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Formation study of nanostructured Cr100-xCox (x = 10, 90) alloys

Identifieur interne : 000051 ( PascalFrancis/Checkpoint ); précédent : 000050; suivant : 000052

Formation study of nanostructured Cr100-xCox (x = 10, 90) alloys

Auteurs : S. Louidi [Algérie] ; F. Z. Bentayeb [Algérie] ; W. Tebib [Algérie] ; J. J. Sunol [Espagne] ; L. Escoda [Espagne] ; A. M. Mercier [France]

Source :

RBID : Pascal:12-0425051

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English descriptors

Abstract

Cr90Co10 and Cr10Co90 mixtures were mechanically alloyed in order to obtain nanocrystalline alloys. The obtained powders were characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The structural parameters such as the lattice parameters, the crystallite size, the microstrains and the defect density of the different phases were deduced from the Rietveld refinement of the XRD patterns using the MAUD program. For the Co-rich mixture the evolution with milling time of the SEM micrographs shows a tendency of particle agglomeration. However, in the case of the Cr-rich mixture, the particles tend to the fragmentation. The Rietveld refinement of XRD patterns of the Cr10Co90 mixture reveals the formation of disordered hcp and fcc Co(Cr) solid solutions. In the case of the Cr90Co10 mixture, only a disordered bcc Cr(Co) solid solution is obtained. The changes in the morphology and the structure of the two mixtures are explained on the basis of the mechanical and structural properties.


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<div type="abstract" xml:lang="en">Cr
<sub>90</sub>
Co
<sub>10</sub>
and Cr
<sub>10</sub>
Co
<sub>90</sub>
mixtures were mechanically alloyed in order to obtain nanocrystalline alloys. The obtained powders were characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The structural parameters such as the lattice parameters, the crystallite size, the microstrains and the defect density of the different phases were deduced from the Rietveld refinement of the XRD patterns using the MAUD program. For the Co-rich mixture the evolution with milling time of the SEM micrographs shows a tendency of particle agglomeration. However, in the case of the Cr-rich mixture, the particles tend to the fragmentation. The Rietveld refinement of XRD patterns of the Cr
<sub>10</sub>
Co
<sub>90</sub>
mixture reveals the formation of disordered hcp and fcc Co(Cr) solid solutions. In the case of the Cr
<sub>90</sub>
Co
<sub>10</sub>
mixture, only a disordered bcc Cr(Co) solid solution is obtained. The changes in the morphology and the structure of the two mixtures are explained on the basis of the mechanical and structural properties.</div>
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<s0>Dislocation density</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Broyeur boulet</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Ball mill</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Molino bolas</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Relation structure propriété</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Property structure relationship</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Relación estructura propiedad</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Synthèse nanomatériau</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Nanomaterial synthesis</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Síntesis nanomaterial</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Alliage désordonné</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Disordered alloy</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Aleación desordenada</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Alliage ordonné</s0>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Ordered alloy</s0>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>Aleación ordenada</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Nanocristal</s0>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Nanocrystal</s0>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Nanocristal</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Chrome alliage</s0>
<s5>19</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG">
<s0>Chromium alloys</s0>
<s5>19</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Solution solide</s0>
<s5>20</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG">
<s0>Solid solutions</s0>
<s5>20</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>Cobalt alliage</s0>
<s5>21</s5>
</fC03>
<fC03 i1="19" i2="3" l="ENG">
<s0>Cobalt alloys</s0>
<s5>21</s5>
</fC03>
<fN21>
<s1>331</s1>
</fN21>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>ISMANAM-2011 International Symposium on Metastable Amorphous and Nanostructured Materials1</s1>
<s2>18</s2>
<s3>Gijón ESP</s3>
<s4>2011-06-26</s4>
</fA30>
</pR>
</standard>
</inist>
<affiliations>
<list>
<country>
<li>Algérie</li>
<li>Espagne</li>
<li>France</li>
</country>
<region>
<li>Catalogne</li>
<li>Pays de la Loire</li>
</region>
<settlement>
<li>Le Mans</li>
</settlement>
<orgName>
<li>Université du Maine</li>
</orgName>
</list>
<tree>
<country name="Algérie">
<noRegion>
<name sortKey="Louidi, S" sort="Louidi, S" uniqKey="Louidi S" first="S." last="Louidi">S. Louidi</name>
</noRegion>
<name sortKey="Bentayeb, F Z" sort="Bentayeb, F Z" uniqKey="Bentayeb F" first="F. Z." last="Bentayeb">F. Z. Bentayeb</name>
<name sortKey="Louidi, S" sort="Louidi, S" uniqKey="Louidi S" first="S." last="Louidi">S. Louidi</name>
<name sortKey="Tebib, W" sort="Tebib, W" uniqKey="Tebib W" first="W." last="Tebib">W. Tebib</name>
</country>
<country name="Espagne">
<region name="Catalogne">
<name sortKey="Sunol, J J" sort="Sunol, J J" uniqKey="Sunol J" first="J. J." last="Sunol">J. J. Sunol</name>
</region>
<name sortKey="Escoda, L" sort="Escoda, L" uniqKey="Escoda L" first="L." last="Escoda">L. Escoda</name>
</country>
<country name="France">
<region name="Pays de la Loire">
<name sortKey="Mercier, A M" sort="Mercier, A M" uniqKey="Mercier A" first="A. M." last="Mercier">A. M. Mercier</name>
</region>
</country>
</tree>
</affiliations>
</record>

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