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Calcium Manganese(III) Oxides (CaMn2O4⋅x H2O) as Biomimetic Oxygen‐Evolving Catalysts

Identifieur interne : 000616 ( Main/Exploration ); précédent : 000615; suivant : 000617

Calcium Manganese(III) Oxides (CaMn2O4⋅x H2O) as Biomimetic Oxygen‐Evolving Catalysts

Auteurs : Mohammad Ahdi Najafpour [Iran] ; Till Ehrenberg ; Mathias Wiechen ; Philipp Kurz [Allemagne]

Source :

RBID : ISTEX:450E37F1C870AFE43206BEE821267937DF6F4EE8

English descriptors

Abstract

Biomimetic and efficient: Mixed calcium manganese(III) oxides (see structure; Ca green, Mn red, O white) with elemental compositions and structures mimicking the active site of photosystem II were found to be highly active catalysts for the oxidation of water to molecular oxygen. As for PS II, the presence of Ca2+ greatly enhances the catalyst performance in comparison to the related manganese‐only system Mn2O3.

Url:
DOI: 10.1002/anie.200906745


Affiliations:


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Le document en format XML

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