Crystal structure approach of the disordered new compounds Bi∼1.2M∼1.2PO5.5 (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates
Identifieur interne : 000256 ( PascalFrancis/Checkpoint ); précédent : 000255; suivant : 000257Crystal structure approach of the disordered new compounds Bi∼1.2M∼1.2PO5.5 (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates
Auteurs : F. Abraham [France] ; O. Cousin [France] ; O. Mentre [France] ; El M. Ketatni [Maroc]Source :
- Journal of solid state chemistry [ 0022-4596 ] ; 2002.
Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Préparation chimique, Réaction état solide, Diffraction RX, Structure cristalline, Cristal désordonné, Structure fluorite, Cobalt oxyde, Cobalt phosphate, Manganèse oxyde, Manganèse phosphate, Bismuth oxyde, Bismuth Phosphate, Susceptibilité magnétique, Bi Co O P, 6166F, Oxyphosphate, Bi1,2Mn1,2PO5,5, Bi1,2Co1,2PO5,5, Bi Mn O P.
English descriptors
- KwdEn :
Abstract
The crystal structures of some recently published bismuth-transition metal oxy-phosphates are described as the association of complex infinite one-dimensional polycations and phosphate anions. The complex cations are built from oxygen-centered tetrahedra sharing edges to form infinite ribbons of n tetrahedra width. This structural concept allows one to describe the essential structural features of new highly disordered bismuth-transition metal oxy-phosphates, Bi∼1.2M∼1.2PO5.5 (M = Mn, Co, Zn). The new compounds have been synthesized and structurally characterized by single-crystal X-ray diffraction. The three compounds crystallize in the orthorhombic space group Ibam (No. 72), Z=8. The lattice parameters are a = 15.079(2), b = 11.247(2), c = 5.437(1) Å for M = Mn, a = 14.752(3), b = 11.205(3), c = 5.434(2) Å for M = Co and a = 14.809(2), b = 11.214(1), c = 5.440(1) Å for M = Zn. Because of a high disorder over several cationic sites, only an approach of the crystal structure determination has been achieved. Actually, the structure is characterized by perfectly defined ribbons parallel to the (010) plane and built from a central chain of edge-shared OBi4 tetrahedra running along the c axis and linked by edges to two other edge-shared O(Bi,M)4 tetrahedra chains. The positions at the border of ribbons are randomly occupied by bismuth and M atoms. The formula of the three tetrahedra width ribbons is (O3Bi2.4M1.6)+4.4. The phosphate ions and M2+ cations are disordered in the interspace between the ribbons.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Crystal structure approach of the disordered new compounds Bi<sub>∼1.2</sub>M<sub>∼1.2</sub>PO<sub>5.5</sub> (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates</title><author><name sortKey="Abraham, F" sort="Abraham, F" uniqKey="Abraham F" first="F." last="Abraham">F. Abraham</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Cousin, O" sort="Cousin, O" uniqKey="Cousin O" first="O." last="Cousin">O. Cousin</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Mentre, O" sort="Mentre, O" uniqKey="Mentre O" first="O." last="Mentre">O. Mentre</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Ketatni, El M" sort="Ketatni, El M" uniqKey="Ketatni E" first="El M." last="Ketatni">El M. Ketatni</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Electrochimie et Chimie des Matériaux, Faculté des Sciences, Université Cadi Ayyad, B.P. 523</s1><s2>Beni Mellal</s2><s3>MAR</s3><sZ>4 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>Beni Mellal</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">02-0529086</idno><date when="2002">2002</date><idno type="stanalyst">PASCAL 02-0529086 INIST</idno><idno type="RBID">Pascal:02-0529086</idno><idno type="wicri:Area/PascalFrancis/Corpus">000244</idno><idno