Low temperature synthesis of LiCr0.3Co0.7O2 intercalation compounds using citrate, oxalate, succinate, and glycinate precursors
Identifieur interne : 000224 ( PascalFrancis/Checkpoint ); précédent : 000223; suivant : 000225Low temperature synthesis of LiCr0.3Co0.7O2 intercalation compounds using citrate, oxalate, succinate, and glycinate precursors
Auteurs : N. Amdouni [Tunisie] ; H. Zarrouk [Tunisie] ; C. Julien [France]Source :
- British ceramic transactions [ 0967-9782 ] ; 2003.
Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Préparation chimique, Composé insertion, Basse température, Lithium oxyde, Chrome oxyde, Cobalt oxyde, Substitution ion, Procédé voie humide, Solution aqueuse, Méthode en solution, Citrate, Oxalate, Précurseur, Carboxylate, Thermogravimétrie, Analyse thermique différentielle, Diffraction RX, Microscopie électronique balayage, Spectre IR, Propriété électrochimique, Matériau électrode, LiCr0,3Co0,7O2, Co Cr Li O, Succinate, Glycinate.
English descriptors
- KwdEn :
- Aqueous solution, Carboxylate, Chemical preparation, Chromium oxide, Citrate, Cobalt oxide, Differential thermal analysis, Electrochemical properties, Electrode material, Experimental study, Growth from solution, Infrared spectrum, Intercalation compound, Ion substitution, Lithium oxide, Low temperature, Oxalate, Precursor, Scanning electron microscopy, Thermogravimetry, Wet process, X ray diffraction.
Abstract
The synthesis of Cr substituted lithium cobaltate LiCr0.3Co0.7O2 using four different low temperature methods is presented. These wet chemical routes involve the mixing of either acetates or nitrates of Co and Cr with a chelating agent in aqueous solution, namely citric acid for the sol-gel method, oxalic acid for the coprecipitation method, succinic acid for the pyrolysis method, or the complexing agent glycine for the combustion method. The synthesised products were characterised by TG-DTA, XRD, SEM, and FTIR. Structural analysis revealed the R 3 m space group for the solid solution. The electrochemical behaviour of LiCr0.3Co0.7O2 was evaluated in a lithium cell.
Affiliations:
- France, Tunisie
- Gouvernorat de Tunis, Île-de-France
- Paris 05, Tunis
- Université Pierre-et-Marie-Curie, Université de Tunis - El Manar
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Amdouni</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Tunis, Université de Tunis El Manar, Campus Universitaire</s1><s2>2092 El Manar II</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Tunisie</country><wicri:noRegion>2092 El Manar II</wicri:noRegion><orgName type="university">Université de Tunis - El Manar</orgName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Zarrouk, H" sort="Zarrouk, H" uniqKey="Zarrouk H" first="H." last="Zarrouk">H. Zarrouk</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Tunis, Université de Tunis El Manar, Campus Universitaire</s1><s2>2092 El Manar II</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Tunisie</country><wicri:noRegion>2092 El Manar II</wicri:noRegion><orgName type="university">Université de Tunis - El Manar</orgName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Julien, C" sort="Julien, C" uniqKey="Julien C" first="C." last="Julien">C. Julien</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Laboratoire des Milieux Désordonnés et Hétérogènes, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1><s2>75252 Paris 05</s2><s3>FRA</s3><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Paris 05</settlement></placeName><orgName type="university">Université Pierre-et-Marie-Curie</orgName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">03-0374058</idno><date when="2003">2003</date><idno type="stanalyst">PASCAL 03-0374058 INIST</idno><idno type="RBID">Pascal:03-0374058</idno><idno type="wicri:Area/PascalFrancis/Corpus">000228</idno><idno type="wicri:Area/PascalFrancis/Curation">000067</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000224</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000224</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Low temperature synthesis of LiCr<sub>0.3</sub>Co<sub>0.7</sub>O<sub>2</sub> intercalation compounds using citrate, oxalate, succinate, and glycinate precursors</title><author><name sortKey="Amdouni, N" sort="Amdouni, N" uniqKey="Amdouni N" first="N." last="Amdouni">N. Amdouni</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Tunis, Université de Tunis El Manar, Campus Universitaire</s1><s2>2092 El Manar II</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Tunisie</country><wicri:noRegion>2092 