Electrical and magnetic properties of new mixed transition metal sulfides BaKCu3MS4 (M= Mn, Co, Ni)
Identifieur interne : 000267 ( PascalFrancis/Checkpoint ); précédent : 000266; suivant : 000268Electrical and magnetic properties of new mixed transition metal sulfides BaKCu3MS4 (M= Mn, Co, Ni)
Auteurs : M. Mouallem-Bahout [France] ; O. Pena [France] ; C. Carel [France] ; A. Ouammou [Maroc]Source :
- Journal of solid state chemistry [ 0022-4596 ] ; 2001.
Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Susceptibilité magnétique, Loi Curie Weiss, Polycristal, Diffraction RX, Structure cristalline, Conductivité électrique, Baryum sulfure, Potassium sulfure, Cuivre sulfure, Manganèse sulfure, Cobalt sulfure, Nickel sulfure, BaKCu3NiS4, Ba Cu K Ni S, 7530C, 7560E, 7220F, 6166F, BaKCu3MnS4, Ba Cu K Mn S, BaKCu3CoS4, Ba Co Cu K S.
English descriptors
- KwdEn :
Abstract
New transition metal sulfides BaKCu3MS4 (M = Mn, Co, Ni) were prepared from BaCO3, K2CO3, and the corresponding transition metal oxides by CS2/Ar sulfurization. The materials are based on a common structural pattern consisting of 2-D arrangements of MS4 tetrahedra linked by edges, crystallizing in the tetragonal ThCr2Si2-type structure in space group I4/mmm. Electrical resistivity measurements show that the new phases are semiconducting. The temperature dependence of magnetic susceptibility shows different behaviors depending on the substituting transition element: the data for BaKCu3MnS4 can be fitted to the Curie-Weiss equation (μeff = 2.50 μB per manganese ion) while magnetic ordering occurs for BaKCu3CoS4 (TN ∼ 12 K). BaKCu3NiS4 exhibits temperature-independent paramagnetic behavior.
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Pena</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire CSIM, UMR du CNRS 6511, Université de Rennes 1 CS 74205</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author><author><name sortKey="Carel, C" sort="Carel, C" uniqKey="Carel C" first="C." last="Carel">C. Carel</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire CSIM, UMR du CNRS 6511, Université de Rennes 1 CS 74205</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author><author><name sortKey="Ouammou, A" sort="Ouammou, A" uniqKey="Ouammou A" first="A." last="Ouammou">A. Ouammou</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire Matériaux et Protection de l'Environnement, Département de Chimie, Faculté des Sciences Dhar Mehraz, Université Sidi Mohamed Ben Abdellah. B.P.</s1><s2>1796 Atlas, Fès</s2><s3>MAR</s3><sZ>4 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>1796 Atlas, Fès</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">01-0215466</idno><date when="2001">2001</date><idno type="stanalyst">PASCAL 01-0215466 INIST</idno><idno type="RBID">Pascal:01-0215466</idno><idno type="wicri:Area/PascalFrancis/Corpus">000275</idno><idno type="wicri:Area/PascalFrancis/Curation">000020</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000267</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000267</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Electrical and magnetic properties of new mixed transition metal sulfides BaKCu<sub>3</sub>MS<sub>4</sub> (M= Mn, Co, Ni)</title><author><name sortKey="Mouallem Bahout, M" sort="Mouallem Bahout, M" uniqKey="Mouallem Bahout M" first="M." last="Mouallem-Bahout">M. Mouallem-Bahout</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire CSIM, UMR du CNRS 6511, Université de Rennes 1 CS 74205</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author><author><name sortKey="Pena, O" sort="Pena, O" uniqKey="Pena O" first="O." last="Pena">O. Pena</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire CSIM, UMR du CNRS 6511, Université de Rennes 1 CS 74205</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author><author><name sortKey="Carel, C" sort="Carel, C" uniqKey="Carel C" first="C." last="Carel">C. Carel</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire CSIM, UMR du CNRS 6511, Université de Rennes 1 CS 74205</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author><author><name sortKey="Ouammou, A" sort="Ouammou, A" uniqKey="Ouammou A" first="A." last="Ouammou">A. Ouammou</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire Matériaux et Protection de l'Environnement, Département de Chimie, Faculté des Sciences Dhar Mehraz, Université Sidi Mohamed Ben Abdellah. B.P.</s1><s2>1796 Atlas, Fès</s2><s3>MAR</s3><sZ>4 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>1796 Atlas, Fès</wicri:noRegion></affiliation></author></analytic><series><title level="j" type="main">Journal of solid state chemistry</title><title level="j" type="abbreviated">J. solid state chem.