type="wicri:Area/PascalFrancis/Curation">000051</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000256</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000256</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Crystal structure approach of the disordered new compounds Bi<sub>∼1.2</sub>M<sub>∼1.2</sub>PO<sub>5.5</sub> (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates</title><author><name sortKey="Abraham, F" sort="Abraham, F" uniqKey="Abraham F" first="F." last="Abraham">F. Abraham</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Cousin, O" sort="Cousin, O" uniqKey="Cousin O" first="O." last="Cousin">O. Cousin</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Mentre, O" sort="Mentre, O" uniqKey="Mentre O" first="O." last="Mentre">O. Mentre</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve d'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Ketatni, El M" sort="Ketatni, El M" uniqKey="Ketatni E" first="El M." last="Ketatni">El M. Ketatni</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Electrochimie et Chimie des Matériaux, Faculté des Sciences, Université Cadi Ayyad, B.P. 523</s1><s2>Beni Mellal</s2><s3>MAR</s3><sZ>4 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>Beni Mellal</wicri:noRegion></affiliation></author></analytic><series><title level="j" type="main">Journal of solid state chemistry</title><title level="j" type="abbreviated">J. solid state chem.</title><idno type="ISSN">0022-4596</idno><imprint><date when="2002">2002</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Journal of solid state chemistry</title><title level="j" type="abbreviated">J. solid state chem.</title><idno type="ISSN">0022-4596</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bismuth Phosphates</term><term>Bismuth oxides</term><term>Chemical preparation</term><term>Cobalt oxides</term><term>Cobalt phosphates</term><term>Crystal structure</term><term>Disordered crystals</term><term>Experimental study</term><term>Fluorite structure</term><term>Magnetic susceptibility</term><term>Manganese oxides</term><term>Manganese phosphates</term><term>Solid state reaction</term><term>XRD</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Préparation chimique</term><term>Réaction état solide</term><term>Diffraction RX</term><term>Structure cristalline</term><term>Cristal désordonné</term><term>Structure fluorite</term><term>Cobalt oxyde</term><term>Cobalt phosphate</term><term>Manganèse oxyde</term><term>Manganèse phosphate</term><term>Bismuth oxyde</term><term>Bismuth Phosphate</term><term>Susceptibilité magnétique</term><term>Bi Co O P</term><term>6166F</term><term>Oxyphosphate</term><term>Bi1,2Mn1,2PO5,5</term><term>Bi1,2Co1,2PO5,5</term><term>Bi Mn O P</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The crystal structures of some recently published bismuth-transition metal oxy-phosphates are described as the association of complex infinite one-dimensional polycations and phosphate anions. The complex cations are built from oxygen-centered tetrahedra sharing edges to form infinite ribbons of n tetrahedra width. This structural concept allows one to describe the essential structural features of new highly disordered bismuth-transition metal oxy-phosphates, Bi<sub>∼1.2</sub>M<sub>∼1.2</sub>PO<sub>5.5</sub> (M = Mn, Co, Zn). The new compounds have been synthesized and structurally characterized by single-crystal X-ray diffraction. The three compounds crystallize in the orthorhombic space group Ibam (No. 72), Z=8. The lattice parameters are a = 15.079(2), b = 11.247(2), c = 5.437(1) Å for M = Mn, a = 14.752(3), b = 11.205(3), c = 5.434(2) Å for M = Co and a = 14.809(2), b = 11.214(1), c = 5.440(1) Å for M = Zn. Because of a high disorder over several cationic sites, only an approach of the crystal structure determination has been achieved. Actually, the structure is characterized by perfectly defined ribbons parallel to the (010) plane and built from a central chain of edge-shared OBi<sub>4</sub> tetrahedra running along the c axis and linked by edges to two other edge-shared O(Bi,M)<sub>4</sub> tetrahedra chains. The positions at the border of ribbons are randomly occupied by bismuth and M atoms. The formula of the three tetrahedra width ribbons is (O<sub>3</sub>Bi<sub>2.4</sub>M<sub>1.6</sub>)<sup>+4.4</sup>. The phosphate ions and M<sup>2+</sup> cations are disordered in the interspace between the ribbons.