El Manar II</wicri:noRegion><orgName type="university">Université de Tunis - El Manar</orgName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Zarrouk, H" sort="Zarrouk, H" uniqKey="Zarrouk H" first="H." last="Zarrouk">H. Zarrouk</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Tunis, Université de Tunis El Manar, Campus Universitaire</s1><s2>2092 El Manar II</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Tunisie</country><wicri:noRegion>2092 El Manar II</wicri:noRegion><orgName type="university">Université de Tunis - El Manar</orgName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Julien, C" sort="Julien, C" uniqKey="Julien C" first="C." last="Julien">C. Julien</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Laboratoire des Milieux Désordonnés et Hétérogènes, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1><s2>75252 Paris 05</s2><s3>FRA</s3><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Paris 05</settlement></placeName><orgName type="university">Université Pierre-et-Marie-Curie</orgName></affiliation></author></analytic><series><title level="j" type="main">British ceramic transactions</title><title level="j" type="abbreviated">Br. ceram. trans.</title><idno type="ISSN">0967-9782</idno><imprint><date when="2003">2003</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">British ceramic transactions</title><title level="j" type="abbreviated">Br. ceram. trans.</title><idno type="ISSN">0967-9782</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aqueous solution</term><term>Carboxylate</term><term>Chemical preparation</term><term>Chromium oxide</term><term>Citrate</term><term>Cobalt oxide</term><term>Differential thermal analysis</term><term>Electrochemical properties</term><term>Electrode material</term><term>Experimental study</term><term>Growth from solution</term><term>Infrared spectrum</term><term>Intercalation compound</term><term>Ion substitution</term><term>Lithium oxide</term><term>Low temperature</term><term>Oxalate</term><term>Precursor</term><term>Scanning electron microscopy</term><term>Thermogravimetry</term><term>Wet process</term><term>X ray diffraction</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Préparation chimique</term><term>Composé insertion</term><term>Basse température</term><term>Lithium oxyde</term><term>Chrome oxyde</term><term>Cobalt oxyde</term><term>Substitution ion</term><term>Procédé voie humide</term><term>Solution aqueuse</term><term>Méthode en solution</term><term>Citrate</term><term>Oxalate</term><term>Précurseur</term><term>Carboxylate</term><term>Thermogravimétrie</term><term>Analyse thermique différentielle</term><term>Diffraction RX</term><term>Microscopie électronique balayage</term><term>Spectre IR</term><term>Propriété électrochimique</term><term>Matériau électrode</term><term>LiCr0,3Co0,7O2</term><term>Co Cr Li O</term><term>Succinate</term><term>Glycinate</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The synthesis of Cr substituted lithium cobaltate LiCr<sub>0.3</sub>Co<sub>0.7</sub>O<sub>2</sub> using four different low temperature methods is presented. These wet chemical routes involve the mixing of either acetates or nitrates of Co and Cr with a chelating agent in aqueous solution, namely citric acid for the sol-gel method, oxalic acid for the coprecipitation method, succinic acid for the pyrolysis method, or the complexing agent glycine for the combustion method. The synthesised products were characterised by TG-DTA, XRD, SEM, and FTIR. Structural analysis revealed the R 3 m space group for the solid solution. The electrochemical behaviour of LiCr<sub>0.3</sub>Co<sub>0.7</sub>O<sub>2</sub> was evaluated in a lithium cell.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0967-9782</s0></fA01><fA03 i2="1"><s0>Br. ceram. trans.</s0></fA03><fA05><s2>102</s2></fA05><fA06><s2>1</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Low temperature synthesis of LiCr<sub>0.3</sub>Co<sub>0.7</sub>O<sub>2</sub> intercalation compounds using citrate, oxalate, succinate, and glycinate precursors</s1></fA08><fA11 i1="01" i2="1"><s1>AMDOUNI (N.)</s1></fA11><fA11 i1="02" i2="1"><s1>ZARROUK (H.)</s1></fA11><fA11 i1="03" i2="1"><s1>JULIEN (C.)</s1></fA11><fA14 i1="01"><s1>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Tunis, Université de Tunis El Manar, Campus Universitaire</s1><s2>2092 El Manar II</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></fA14><fA14 i1="02"><s1>Laboratoire des Milieux Désordonnés et Hétérogènes, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1><s2>75252 Paris 05</s2><s3>FRA</s3><sZ>3 aut.