Serveur d'exploration sur le cobalt au Maghreb

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Cobalt spinel CoAl2O4 via sol-gel process : elaboration and surface properties

Identifieur interne : 000D69 ( Main/Merge ); précédent : 000D68; suivant : 000D70

Cobalt spinel CoAl2O4 via sol-gel process : elaboration and surface properties

Auteurs : S. Chemlal [Maroc] ; A. Larbot [France] ; M. Persin [France] ; J. Sarrazin [France] ; M. Sghyar [Maroc] ; M. Rafiq [Maroc]

Source :

RBID : Pascal:01-0421046

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English descriptors

Abstract

In this work the preparation of cobalt spinel CoAl2O4 is described. The technique of colloidal solution destabilization was used as the sol-gel process. The powder obtained from the dried gel was characterized by thermal analysis (thermogravimetric and differential), X-ray diffraction, infrared spectroscopy, and specific surface area measurement. Crystallization of CoAl2O4 spinels occurs at about 400°C. The study of surface properties (surface charge and electrophoretic mobility) of the spinel powder fired at 600°C, in suspension in different electrolyte solutions (10-3 molar ionic strength), shows that the spinel material charge depends on the pH of the solution. The spinel sol was used for the preparation of membrane by the slip-casting method.

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Pascal:01-0421046

Le document en format XML

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<sub>2</sub>
O
<sub>4</sub>
via sol-gel process : elaboration and surface properties</title>
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<title xml:lang="en" level="a">Cobalt spinel CoAl
<sub>2</sub>
O
<sub>4</sub>
via sol-gel process : elaboration and surface properties</title>
<author>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Aluminium oxide</term>
<term>Characterization</term>
<term>Cobalt oxide</term>
<term>Colloidal suspension</term>
<term>Crystallization</term>
<term>Destatization</term>
<term>Electrophoretic mobility</term>
<term>Experimental study</term>
<term>Heat treatment</term>
<term>Membrane</term>
<term>Morphology</term>
<term>Powder</term>
<term>Slip casting</term>
<term>Sol gel process</term>
<term>Spinels</term>
<term>Surface area</term>
<term>Surface charge</term>
<term>Thermal properties</term>
<term>Ultrafiltration</term>
<term>pH</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Etude expérimentale</term>
<term>Poudre</term>
<term>Procédé sol gel</term>
<term>Suspension colloïdale</term>
<term>Déstatisation</term>
<term>Traitement thermique</term>
<term>Cristallisation</term>
<term>Spinelles</term>
<term>Aluminium oxyde</term>
<term>Cobalt oxyde</term>
<term>Caractérisation</term>
<term>Propriété thermique</term>
<term>Morphologie</term>
<term>Aire superficielle</term>
<term>Charge superficielle</term>
<term>pH</term>
<term>Mobilité électrophorétique</term>
<term>Coulée en barbotine</term>
<term>8270</term>
<term>8110D</term>
<term>Membrane</term>
<term>Ultrafiltration</term>
<term>CoAl2O4</term>
<term>Al Co O</term>
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<front>
<div type="abstract" xml:lang="en">In this work the preparation of cobalt spinel CoAl
<sub>2</sub>
O
<sub>4</sub>
is described. The technique of colloidal solution destabilization was used as the sol-gel process. The powder obtained from the dried gel was characterized by thermal analysis (thermogravimetric and differential), X-ray diffraction, infrared spectroscopy, and specific surface area measurement. Crystallization of CoAl
<sub>2</sub>
O
<sub>4</sub>
spinels occurs at about 400°C. The study of surface properties (surface charge and electrophoretic mobility) of the spinel powder fired at 600°C, in suspension in different electrolyte solutions (10
<sup>-3</sup>
molar ionic strength), shows that the spinel material charge depends on the pH of the solution. The spinel sol was used for the preparation of membrane by the slip-casting method.</div>
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