CobaltMaghrebV1, PascalFrancis, Checkpoint, bibRecord, 000170

Electrochemical nucleation and growth of Co and CoFe alloys on Pt/Si substrates

Identifieur interne : 000170 ( PascalFrancis/Checkpoint ); précédent : 000169; suivant : 000171

Electrochemical nucleation and growth of Co and CoFe alloys on Pt/Si substrates

Auteurs : A. Sahari [Algérie] ; A. Azizi [Algérie] ; G. Schmerber [France] ; M. Abes [France] ; J. P. Bucher [France] ; A. Dinia [France]

Source :

Catalysis today [ 0920-5861 ] ; 2006.

RBID : Pascal:06-0371437

Descripteurs français

Pascal (Inist)
- Electrochimie, Nucléation, Croissance, Alliage, Substrat, Cobalt, Dépôt électrolytique, Morphologie, Catalyse hétérogène, Cobalt alliage, Fer alliage, Platine, Silicium, Face cristalline, Métal transition Alliage.
Wicri :
- topic : Alliage, Cobalt, Platine.

English descriptors

KwdEn :
- Alloys, Cobalt, Cobalt alloy, Crystal face, Electrochemistry, Electrodeposition, Growth, Heterogeneous catalysis, Iron alloy, Morphology, Nucleation, Platinum, Silicon, Substrate, Transition metal Alloys.

Abstract

Electrochemical nucleation and growth of Co and CoFe alloys on Pt/Si(1 0 0) surface from watts (mixed chloride sulfate) baths were studied by voltammetric, chronoamperometric and AFM measurements. The CoFe alloys were deposited from solution with molar ratio of (1/1) and (10/1). The Scharifker and Hills model was employed to analyse the current transients. For both Co and CoFe (10/1) alloys the nucleation was a good agreement with the instantaneous model followed by 3D diffusion-limited growth. Inversely, for CoFe (1/1) alloy the nucleation was an agreement with the progressive model. It is evident that the compositions of the electrolyte influence greatly the type of nucleation. The atomic force microscopy (AFM) images revealed a compact and a granular structure of the electrodeposited Co layers and CoFe alloys.

Affiliations:

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Le document en format XML

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<front><div type="abstract" xml:lang="en">Electrochemical nucleation and growth of Co and CoFe alloys on Pt/Si(1 0 0) surface from watts (mixed chloride sulfate) baths were studied by voltammetric, chronoamperometric and AFM measurements. The CoFe alloys were deposited from solution with molar ratio of (1/1) and (10/1). The Scharifker and Hills model was employed to analyse the current transients. For both Co and CoFe (10/1) alloys the nucleation was a good agreement with the instantaneous model followed by 3D diffusion-limited growth. Inversely, for CoFe (1/1) alloy the nucleation was an agreement with the progressive model. It is evident that the compositions of the electrolyte influence greatly the type of nucleation. The atomic force microscopy (AFM) images revealed a compact and a granular structure of the electrodeposited Co layers and CoFe alloys.</div>
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<s5>09</s5>
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<fC03 i1="09" i2="X" l="SPA"><s0>Catálisis heterogénea</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Cobalt alliage</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Cobalt alloy</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Cobalto aleación</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Fer alliage</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Iron alloy</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Hierro aleación</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Platine</s0>
<s2>NC</s2>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Platinum</s0>
<s2>NC</s2>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Platino</s0>
<s2>NC</s2>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Silicium</s0>
<s2>NC</s2>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Silicon</s0>
<s2>NC</s2>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Silicio</s0>
<s2>NC</s2>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Face cristalline</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Crystal face</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Cara cristal</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Métal transition Alliage</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Transition metal Alloys</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Metal transición Aleación</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Métal transition</s0>
<s2>NC</s2>
<s5>10</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Transition metal</s0>
<s2>NC</s2>
<s5>10</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Metal transición</s0>
<s2>NC</s2>
<s5>10</s5>
</fC07>
<fN21><s1>247</s1>
</fN21>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>Colloquium on Environment, Materials, Physics and Energy</s1>
<s3>Ouargla DZA</s3>
<s4>2004-12-11</s4>
</fA30>
</pR>
</standard>
</inist>
<affiliations><list><country><li>Algérie</li>
<li>France</li>
</country>
<region><li>Alsace (région administrative)</li>
<li>Grand Est</li>
</region>
<settlement><li>Strasbourg</li>
</settlement>
</list>
<tree><country name="Algérie"><noRegion><name sortKey="Sahari, A" sort="Sahari, A" uniqKey="Sahari A" first="A." last="Sahari">A. Sahari</name>
</noRegion>
<name sortKey="Azizi, A" sort="Azizi, A" uniqKey="Azizi A" first="A." last="Azizi">A. Azizi</name>
</country>
<country name="France"><region name="Grand Est"><name sortKey="Schmerber, G" sort="Schmerber, G" uniqKey="Schmerber G" first="G." last="Schmerber">G. Schmerber</name>
</region>
<name sortKey="Abes, M" sort="Abes, M" uniqKey="Abes M" first="M." last="Abes">M. Abes</name>
<name sortKey="Bucher, J P" sort="Bucher, J P" uniqKey="Bucher J" first="J. P." last="Bucher">J. P. Bucher</name>
<name sortKey="Dinia, A" sort="Dinia, A" uniqKey="Dinia A" first="A." last="Dinia">A. Dinia</name>
</country>
</tree>
</affiliations>
</record>

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Electrochemical nucleation and growth of Co and CoFe alloys on Pt/Si substrates

Electrochemical nucleation and growth of Co and CoFe alloys on Pt/Si substrates

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