</title><idno type="ISSN">0022-4596</idno><imprint><date when="2001">2001</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Journal of solid state chemistry</title><title level="j" type="abbreviated">J. solid state chem.</title><idno type="ISSN">0022-4596</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Barium sulfides</term><term>Cobalt sulfides</term><term>Copper sulfides</term><term>Crystal structure</term><term>Curie-Weiss law</term><term>Electrical conductivity</term><term>Experimental study</term><term>Magnetic susceptibility</term><term>Manganese sulfides</term><term>Nickel sulfides</term><term>Polycrystals</term><term>Potassium sulfides</term><term>XRD</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Susceptibilité magnétique</term><term>Loi Curie Weiss</term><term>Polycristal</term><term>Diffraction RX</term><term>Structure cristalline</term><term>Conductivité électrique</term><term>Baryum sulfure</term><term>Potassium sulfure</term><term>Cuivre sulfure</term><term>Manganèse sulfure</term><term>Cobalt sulfure</term><term>Nickel sulfure</term><term>BaKCu3NiS4</term><term>Ba Cu K Ni S</term><term>7530C</term><term>7560E</term><term>7220F</term><term>6166F</term><term>BaKCu3MnS4</term><term>Ba Cu K Mn S</term><term>BaKCu3CoS4</term><term>Ba Co Cu K S</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">New transition metal sulfides BaKCu<sub>3</sub>MS<sub>4</sub> (M = Mn, Co, Ni) were prepared from BaCO<sub>3</sub>, K<sub>2</sub>CO<sub>3</sub>, and the corresponding transition metal oxides by CS<sub>2</sub>/Ar sulfurization. The materials are based on a common structural pattern consisting of 2-D arrangements of MS<sub>4</sub> tetrahedra linked by edges, crystallizing in the tetragonal ThCr<sub>2</sub>Si<sub>2</sub>-type structure in space group I4/mmm. Electrical resistivity measurements show that the new phases are semiconducting. The temperature dependence of magnetic susceptibility shows different behaviors depending on the substituting transition element: the data for BaKCu<sub>3</sub>MnS<sub>4</sub> can be fitted to the Curie-Weiss equation (μ<sub>eff</sub> = 2.50 μ<sub>B</sub> per manganese ion) while magnetic ordering occurs for BaKCu<sub>3</sub>CoS<sub>4</sub> (T<sub>N</sub> ∼ 12 K). BaKCu<sub>3</sub>NiS<sub>4</sub> exhibits temperature-independent paramagnetic behavior.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0022-4596</s0></fA01><fA02 i1="01"><s0>JSSCBI</s0></fA02><fA03 i2="1"><s0>J. solid state chem.</s0></fA03><fA05><s2>157</s2></fA05><fA06><s2>1</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Electrical and magnetic properties of new mixed transition metal sulfides BaKCu<sub>3</sub>MS<sub>4</sub> (M= Mn, Co, Ni)</s1></fA08><fA11 i1="01" i2="1"><s1>MOUALLEM-BAHOUT (M.)</s1></fA11><fA11 i1="02" i2="1"><s1>PENA (O.)</s1></fA11><fA11 i1="03" i2="1"><s1>CAREL (C.)</s1></fA11><fA11 i1="04" i2="1"><s1>OUAMMOU (A.)</s1></fA11><fA14 i1="01"><s1>Laboratoire CSIM, UMR du CNRS 6511, Université de Rennes 1 CS 74205</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></fA14><fA14 i1="02"><s1>Laboratoire Matériaux et Protection de l'Environnement, Département de Chimie, Faculté des Sciences Dhar Mehraz, Université Sidi Mohamed Ben Abdellah. B.P.</s1><s2>1796 Atlas, Fès</s2><s3>MAR</s3><sZ>4 aut.</sZ></fA14><fA20><s1>144-148</s1></fA20><fA21><s1>2001</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>14677</s2><s5>354000098108890190</s5></fA43><fA44><s0>0000</s0><s1>© 2001 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>25 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>01-0215466</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Journal of solid state chemistry</s0></fA64><fA66 i1="01"><s0>USA</s0></fA66><fC01 i1="01" l="ENG"><s0>New transition metal sulfides BaKCu<sub>3</sub>MS<sub>4</sub> (M = Mn, Co, Ni) were prepared from BaCO<sub>3</sub>, K<sub>2</sub>CO<sub>3</sub>, and the corresponding transition metal oxides by CS<sub>2</sub>/Ar sulfurization. The materials are based on a common structural pattern consisting of 2-D arrangements of MS<sub>4</sub> tetrahedra linked by edges, crystallizing in the tetragonal ThCr<sub>2</sub>Si<sub>2</sub>-type structure in space group I4/mmm. Electrical resistivity measurements show that the new phases are semiconducting. The temperature dependence of magnetic susceptibility shows different behaviors depending on the substituting transition element: the data for BaKCu<sub>3</sub>MnS<sub>4</sub> can be fitted to the Curie-Weiss equation (μ<sub>eff</sub> = 2.50 μ<sub>B</sub> per manganese ion) while magnetic ordering occurs for BaKCu<sub>3</sub>CoS<sub>4</sub> (T<sub>N</sub> ∼ 12 K). BaKCu<sub>3</sub>NiS<sub>4</sub> exhibits temperature-independent paramagnetic behavior.