CoII5(OH)6(SO4)2(H2O)4: the first ferromagnet based on a layered cobalt–hydroxide pillared by inorganic ⋯OSO3–Co(H2O)4–O3SO⋯
Identifieur interne : 000960 ( Main/Curation ); précédent : 000959; suivant : 000961CoII5(OH)6(SO4)2(H2O)4: the first ferromagnet based on a layered cobalt–hydroxide pillared by inorganic ⋯OSO3–Co(H2O)4–O3SO⋯
Auteurs : Mohsen Ben Salah [France, Tunisie] ; Serge Vilminot [France] ; Mireille Richard-Plouet [France] ; Gilles André [France] ; Tahar Mhiri [Tunisie] ; Mohamedally Kurmoopresent Address Laboratoire De Chimie De Coordination Organique Umr7140-Cnrs Université Louis Pasteur Institut Le Bel Rue Blaise Pascal Strasbourg Cedex France. [France]Source :
- Chemical Communications [ 1359-7345 ] ; 2004.
Abstract
The synthetic mineral CoII5(OH)6(SO4)2(H2O)4 (1), obtained by hydrothermal reaction of CoSO4·7H2O and NaOH at 165 °C and consisting of brucite-like Co4(OH)6O2 layers pillared by OSO3–Co(H2O)4–O3SO, is a ferromagnet (TCurie = 12 K, Hc = 580 Oe).
Url:
DOI: 10.1039/b411304g
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<front><div type="abstract">The synthetic mineral CoII5(OH)6(SO4)2(H2O)4 (1), obtained by hydrothermal reaction of CoSO4·7H2O and NaOH at 165 °C and consisting of brucite-like Co4(OH)6O2 layers pillared by OSO3–Co(H2O)4–O3SO, is a ferromagnet (TCurie = 12 K, Hc = 580 Oe).</div>
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