The Structure and Luminescent Properties of TlZn(PO3)3
Identifieur interne : 000D07 ( Main/Merge ); précédent : 000D06; suivant : 000D08The Structure and Luminescent Properties of TlZn(PO3)3
Auteurs : A. El Abiad [Maroc] ; B. Es-Sakhi [Maroc] ; M. Mesnaoui [Maroc] ; M. Maazaz [Maroc] ; I. Belharouak [France] ; P. Gravereau [France] ; C. Parent [France] ; G. Wallez [France] ; G. Le Flem [France]Source :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 2000.
English descriptors
Abstract
The crystal structure and the luminescent properties of TlZn(PO3)3 are studied with respect to Tl+ stereochemistry. In this polyphosphate the Tl+ ions are located in tunnels created by the zinc polyphosphate network [Zn(PO3)3]. Actually the thallium atoms are found in a disymmetric configuration and bond calculation allows the determination of the coordination number by oxygen: 6. Nevertheless a large Tl–O distance induces a low stereochemical activity of the 6s2 lone pair. The luminescent properties are analyzed in the context of Fukuda's model. Thermal variations of excitation and emission spectra can be explained by the small influence of the electron–lattice interaction in agreement with the thallium environment.
Url:
DOI: 10.1006/jssc.2000.8898
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000D21
- to stream Istex, to step Curation: 000889
- to stream Istex, to step Checkpoint: 000590
Links to Exploration step
ISTEX:4EBF50C7241036975C91D6909702D32870B0483DLe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">The Structure and Luminescent Properties of TlZn(PO3)3</title>
<author><name sortKey="El Abiad, A" sort="El Abiad, A" uniqKey="El Abiad A" first="A." last="El Abiad">A. El Abiad</name>
</author>
<author><name sortKey="Es Sakhi, B" sort="Es Sakhi, B" uniqKey="Es Sakhi B" first="B." last="Es-Sakhi">B. Es-Sakhi</name>
</author>
<author><name sortKey="Mesnaoui, M" sort="Mesnaoui, M" uniqKey="Mesnaoui M" first="M." last="Mesnaoui">M. Mesnaoui</name>
</author>
<author><name sortKey="Maazaz, M" sort="Maazaz, M" uniqKey="Maazaz M" first="M." last="Maazaz">M. Maazaz</name>
</author>
<author><name sortKey="Belharouak, I" sort="Belharouak, I" uniqKey="Belharouak I" first="I." last="Belharouak">I. Belharouak</name>
</author>
<author><name sortKey="Gravereau, P" sort="Gravereau, P" uniqKey="Gravereau P" first="P." last="Gravereau">P. Gravereau</name>
</author>
<author><name sortKey="Parent, C" sort="Parent, C" uniqKey="Parent C" first="C." last="Parent">C. Parent</name>
</author>
<author><name sortKey="Wallez, G" sort="Wallez, G" uniqKey="Wallez G" first="G." last="Wallez">G. Wallez</name>
</author>
<author><name sortKey="Flem, G Le" sort="Flem, G Le" uniqKey="Flem G" first="G. Le" last="Flem">G. Le Flem</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:4EBF50C7241036975C91D6909702D32870B0483D</idno>
<date when="2000" year="2000">2000</date>
<idno type="doi">10.1006/jssc.2000.8898</idno>
<idno type="url">https://api.istex.fr/document/4EBF50C7241036975C91D6909702D32870B0483D/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000D21</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000D21</idno>
<idno type="wicri:Area/Istex/Curation">000889</idno>
<idno type="wicri:Area/Istex/Checkpoint">000590</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000590</idno>
<idno type="wicri:doubleKey">0022-4596:2000:El Abiad A:the:structure:and</idno>
<idno type="wicri:Area/Main/Merge">000D07</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">The Structure and Luminescent Properties of TlZn(PO3)3</title>
<author><name sortKey="El Abiad, A" sort="El Abiad, A" uniqKey="El Abiad A" first="A." last="El Abiad">A. El Abiad</name>
<affiliation wicri:level="3"><country xml:lang="fr">Maroc</country>
<wicri:regionArea>Faculté des Sciences Semlalia-Marrakech, B.P. 2390, Marrakech</wicri:regionArea>
<placeName><settlement type="city">Marrakech</settlement>
<region nuts="2">Marrakech-Tensift-Al Haouz</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Es Sakhi, B" sort="Es Sakhi, B" uniqKey="Es Sakhi B" first="B." last="Es-Sakhi">B. Es-Sakhi</name>
<affiliation wicri:level="1"><country xml:lang="fr">Maroc</country>
<wicri:regionArea>Département de Physique, Faculté des Sciences d'Agadir, Agadir</wicri:regionArea>
<wicri:noRegion>Agadir</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Mesnaoui, M" sort="Mesnaoui, M" uniqKey="Mesnaoui M" first="M." last="Mesnaoui">M. Mesnaoui</name>
<affiliation wicri:level="3"><country xml:lang="fr">Maroc</country>