</s0></fC01><fC02 i1="01" i2="3"><s0>001B70E30C</s0></fC02><fC02 i1="02" i2="3"><s0>001B70E60E</s0></fC02><fC02 i1="03" i2="3"><s0>001B70B20F</s0></fC02><fC02 i1="04" i2="3"><s0>001B60A66F2</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0><s5>01</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Susceptibilité magnétique</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>Magnetic susceptibility</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Loi Curie Weiss</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Curie-Weiss law</s0><s5>03</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Polycristal</s0><s5>04</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Polycrystals</s0><s5>04</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Diffraction RX</s0><s5>05</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>XRD</s0><s5>05</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Structure cristalline</s0><s5>06</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>Crystal structure</s0><s5>06</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Conductivité électrique</s0><s5>07</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>Electrical conductivity</s0><s5>07</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>Baryum sulfure</s0><s2>NK</s2><s5>11</s5></fC03><fC03 i1="08" i2="3" l="ENG"><s0>Barium sulfides</s0><s2>NK</s2><s5>11</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Potassium sulfure</s0><s2>NK</s2><s5>12</s5></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Potassium sulfides</s0><s2>NK</s2><s5>12</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>Cuivre sulfure</s0><s2>NK</s2><s5>13</s5></fC03><fC03 i1="10" i2="3" l="ENG"><s0>Copper sulfides</s0><s2>NK</s2><s5>13</s5></fC03><fC03 i1="11" i2="3" l="FRE"><s0>Manganèse sulfure</s0><s2>NK</s2><s5>14</s5></fC03><fC03 i1="11" i2="3" l="ENG"><s0>Manganese sulfides</s0><s2>NK</s2><s5>14</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Cobalt sulfure</s0><s2>NK</s2><s5>15</s5></fC03><fC03 i1="12" i2="3" l="ENG"><s0>Cobalt sulfides</s0><s2>NK</s2><s5>15</s5></fC03><fC03 i1="13" i2="3" l="FRE"><s0>Nickel sulfure</s0><s2>NK</s2><s5>16</s5></fC03><fC03 i1="13" i2="3" l="ENG"><s0>Nickel sulfides</s0><s2>NK</s2><s5>16</s5></fC03><fC03 i1="14" i2="3" l="FRE"><s0>BaKCu3NiS4</s0><s4>INC</s4><s5>52</s5></fC03><fC03 i1="15" i2="3" l="FRE"><s0>Ba Cu K Ni S</s0><s4>INC</s4><s5>53</s5></fC03><fC03 i1="16" i2="3" l="FRE"><s0>7530C</s0><s2>PAC</s2><s4>INC</s4><s5>56</s5></fC03><fC03 i1="17" i2="3" l="FRE"><s0>7560E</s0><s2>PAC</s2><s4>INC</s4><s5>57</s5></fC03><fC03 i1="18" i2="3" l="FRE"><s0>7220F</s0><s2>PAC</s2><s4>INC</s4><s5>58</s5></fC03><fC03 i1="19" i2="3" l="FRE"><s0>6166F</s0><s2>PAC</s2><s4>INC</s4><s5>59</s5></fC03><fC03 i1="20" i2="3" l="FRE"><s0>BaKCu3MnS4</s0><s4>INC</s4><s5>92</s5></fC03><fC03 i1="21" i2="3" l="FRE"><s0>Ba Cu K Mn S</s0><s4>INC</s4><s5>93</s5></fC03><fC03 i1="22" i2="3" l="FRE"><s0>BaKCu3CoS4</s0><s4>INC</s4><s5>94</s5></fC03><fC03 i1="23" i2="3" l="FRE"><s0>Ba Co Cu K S</s0><s4>INC</s4><s5>95</s5></fC03><fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0><s5>08</s5></fC07><fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0><s5>08</s5></fC07><fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0><s5>10</s5></fC07><fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0><s5>10</s5></fC07><fN21><s1>148</s1></fN21></pA></standard></inist><affiliations><list><country><li>France</li><li>Maroc</li></country><region><li>Région Bretagne</li></region><settlement><li>Rennes</li></settlement></list><tree><country name="France"><region name="Région Bretagne"><name sortKey="Mouallem Bahout, M" sort="Mouallem Bahout, M" uniqKey="Mouallem Bahout M" first="M." last="Mouallem-Bahout">M. Mouallem-Bahout</name></region><name sortKey="Carel, C" sort="Carel, C" uniqKey="Carel C" first="C." last="Carel">C. Carel</name><name sortKey="Pena, O" sort="Pena, O" uniqKey="Pena O" first="O." last="Pena">O. Pena</name></country><country name="Maroc"><noRegion><name sortKey="Ouammou, A" sort="Ouammou, A" uniqKey="Ouammou A" first="A." last="Ouammou">A. Ouammou</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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