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0022-4596</s0></fA01><fA02 i1="01"><s0>JSSCBI</s0></fA02><fA03 i2="1"><s0>J. solid state chem.</s0></fA03><fA05><s2>167</s2></fA05><fA06><s2>1</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Crystal structure approach of the disordered new compounds Bi<sub>∼1.2</sub>M<sub>∼1.2</sub>PO<sub>5.5</sub> (M=Mn, Co, Zn): The role of oxygen-centered tetrahedra linkage in the structure of bismuth-transition metal oxy-phosphates</s1></fA08><fA11 i1="01" i2="1"><s1>ABRAHAM (F.)</s1></fA11><fA11 i1="02" i2="1"><s1>COUSIN (O.)</s1></fA11><fA11 i1="03" i2="1"><s1>MENTRE (O.)</s1></fA11><fA11 i1="04" i2="1"><s1>KETATNI (El M.)</s1></fA11><fA14 i1="01"><s1>Laboratoire de Cristallochimie et Physicochimie du Solide, UPRESA CNRS 8012, ENSCL, Université des Sciences et Technologies de Lille, B P. 108</s1><s2>59652 Villeneuve d'Ascq</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></fA14><fA14 i1="02"><s1>Laboratoire d'Electrochimie et Chimie des Matériaux, Faculté des Sciences, Université Cadi Ayyad, B.P. 523</s1><s2>Beni Mellal</s2><s3>MAR</s3><sZ>4 aut.</sZ></fA14><fA20><s1>168-181</s1></fA20><fA21><s1>2002</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>14677</s2><s5>354000109317650210</s5></fA43><fA44><s0>0000</s0><s1>© 2002 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>51 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>02-0529086</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Journal of solid state chemistry</s0></fA64><fA66 i1="01"><s0>USA</s0></fA66><fC01 i1="01" l="ENG"><s0>The crystal structures of some recently published bismuth-transition metal oxy-phosphates are described as the association of complex infinite one-dimensional polycations and phosphate anions. The complex cations are built from oxygen-centered tetrahedra sharing edges to form infinite ribbons of n tetrahedra width. This structural concept allows one to describe the essential structural features of new highly disordered bismuth-transition metal oxy-phosphates, Bi<sub>∼1.2</sub>M<sub>∼1.2</sub>PO<sub>5.5</sub> (M = Mn, Co, Zn). The new compounds have been synthesized and structurally characterized by single-crystal X-ray diffraction. The three compounds crystallize in the orthorhombic space group Ibam (No. 72), Z=8. The lattice parameters are a = 15.079(2), b = 11.247(2), c = 5.437(1) Å for M = Mn, a = 14.752(3), b = 11.205(3), c = 5.434(2) Å for M = Co and a = 14.809(2), b = 11.214(1), c = 5.440(1) Å for M = Zn. Because of a high disorder over several cationic sites, only an approach of the crystal structure determination has been achieved. Actually, the structure is characterized by perfectly defined ribbons parallel to the (010) plane and built from a central chain of edge-shared OBi<sub>4</sub> tetrahedra running along the c axis and linked by edges to two other edge-shared O(Bi,M)<sub>4</sub> tetrahedra chains. The positions at the border of ribbons are randomly occupied by bismuth and M atoms. The formula of the three tetrahedra width ribbons is (O<sub>3</sub>Bi<sub>2.4</sub>M<sub>1.6</sub>)<sup>+4.4</sup>. The phosphate ions and M<sup>2+</sup> cations are disordered in the interspace between the ribbons.