<wicri:regionArea>Faculté des Sciences Semlalia-Marrakech, B.P. 2390, Marrakech</wicri:regionArea>
<placeName><settlement type="city">Marrakech</settlement>
<region nuts="2">Marrakech-Tensift-Al Haouz</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Maazaz, M" sort="Maazaz, M" uniqKey="Maazaz M" first="M." last="Maazaz">M. Maazaz</name>
<affiliation wicri:level="3"><country xml:lang="fr">Maroc</country>
<wicri:regionArea>Faculté des Sciences Semlalia-Marrakech, B.P. 2390, Marrakech</wicri:regionArea>
<placeName><settlement type="city">Marrakech</settlement>
<region nuts="2">Marrakech-Tensift-Al Haouz</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Belharouak, I" sort="Belharouak, I" uniqKey="Belharouak I" first="I." last="Belharouak">I. Belharouak</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>ICMCB, UPR, CNRS 9048, Avenue du DR Schweitzer, 33608, Pessac</wicri:regionArea>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Gravereau, P" sort="Gravereau, P" uniqKey="Gravereau P" first="P." last="Gravereau">P. Gravereau</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>ICMCB, UPR, CNRS 9048, Avenue du DR Schweitzer, 33608, Pessac</wicri:regionArea>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Parent, C" sort="Parent, C" uniqKey="Parent C" first="C." last="Parent">C. Parent</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>ICMCB, UPR, CNRS 9048, Avenue du DR Schweitzer, 33608, Pessac</wicri:regionArea>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Wallez, G" sort="Wallez, G" uniqKey="Wallez G" first="G." last="Wallez">G. Wallez</name>
<affiliation wicri:level="4"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de Cristallochimie du Solide, Université Pierre et Marie Curie, 4 Place Jussieu, 75252, Paris cédex 05</wicri:regionArea>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris cédex 05</settlement>
</placeName>
<orgName type="university">Université Pierre-et-Marie-Curie</orgName>
</affiliation>
</author>
<author><name sortKey="Flem, G Le" sort="Flem, G Le" uniqKey="Flem G" first="G. Le" last="Flem">G. Le Flem</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>ICMCB, UPR, CNRS 9048, Avenue du DR Schweitzer, 33608, Pessac</wicri:regionArea>
<placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region>
<region type="old region" nuts="2">Aquitaine</region>
<settlement type="city">Pessac</settlement>
</placeName>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Journal of Solid State Chemistry</title>
<title level="j" type="abbrev">YJSSC</title>
<idno type="ISSN">0022-4596</idno>
<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="2000">2000</date>
<biblScope unit="volume">154</biblScope>
<biblScope unit="issue">2</biblScope>
<biblScope unit="page" from="584">584</biblScope>
<biblScope unit="page" to="590">590</biblScope>
</imprint>
<idno type="ISSN">0022-4596</idno>
</series>
<idno type="istex">4EBF50C7241036975C91D6909702D32870B0483D</idno>
<idno type="DOI">10.1006/jssc.2000.8898</idno>
<idno type="PII">S0022-4596(00)98898-4</idno>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0022-4596</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Tl+ luminescence</term>
<term>Tl+ stereoactivity</term>
<term>TlZn polyphosphate structure</term>
<term>lone pair effect.</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The crystal structure and the luminescent properties of TlZn(PO3)3 are studied with respect to Tl+ stereochemistry. In this polyphosphate the Tl+ ions are located in tunnels created by the zinc polyphosphate network [Zn(PO3)3]. Actually the thallium atoms are found in a disymmetric configuration and bond calculation allows the determination of the coordination number by oxygen: 6. Nevertheless a large Tl–O distance induces a low stereochemical activity of the 6s2 lone pair. The luminescent properties are analyzed in the context of Fukuda's model. Thermal variations of excitation and emission spectra can be explained by the small influence of the electron–lattice interaction in agreement with the thallium environment.</div>
</front>
</TEI>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Main/Merge
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000D07 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Merge/biblio.hfd -nk 000D07 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Terre |area= CobaltMaghrebV1 |flux= Main |étape= Merge |type= RBID |clé= ISTEX:4EBF50C7241036975C91D6909702D32870B0483D |texte= The Structure and Luminescent Properties of TlZn(PO3)3 }}
This area was generated with Dilib version V0.6.32. |