (3) Å] with distorted octahedral geometry at each metal atom.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F4</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Composé quaternaire</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Quaternary compounds</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Plomb phosphate</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Lead phosphates</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Cobalt phosphate</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Cobalt phosphates</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Fer phosphate</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Iron phosphates</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Plomb Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Lead Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Cobalt Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Cobalt Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Fer Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Iron Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>PbCo3(P2O7)2</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Co O P Pb</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>PbFe3(P2O7)2</s0>
<s4>INC</s4>
<s5>94</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Fe O P Pb</s0>
<s4>INC</s4>
<s5>95</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>04</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>04</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>06</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>06</s5>
</fC07>
<fN21><s1>275</s1>
</fN21>
</pA>
</standard>
</inist>
<affiliations><list><country><li>Maroc</li>
</country>
<region><li>Rabat-Salé-Kénitra</li>
</region>
<settlement><li>Rabat</li>
</settlement>
</list>
<tree><noCountry><name sortKey="Holt, E M" sort="Holt, E M" uniqKey="Holt E" first="E. M." last="Holt">E. M. Holt</name>
</noCountry>
<country name="Maroc"><region name="Rabat-Salé-Kénitra"><name sortKey="Elmarzouki, A" sort="Elmarzouki, A" uniqKey="Elmarzouki A" first="A." last="Elmarzouki">A. Elmarzouki</name>
</region>
<name sortKey="Berrada, A" sort="Berrada, A" uniqKey="Berrada A" first="A." last="Berrada">A. Berrada</name>
<name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/PascalFrancis/Checkpoint

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000358 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/PascalFrancis/Checkpoint/biblio.hfd -nk 000358 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    PascalFrancis
   |étape=   Checkpoint
   |type=    RBID
   |clé=     Pascal:95-0489047
   |texte=   Crystal structures of isotypical diphosphates PbCo3(P2O7)2 and PbFe3(P2O7)2
}}

This area was generated with Dilib version V0.6.32.
Data generation: Tue Nov 14 12:56:51 2017. Site generation: Mon Feb 12 07:59:49 2024

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

Crystal structures of isotypical diphosphates PbCo3(P2O7)2 and PbFe3(P2O7)2

Crystal structures of isotypical diphosphates PbCo3(P2O7)2 and PbFe3(P2O7)2

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri