Etude structurale et vibrationnelle d’un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl
Identifieur interne : 000422 ( Ncbi/Merge ); précédent : 000421; suivant : 000423Etude structurale et vibrationnelle d’un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl
Auteurs : Amira Derbel [Tunisie] ; Tahar Mhiri [Tunisie] ; Mohsen Graia [Tunisie]Source :
- Acta Crystallographica Section E: Crystallographic Communications [ 2056-9890 ] ; 2015.
Abstract
In the title complex, the CoII cation has a distorted square-pyramidal coordination environment, being coordinated by four N atoms of four imidazole groups in the basal plane and by a Cl atom in the apical position. In the crystal, the [CoCl(C3H4N2)4]+ cations and chloride Cl− anions are linked
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DOI: 10.1107/S2056989015015807
PubMed: 26594402
PubMed Central: 4647365
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In the crystal, the [CoCl(C<sub>3</sub>H<sub>4</sub>N<sub>2</sub>)<sub>4</sub>]<sup>+</sup> cations and chloride Cl<sup>−</sup> anions are linked <italic>via</italic> N—H⋯Cl hydrogen bonds, forming layers parallel to (010).</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><double pmid="26594402"><pmc><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Etude structurale et vibrationnelle d’un nouveau composé complexe de cobalt: [Co(imidazole)<sub>4</sub>Cl]Cl</title><author><name sortKey="Derbel, Amira" sort="Derbel, Amira" uniqKey="Derbel A" first="Amira" last="Derbel">Amira Derbel</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de l’état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax,<country>Tunisie</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de l’état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax,<country>Tunisie</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Graia, Mohsen" sort="Graia, Mohsen" 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Faculté des Sciences, Université de Sfax, BP W 3038 Sfax,<country>Tunisie</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Graia, Mohsen" sort="Graia, Mohsen" uniqKey="Graia M" first="Mohsen" last="Graia">Mohsen Graia</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis,<country>Tunisie</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Crystallographic Communications</title><idno type="eISSN">2056-9890</idno><imprint><date when="2015">2015</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>In the title complex, the Co<sup>II</sup> cation has a distorted square-pyramidal coordination environment, being coordinated by four N atoms of four imidazole groups in the basal plane and by a Cl atom in the apical position. In the crystal, the [CoCl(C<sub>3</sub>H<sub>4</sub>N<sub>2</sub>)<sub>4</sub>]<sup>+</sup> cations and chloride Cl<sup>−</sup> anions are linked <italic>via</italic> N—H⋯Cl hydrogen bonds, forming layers parallel to (010).</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI></pmc><pubmed><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.</title><author><name sortKey="Derbel, Amira" sort="Derbel, Amira" uniqKey="Derbel A" first="Amira" last="Derbel">Amira Derbel</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax</wicri:regionArea><wicri:noRegion>BP W 3038 Sfax</wicri:noRegion></affiliation></author><author><name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax</wicri:regionArea><wicri:noRegion>BP W 3038 Sfax</wicri:noRegion></affiliation></author><author><name sortKey="Graia, Mohsen" sort="Graia, Mohsen" uniqKey="Graia M" first="Mohsen" last="Graia">Mohsen Graia</name><affiliation wicri:level="4"><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisie.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis</wicri:regionArea><orgName type="university">Université de Tunis - El Manar</orgName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2015">2015</date><idno type="RBID">pubmed:26594402</idno><idno type="pmid">26594402</idno><idno type="doi">10.1107/S2056989015015807</idno><idno type="wicri:Area/PubMed/Corpus">000009</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000009</idno><idno type="wicri:Area/PubMed/Curation">000009</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000009</idno><idno type="wicri:Area/PubMed/Checkpoint">000009</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000009</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Etude structurale et vibrationnelle d'un nouveau composé complexe de cobalt: [Co(imidazole)4Cl]Cl.</title><author><name sortKey="Derbel, Amira" sort="Derbel, Amira" uniqKey="Derbel A" first="Amira" last="Derbel">Amira Derbel</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax</wicri:regionArea><wicri:noRegion>BP W 3038 Sfax</wicri:noRegion></affiliation></author><author><name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax, Tunisie.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de l'état solide, Faculté des Sciences, Université de Sfax, BP W 3038 Sfax</wicri:regionArea><wicri:noRegion>BP W 3038 Sfax</wicri:noRegion></affiliation></author><author><name sortKey="Graia, Mohsen" sort="Graia, Mohsen" uniqKey="Graia M" first="Mohsen" last="Graia">Mohsen Graia</name><affiliation wicri:level="4"><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, Tunisie.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis</wicri:regionArea><orgName type="university">Université de Tunis - El Manar</orgName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author></analytic><series><title level="j">Acta crystallographica. Section E, Crystallographic communications</title><imprint><date when="2015" type="published">2015</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">In the title complex, chlorido-tetra-kis-(1H-imidazole-κN (3))cobalt(II) chloride, [CoCl(C3H4N2)4]Cl, the Co(II) cation has a distorted square-pyramidal coordination environment. It is coordinated by four N atoms of four imidazole (Im) groups in the basal plane, and by a Cl atom in the apical position. It is isostructural with [Cu(Im)4Cl]Cl [Morzyk-Ociepa et al. (2012 ▸). J. Mol. Struct. 1028, 49-56] and [Cu(Im)4Br]Br [Hossaini Sadr et al. (2004 ▸). Acta Cryst. E60, m1324-m1326]. In the crystal, the [CoCl(C3H4N2)4](+) cations and Cl(-) anions are linked via N-H⋯Cl hydrogen bonds, forming layers parallel to (010). These layers are linked via C-H⋯Cl hydrogen bonds and C-H⋯π and π-π [inter-centroid distance = 3.794 (2) Å] inter-actions, forming a three-dimensional framework. The IR spectrum shows vibrational bands typical for imidazol groups. The monoclinic unit cell of the title compound emulates an ortho-rhom-bic cell as its β angle is close to 90°. The crystal is twinned, with the refined ratio of twin components being 0.569 (1):0.431 (1).</div></front></TEI></pubmed></double></record>Pour manipuler ce document sous Unix (Dilib)
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