catena-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]
Identifieur interne : 000166 ( Ncbi/Merge ); précédent : 000165; suivant : 000167catena-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]
Auteurs : Hanène Hemissi [Tunisie] ; Mohammed Rzaigui [Tunisie, Arabie saoudite] ; Zeid Abdullah Al Othman [Arabie saoudite]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2010.
Abstract
The cyclotetraphosphate anion, [P4O12]4−, forms the title complex with cobalt(II) and quinolinium, {(C9H8N)2[Co(P4O12)(H2O)2]·6H2O}
Url:
DOI: 10.1107/S1600536810002096
PubMed: 21579654
PubMed Central: 2979730
Links toward previous steps (curation, corpus...)
- to stream Pmc, to step Corpus: 000390
- to stream Pmc, to step Curation: 000389
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PMC:2979730Le document en format XML
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-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]</title>
<author><name sortKey="Hemissi, Hanene" sort="Hemissi, Hanene" uniqKey="Hemissi H" first="Hanène" last="Hemissi">Hanène Hemissi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Rzaigui, Mohammed" sort="Rzaigui, Mohammed" uniqKey="Rzaigui M" first="Mohammed" last="Rzaigui">Mohammed Rzaigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Chemistry Departement, Faculty of Sciences, King Saud University, Riyadh,<country>Saudi Arabia</country>
</nlm:aff>
<country xml:lang="fr">Arabie saoudite</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Al Othman, Zeid Abdullah" sort="Al Othman, Zeid Abdullah" uniqKey="Al Othman Z" first="Zeid Abdullah" last="Al Othman">Zeid Abdullah Al Othman</name>
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</nlm:aff>
<country xml:lang="fr">Arabie saoudite</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main"><italic>catena</italic>
-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]</title>
<author><name sortKey="Hemissi, Hanene" sort="Hemissi, Hanene" uniqKey="Hemissi H" first="Hanène" last="Hemissi">Hanène Hemissi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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</author>
<author><name sortKey="Rzaigui, Mohammed" sort="Rzaigui, Mohammed" uniqKey="Rzaigui M" first="Mohammed" last="Rzaigui">Mohammed Rzaigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Chemistry Departement, Faculty of Sciences, King Saud University, Riyadh,<country>Saudi Arabia</country>
</nlm:aff>
<country xml:lang="fr">Arabie saoudite</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Al Othman, Zeid Abdullah" sort="Al Othman, Zeid Abdullah" uniqKey="Al Othman Z" first="Zeid Abdullah" last="Al Othman">Zeid Abdullah Al Othman</name>
<affiliation wicri:level="1"><nlm:aff id="b">Chemistry Departement, Faculty of Sciences, King Saud University, Riyadh,<country>Saudi Arabia</country>
</nlm:aff>
<country xml:lang="fr">Arabie saoudite</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2010">2010</date>
</imprint>
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<front><div type="abstract" xml:lang="en"><p>The cyclotetraphosphate anion, [P<sub>4</sub>
O<sub>12</sub>
]<sup>4−</sup>
, forms the title complex with cobalt(II) and quinolinium, {(C<sub>9</sub>
H<sub>8</sub>
N)<sub>2</sub>
[Co(P<sub>4</sub>
O<sub>12</sub>
)(H<sub>2</sub>
O)<sub>2</sub>
]·6H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
. In the complex anion, the Co<sup>II</sup>
ion, lying on an inversion center, is surrounded by four phosphate O atoms and two water molecules in a slightly distorted octahedral geometry. The crystal structure consists of anionic ribbons of formula {[Co(P<sub>4</sub>
O<sub>12</sub>
)(H<sub>2</sub>
O)<sub>2</sub>
]<sup>2−</sup>
}<sub><italic>n</italic>
</sub>
extending along [100]. A network of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds consolidates the crystal packing.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
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<biblStruct></biblStruct>
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<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">21579654</article-id>
<article-id pub-id-type="pmc">2979730</article-id>
<article-id pub-id-type="publisher-id">hy2272</article-id>
<article-id pub-id-type="doi">10.1107/S1600536810002096</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536810002096</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title><italic>catena</italic>
-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]</article-title>
<alt-title><italic>(C<sub>9</sub>
H<sub>8</sub>
N)<sub>2</sub>
[Co(P<sub>4</sub>
O<sub>12</sub>
)(H<sub>2</sub>
O)<sub>2</sub>
]·6H<sub>2</sub>
O</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Hemissi</surname>
<given-names>Hanène</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Rzaigui</surname>
<given-names>Mohammed</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="aff" rid="b">b</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Al Othman</surname>
<given-names>Zeid Abdullah</given-names>
</name>
<xref ref-type="aff" rid="b">b</xref>
</contrib>
<aff id="a"><label>a</label>
Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</aff>
<aff id="b"><label>b</label>
Chemistry Departement, Faculty of Sciences, King Saud University, Riyadh,<country>Saudi Arabia</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>Hanene.Hemissi@fsb.rnu.tn</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>2</month>
<year>2010</year>
</pub-date>
<pub-date pub-type="epub"><day>23</day>
<month>1</month>
<year>2010</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>23</day>
<month>1</month>
<year>2010</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
. </pmc-comment>
<volume>66</volume>
<issue>Pt 2</issue>
<issue-id pub-id-type="publisher-id">e100200</issue-id>
<fpage>m186</fpage>
<lpage>m187</lpage>
<history><date date-type="received"><day>09</day>
<month>1</month>
<year>2010</year>
</date>
<date date-type="accepted"><day>17</day>
<month>1</month>
<year>2010</year>
</date>
</history>
<permissions><copyright-statement>© Hemissi et al. 2010</copyright-statement>
<copyright-year>2010</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536810002096">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>The cyclotetraphosphate anion, [P<sub>4</sub>
