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Magnetic structure of layered LiFe1-xCoxO2: a powder-neutron diffraction study

Identifieur interne : 000247 ( PascalFrancis/Checkpoint ); précédent : 000246; suivant : 000248

Magnetic structure of layered LiFe1-xCoxO2: a powder-neutron diffraction study

Auteurs : E. Chappel [France] ; M. Holzapfel [France, Allemagne] ; N. Douakha [France, Algérie] ; G. Chouteau [France] ; A. Ott [France] ; B. Ouladdiaf [France]

Source :

RBID : Pascal:02-0401233

Descripteurs français

English descriptors

Abstract

Layered LiFe1-xCoxO2 compounds have been studied by powder-neutron diffraction in the temperature range 1.5 100 K and at room temperature. The Bragg reflections of LiFe1-xCoxO2 can be indexed in the R-3m space group. At low temperatures, for x < 0.6 samples. an A-type AF structure is observed with a propagation vector k = [0 0 1/2] and a magnetic moment μ3b(Fe3- ) = 3.9 μB.


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Pascal:02-0401233

Le document en format XML

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: a powder-neutron diffraction study</title>
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<title level="j" type="main">Journal of magnetism and magnetic materials</title>
<title level="j" type="abbreviated">J. magn. magn. mater.</title>
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<term>Antiferromagnetism</term>
<term>Bragg reflection</term>
<term>Cobalt oxides</term>
<term>Composition effect</term>
<term>Experimental study</term>
<term>Iron oxides</term>
<term>Layered crystals</term>
<term>Lithium oxides</term>
<term>Magnetic moments</term>
<term>Magnetic structure</term>
<term>Neutron diffraction</term>
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<term>Temperature dependence</term>
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<term>Structure magnétique</term>
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<term>Effet composition</term>
<term>Cristal lamellaire</term>
<term>Lithium oxyde</term>
<term>Fer oxyde</term>
<term>Cobalt oxyde</term>
<term>Composé quaternaire</term>
<term>Etude expérimentale</term>
<term>LiFe1-xCoxO2</term>
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<div type="abstract" xml:lang="en">Layered LiFe
<sub>1-x</sub>
Co
<sub>x</sub>
O
<sub>2</sub>
compounds have been studied by powder-neutron diffraction in the temperature range 1.5 100 K and at room temperature. The Bragg reflections of LiFe
<sub>1-x</sub>
Co
<sub>x</sub>
O
<sub>2</sub>
can be indexed in the R-3m space group. At low temperatures, for x < 0.6 samples. an A-type AF structure is observed with a propagation vector k = [0 0 1/2] and a magnetic moment μ
<sub>3b</sub>
(Fe
<sup>3-</sup>
) = 3.9 μ
<sub>B</sub>
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O
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Co
<sub>x</sub>
O
<sub>2</sub>
can be indexed in the R-3m space group. At low temperatures, for x < 0.6 samples. an A-type AF structure is observed with a propagation vector k = [0 0 1/2] and a magnetic moment μ
<sub>3b</sub>
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<fC03 i1="05" i2="3" l="FRE">
<s0>Moment magnétique</s0>
<s5>08</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Magnetic moments</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Antiferromagnétisme</s0>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Antiferromagnetism</s0>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Effet composition</s0>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Composition effect</s0>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Efecto composición</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Cristal lamellaire</s0>
<s5>11</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Layered crystals</s0>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Lithium oxyde</s0>
<s2>NK</s2>
<s5>12</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Lithium oxides</s0>
<s2>NK</s2>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Fer oxyde</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Iron oxides</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Cobalt oxyde</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Cobalt oxides</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Composé quaternaire</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Quaternary compounds</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Etude expérimentale</s0>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Experimental study</s0>
<s5>16</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>LiFe1-xCoxO2</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Co Fe Li O</s0>
<s4>INC</s4>
<s5>54</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>7525</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE">
<s0>Composé minéral</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG">
<s0>Inorganic compounds</s0>
<s5>48</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE">
<s0>Métal transition composé</s0>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG">
<s0>Transition element compounds</s0>
<s5>49</s5>
</fC07>
<fN21>
<s1>224</s1>
</fN21>
<fN82>
<s1>PSI</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>JEMS'01 Joint European Magnetic Symposia</s1>
<s2>1</s2>
<s3>Grenoble FRA</s3>
<s4>2001-08-28</s4>
</fA30>
</pR>
</standard>
</inist>
<affiliations>
<list>
<country>
<li>Algérie</li>
<li>Allemagne</li>
<li>France</li>
</country>
<region>
<li>Auvergne-Rhône-Alpes</li>
<li>Bade-Wurtemberg</li>
<li>District de Stuttgart</li>
<li>Rhône-Alpes</li>
</region>
<settlement>
<li>Grenoble</li>
<li>St. Martin d'Hères</li>
<li>Stuttgart</li>
</settlement>
</list>
<tree>
<country name="France">
<region name="Auvergne-Rhône-Alpes">
<name sortKey="Chappel, E" sort="Chappel, E" uniqKey="Chappel E" first="E." last="Chappel">E. Chappel</name>
</region>
<name sortKey="Chouteau, G" sort="Chouteau, G" uniqKey="Chouteau G" first="G." last="Chouteau">G. Chouteau</name>
<name sortKey="Douakha, N" sort="Douakha, N" uniqKey="Douakha N" first="N." last="Douakha">N. Douakha</name>
<name sortKey="Holzapfel, M" sort="Holzapfel, M" uniqKey="Holzapfel M" first="M." last="Holzapfel">M. Holzapfel</name>
<name sortKey="Ott, A" sort="Ott, A" uniqKey="Ott A" first="A." last="Ott">A. Ott</name>
<name sortKey="Ouladdiaf, B" sort="Ouladdiaf, B" uniqKey="Ouladdiaf B" first="B." last="Ouladdiaf">B. Ouladdiaf</name>
</country>
<country name="Allemagne">
<region name="Bade-Wurtemberg">
<name sortKey="Holzapfel, M" sort="Holzapfel, M" uniqKey="Holzapfel M" first="M." last="Holzapfel">M. Holzapfel</name>
</region>
</country>
<country name="Algérie">
<noRegion>
<name sortKey="Douakha, N" sort="Douakha, N" uniqKey="Douakha N" first="N." last="Douakha">N. Douakha</name>
</noRegion>
</country>
</tree>
</affiliations>
</record>

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