Synthesis, Characterization and Crystal Structure of a new Cobalt Borophosphate, NaCoH2BP2O9
Identifieur interne : 000232 ( Istex/Curation ); précédent : 000231; suivant : 000233Synthesis, Characterization and Crystal Structure of a new Cobalt Borophosphate, NaCoH2BP2O9
Auteurs : A. Guesmi [Tunisie] ; A. Driss [Tunisie]Source :
- Advanced Engineering Materials [ 1438-1656 ] ; 2004-10.
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Abstract
A new sodium cobalt hydrogen borophosphate, NaCoH2BP2O9, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single‐crystal x‐ray diffraction method]. The structure consists in anionic groups [(H2BP2O9)3‐]2 (centrosymmetric units [HP(2)O3O1/2‐HBO2O2/2‐P(1)O3O1/2]2) which are interconnected by sharing corners with the Co2O10 bioctahedral units. The framework connection is reinforced by hydrogen bonds.
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DOI: 10.1002/adem.200400088
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