O<sub>12</sub>
]<sup>4−</sup>
, forms the title complex with cobalt(II) and quinolinium, {(C<sub>9</sub>
H<sub>8</sub>
N)<sub>2</sub>
[Co(P<sub>4</sub>
O<sub>12</sub>
)(H<sub>2</sub>
O)<sub>2</sub>
]·6H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
. In the complex anion, the Co<sup>II</sup>
ion, lying on an inversion center, is surrounded by four phosphate O atoms and two water molecules in a slightly distorted octahedral geometry. The crystal structure consists of anionic ribbons of formula {[Co(P<sub>4</sub>
O<sub>12</sub>
)(H<sub>2</sub>
O)<sub>2</sub>
]<sup>2−</sup>
}<sub><italic>n</italic>
</sub>
extending along [100]. A network of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds consolidates the crystal packing.</p>
</abstract>
</article-meta>
</front>
<floats-group><table-wrap id="table1" position="float"><label>Table 1</label>
<caption><title>Hydrogen-bond geometry (Å, °)</title>
</caption>
<table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
</tr>
</thead>
<tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">N1—H1⋯O2</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.88</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.728 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">171</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O1—H11⋯O4</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.83 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.98 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.747 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">154 (3)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O1—H21⋯O2<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.84 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.00 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.841 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">179 (4)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O2—H12⋯O3<sup>ii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.83 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.85 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.666 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">168 (3)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O2—H22⋯O6</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.83 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.95 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.771 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">172 (4)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O3—H13⋯O6</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.86 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.95 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.743 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">152 (3)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O3—H23⋯O5<sup>iii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.87 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.02 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.833 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">154 (3)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O4—H14⋯O9<sup>iv</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.86 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.01 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.824 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">157 (4)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O4—H24⋯O9<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.86 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.06 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.890 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">163 (3)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">C7—H7⋯O9<sup>v</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.93</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.59</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.459 (4)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">156</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">C9—H9⋯O3</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.93</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.54</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.080 (4)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">118</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">C9—H9⋯O10<sup>vi</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.93</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.59</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.381 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">143</td>
</tr>
</tbody>
</table>
<table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-66-0m186-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (ii) <inline-formula><inline-graphic xlink:href="e-66-0m186-efi3.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iii) <inline-formula><inline-graphic xlink:href="e-66-0m186-efi4.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iv) <inline-formula><inline-graphic xlink:href="e-66-0m186-efi5.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (v) <inline-formula><inline-graphic xlink:href="e-66-0m186-efi6.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (vi) <inline-formula><inline-graphic xlink:href="e-66-0m186-efi7.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
.</p>
</table-wrap-foot>
</table-wrap>
</floats-group>
</pmc>
<affiliations><list><country><li>Arabie saoudite</li>
<li>Tunisie</li>
</country>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Hemissi, Hanene" sort="Hemissi, Hanene" uniqKey="Hemissi H" first="Hanène" last="Hemissi">Hanène Hemissi</name>
</noRegion>
<name sortKey="Rzaigui, Mohammed" sort="Rzaigui, Mohammed" uniqKey="Rzaigui M" first="Mohammed" last="Rzaigui">Mohammed Rzaigui</name>
</country>
<country name="Arabie saoudite"><noRegion><name sortKey="Rzaigui, Mohammed" sort="Rzaigui, Mohammed" uniqKey="Rzaigui M" first="Mohammed" last="Rzaigui">Mohammed Rzaigui</name>
</noRegion>
<name sortKey="Al Othman, Zeid Abdullah" sort="Al Othman, Zeid Abdullah" uniqKey="Al Othman Z" first="Zeid Abdullah" last="Al Othman">Zeid Abdullah Al Othman</name>
</country>
</tree>
</affiliations>
</record>
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