</sZ></fA14><fA20><s1>27-33</s1></fA20><fA21><s1>2003</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>616</s2><s5>354000118535700060</s5></fA43><fA44><s0>0000</s0><s1>© 2003 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>21 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>03-0374058</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>British ceramic transactions</s0></fA64><fA66 i1="01"><s0>GBR</s0></fA66><fC01 i1="01" l="ENG"><s0>The synthesis of Cr substituted lithium cobaltate LiCr<sub>0.3</sub>Co<sub>0.7</sub>O<sub>2</sub> using four different low temperature methods is presented. These wet chemical routes involve the mixing of either acetates or nitrates of Co and Cr with a chelating agent in aqueous solution, namely citric acid for the sol-gel method, oxalic acid for the coprecipitation method, succinic acid for the pyrolysis method, or the complexing agent glycine for the combustion method. The synthesised products were characterised by TG-DTA, XRD, SEM, and FTIR. Structural analysis revealed the R 3 m space group for the solid solution. The electrochemical behaviour of LiCr<sub>0.3</sub>Co<sub>0.7</sub>O<sub>2</sub> was evaluated in a lithium cell.</s0></fC01><fC02 i1="01" i2="X"><s0>001C02B06</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Etude expérimentale</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Experimental study</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Estudio experimental</s0><s5>01</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Préparation chimique</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>Chemical preparation</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Composé insertion</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Intercalation compound</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Compuesto inserción</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Basse température</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Low temperature</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Baja temperatura</s0><s5>04</s5></fC03><fC03 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diffraction</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Difracción RX</s0><s5>18</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Microscopie électronique balayage</s0><s5>19</s5></fC03><fC03 i1="19" i2="X" l="ENG"><s0>Scanning electron microscopy</s0><s5>19</s5></fC03><fC03 i1="19" i2="X" l="SPA"><s0>Microscopía electrónica barrido</s0><s5>19</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Spectre IR</s0><s5>20</s5></fC03><fC03 i1="20" i2="X" l="ENG"><s0>Infrared spectrum</s0><s5>20</s5></fC03><fC03 i1="20" i2="X" l="SPA"><s0>Espectro IR</s0><s5>20</s5></fC03><fC03 i1="21" i2="X" l="FRE"><s0>Propriété électrochimique</s0><s5>21</s5></fC03><fC03 i1="21" i2="X" l="ENG"><s0>Electrochemical properties</s0><s5>21</s5></fC03><fC03 i1="21" i2="X" l="SPA"><s0>Propiedad electroquímica</s0><s5>21</s5></fC03><fC03 i1="22" i2="X" l="FRE"><s0>Matériau électrode</s0><s5>22</s5></fC03><fC03 i1="22" i2="X" l="ENG"><s0>Electrode material</s0><s5>22</s5></fC03><fC03 i1="22" i2="X" l="SPA"><s0>Material electrodo</s0><s5>22</s5></fC03><fC03 i1="23" i2="X" l="FRE"><s0>LiCr0,3Co0,7O2</s0><s1>FIN</s1><s4>INC</s4><s5>32</s5></fC03><fC03 i1="24" i2="X" l="FRE"><s0>Co Cr Li O</s0><s4>INC</s4><s5>33</s5></fC03><fC03 i1="25" i2="X" l="FRE"><s0>Succinate</s0><s1>ENT</s1><s4>INC</s4><s5>34</s5></fC03><fC03 i1="26" i2="X" l="FRE"><s0>Glycinate</s0><s1>ENT</s1><s4>INC</s4><s5>35</s5></fC03><fN21><s1>265</s1></fN21><fN82><s1>PSI</s1></fN82></pA></standard></inist><affiliations><list><country><li>France</li><li>Tunisie</li></country><region><li>Gouvernorat de Tunis</li><li>Île-de-France</li></region><settlement><li>Paris 05</li><li>Tunis</li></settlement><orgName><li>Université Pierre-et-Marie-Curie</li><li>Université de Tunis - El Manar</li></orgName></list><tree><country name="Tunisie"><region name="Gouvernorat de Tunis"><name sortKey="Amdouni, N" sort="Amdouni, N" uniqKey="Amdouni N" first="N." last="Amdouni">N. Amdouni</name></region><name sortKey="Zarrouk, H" sort="Zarrouk, H" uniqKey="Zarrouk H" first="H." last="Zarrouk">H. Zarrouk</name></country><country name="France"><region name="Île-de-France"><name sortKey="Julien, C" sort="Julien, C" uniqKey="Julien C" first="C." last="Julien">C. Julien</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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