Enhanced Removal of Lead by Chemically and Biologically Treated Carbonaceous Materials
Identifieur interne : 000372 ( Main/Merge ); précédent : 000371; suivant : 000373Enhanced Removal of Lead by Chemically and Biologically Treated Carbonaceous Materials
Auteurs : Mohamed E. Mahmoud [Égypte] ; Maher M. Osman [Égypte] ; Somia B. Ahmed [Égypte] ; Tarek M. Abdel-Fattah [États-Unis]Source :
- The Scientific World Journal [ 1537-744X ] ; 2012.
Abstract
Hybrid sorbents and biosorbents were synthesized via chemical and biological treatment of active carbon by simple and direct redox reaction followed by surface loading of baker's yeast. Surface functionality and morphology of chemically and biologically modified sorbents and biosorbents were studied by Fourier Transform Infrared analysis and scanning electron microscope imaging. Hybrid carbonaceous sorbents and biosorbents were characterized by excellent efficiency and superiority toward lead(II) sorption compared to blank active carbon providing a maximum sorption capacity of lead(II) ion as 500
Url:
DOI: 10.1100/2012/604198
PubMed: 22629157
PubMed Central: 3353520
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PMC:3353520Le document en format XML
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<author><name sortKey="Ahmed, Somia B" sort="Ahmed, Somia B" uniqKey="Ahmed S" first="Somia B." last="Ahmed">Somia B. Ahmed</name>
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<author><name sortKey="Abdel Fattah, Tarek M" sort="Abdel Fattah, Tarek M" uniqKey="Abdel Fattah T" first="Tarek M." last="Abdel-Fattah">Tarek M. Abdel-Fattah</name>
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<front><div type="abstract" xml:lang="en"><p>Hybrid sorbents and biosorbents were synthesized via chemical and biological treatment of active carbon by simple and direct redox reaction followed by surface loading of baker's yeast. Surface functionality and morphology of chemically and biologically modified sorbents and biosorbents were studied by Fourier Transform Infrared analysis and scanning electron microscope imaging. Hybrid carbonaceous sorbents and biosorbents were characterized by excellent efficiency and superiority toward lead(II) sorption compared to blank active carbon providing a maximum sorption capacity of lead(II) ion as 500 <italic>μ</italic>
mol g<sup>−1</sup>
. Sorption processes of lead(II) by these hybrid materials were investigated under the influence of several controlling parameters such as pH, contact time, mass of sorbent and biosorbent, lead(II) concentration, and foreign ions. Lead(II) sorption mechanisms were found to obey the Langmuir and BET isotherm models. The potential applications of chemically and biologically modified-active carbonaceous materials for removal and extraction of lead from real water matrices were also studied via a double-stage microcolumn technique. The results of this study were found to denote to superior recovery values of lead (95.0–99.0 ± 3.0–5.0%) by various carbonaceous-modified-bakers yeast biosorbents.</p>
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