</s0></fC01><fC02 i1="01" i2="3"><s0>001B60A66F4</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0><s5>01</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Préparation chimique</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>Chemical preparation</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Réaction état solide</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Solid state reaction</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Reacción estado sólido</s0><s5>03</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Diffraction RX</s0><s5>04</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>XRD</s0><s5>04</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Structure cristalline</s0><s5>05</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Crystal structure</s0><s5>05</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Cristal désordonné</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Disordered crystals</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Cristal desordenado</s0><s5>06</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Structure fluorite</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Fluorite structure</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Estructura fluorita</s0><s5>07</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>Cobalt oxyde</s0><s2>NK</s2><s5>09</s5></fC03><fC03 i1="08" i2="3" l="ENG"><s0>Cobalt oxides</s0><s2>NK</s2><s5>09</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Cobalt phosphate</s0><s2>NK</s2><s5>10</s5></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Cobalt phosphates</s0><s2>NK</s2><s5>10</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>Manganèse oxyde</s0><s2>NK</s2><s5>11</s5></fC03><fC03 i1="10" i2="3" l="ENG"><s0>Manganese oxides</s0><s2>NK</s2><s5>11</s5></fC03><fC03 i1="11" i2="3" l="FRE"><s0>Manganèse phosphate</s0><s2>NK</s2><s5>12</s5></fC03><fC03 i1="11" i2="3" l="ENG"><s0>Manganese phosphates</s0><s2>NK</s2><s5>12</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Bismuth oxyde</s0><s2>NK</s2><s5>14</s5></fC03><fC03 i1="12" i2="3" l="ENG"><s0>Bismuth oxides</s0><s2>NK</s2><s5>14</s5></fC03><fC03 i1="13" i2="3" l="FRE"><s0>Bismuth Phosphate</s0><s2>NC</s2><s2>NA</s2><s5>15</s5></fC03><fC03 i1="13" i2="3" l="ENG"><s0>Bismuth Phosphates</s0><s2>NC</s2><s2>NA</s2><s5>15</s5></fC03><fC03 i1="14" i2="3" l="FRE"><s0>Susceptibilité magnétique</s0><s5>16</s5></fC03><fC03 i1="14" i2="3" l="ENG"><s0>Magnetic susceptibility</s0><s5>16</s5></fC03><fC03 i1="15" i2="3" l="FRE"><s0>Bi Co O P</s0><s4>INC</s4><s5>52</s5></fC03><fC03 i1="16" i2="3" l="FRE"><s0>6166F</s0><s2>PAC</s2><s4>INC</s4><s5>56</s5></fC03><fC03 i1="17" i2="3" l="FRE"><s0>Oxyphosphate</s0><s4>INC</s4><s5>92</s5></fC03><fC03 i1="18" i2="3" l="FRE"><s0>Bi1,2Mn1,2PO5,5</s0><s4>INC</s4><s5>93</s5></fC03><fC03 i1="19" i2="3" l="FRE"><s0>Bi1,2Co1,2PO5,5</s0><s4>INC</s4><s5>94</s5></fC03><fC03 i1="20" i2="3" l="FRE"><s0>Bi Mn O P</s0><s4>INC</s4><s5>95</s5></fC03><fC07 i1="01" i2="3" l="FRE"><s0>Propriété magnétique</s0><s5>17</s5></fC07><fC07 i1="01" i2="3" l="ENG"><s0>Magnetic properties</s0><s5>17</s5></fC07><fC07 i1="02" i2="3" l="FRE"><s0>Composé minéral</s0><s5>81</s5></fC07><fC07 i1="02" i2="3" l="ENG"><s0>Inorganic compounds</s0><s5>81</s5></fC07><fC07 i1="03" i2="3" l="FRE"><s0>Métal transition composé</s0><s5>82</s5></fC07><fC07 i1="03" i2="3" l="ENG"><s0>Transition element compounds</s0><s5>82</s5></fC07><fN21><s1>316</s1></fN21><fN82><s1>PSI</s1></fN82></pA></standard></inist><affiliations><list><country><li>France</li><li>Maroc</li></country><region><li>Hauts-de-France</li><li>Nord-Pas-de-Calais</li></region><settlement><li>Villeneuve d'Ascq</li></settlement></list><tree><country name="France"><region name="Hauts-de-France"><name sortKey="Abraham, F" sort="Abraham, F" uniqKey="Abraham F" first="F." last="Abraham">F. 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