Crystal structure of bis(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ2N2,N3]cobalt(II)
Identifieur interne : 000101 ( Main/Curation ); précédent : 000100; suivant : 000102Crystal structure of bis(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ2N2,N3]cobalt(II)
Auteurs : Abdelhakim Laachir [Maroc] ; Fouad Bentiss [Maroc] ; Salaheddine Guesmi [Maroc] ; Mohamed Saadi [Maroc] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Crystallographic Communications [ 2056-9890 ] ; 2015.
Abstract
The structure of the title compound is isotypic with that of the analogous nickel(II) complex, in which the CoN6 core shows an axially weakly compressed octahedral geometry as opposed to the almost regular geometry exhibited by the NiN6 octahedron.
Url:
DOI: 10.1107/S2056989015006544
PubMed: 25995853
PubMed Central: 4420119
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PMC:4420119Le document en format XML
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)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ<sup>2</sup>
<italic>N</italic>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Crystal structure of bis(azido-κ<italic>N</italic>
)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ<sup>2</sup>
<italic>N</italic>
<sup>2</sup>
,<italic>N</italic>
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<author><name sortKey="Bentiss, Fouad" sort="Bentiss, Fouad" uniqKey="Bentiss F" first="Fouad" last="Bentiss">Fouad Bentiss</name>
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<series><title level="j">Acta Crystallographica Section E: Crystallographic Communications</title>
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<front><div type="abstract" xml:lang="en"><p>The structure of the title compound is isotypic with that of the analogous nickel(II) complex, in which the CoN<sub>6</sub>
core shows an axially weakly compressed octahedral geometry as opposed to the almost regular geometry exhibited by the NiN<sub>6</sub>
octahedron.</p>
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