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Sulfide petrology of four nakhlites: Northwest Africa 817, Northwest Africa 998, Nakhla, and Governador Valadares

Identifieur interne : 001A01 ( Istex/Corpus ); précédent : 001A00; suivant : 001A02

Sulfide petrology of four nakhlites: Northwest Africa 817, Northwest Africa 998, Nakhla, and Governador Valadares

Auteurs : Vincent Chevrier ; Jean-Pierre Lorand ; Violaine Sautter

Source :

RBID : ISTEX:B2E8B215DAF9624C1036B5E91E4BC4B96BEA5EE9

Abstract

Abstract– The nakhlites contain small proportions of Cu‐Fe‐Ni sulfide minerals; we have studied these sulfides in Northwest Africa (NWA) 998, Nakhla, Governador Valadares, and NWA 817 with optical microscopy, scanning electron microscope, and electron microprobe. Modal abundances of magmatic sulfides, as estimated by image analysis on thin section, are uniformly low (0.02 to 0.05 ± 0.03 vol%), i.e., a factor 5 lower than in shergottites. Sulfides occur within the glassy mesostasis, as composite two‐phase Fe‐Ti oxide‐sulfide grains, intimately associated with interstitial grains or locally enclosed in postcumulus melt inclusions (e.g., Governador Valadares) in olivine. They exhibit a uniform low‐Ni monoclinic pyrrhotite composition ± chalcopyrite. There is a gradation of sulfide grain sizes and textures across the nakhlites flow(s): droplets in NWA 817; resorbed blebs in Governador Valadares; more massive, true intercumulus blebs in Nakhla and NWA 998. These nakhlites also show evidence for sulfide weathering. Hot desert finds (e.g., NWA 998 and NWA 817) show a few percent fracture‐filling iron (oxy) hydroxides of likely terrestrial origin. Original sulfides are 50% altered in our NWA 998 section, with iron (oxy) hydroxides at grain boundaries and as complete pseudomorphs. The compositions of unaltered pyrrhotites are homogeneous, close to that of the monoclinic endmember Fe7S8, and are too sulfur‐rich to have been in chemical equilibrium with the late magmatic redox state fixed by the fayalite‐magnetite‐quartz buffer. Therefore, the compositions of the pyrrhotites must have been altered during the later stages of magmatic crystallization, by assimilation of S‐rich regolith and hydrothermal circulation.

Url:
DOI: 10.1111/j.1945-5100.2011.01189.x

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S
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, and are too sulfur‐rich to have been in chemical equilibrium with the late magmatic redox state fixed by the fayalite‐magnetite‐quartz buffer. Therefore, the compositions of the pyrrhotites must have been altered during the later stages of magmatic crystallization, by assimilation of S‐rich regolith and hydrothermal circulation.</p>
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<title>Sulfide petrology of four nakhlites: Northwest Africa 817, Northwest Africa 998, Nakhla, and Governador Valadares</title>
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<titleInfo type="abbreviated" lang="en">
<title>Sulfide petrology in nakhlites</title>
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<title>Sulfide petrology of four nakhlites: Northwest Africa 817, Northwest Africa 998, Nakhla, and Governador Valadares</title>
</titleInfo>
<name type="personal">
<namePart type="given">Vincent</namePart>
<namePart type="family">CHEVRIER</namePart>
<affiliation>W.M. Keck Laboratory for Space and Planetary Simulation, Arkansas Center for Space and Planetary Science, MUSE 202, University of Arkansas, Fayetteville, Arkansas 72701, USA</affiliation>
<description>Correspondence: Corresponding author. E‐mail: </description>
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<name type="personal">
<namePart type="given">Jean‐Pierre</namePart>
<namePart type="family">LORAND</namePart>
<affiliation>Laboratoire de Minéralogie et Cosmochimie, Muséum National d’Histoire Naturelle, CNRS UMR 7202, 61 Rue Buffon, 75005 Paris, France</affiliation>
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<roleTerm type="text">author</roleTerm>
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</name>
<name type="personal">
<namePart type="given">Violaine</namePart>
<namePart type="family">SAUTTER</namePart>
<affiliation>Laboratoire de Minéralogie et Cosmochimie, Muséum National d’Histoire Naturelle, CNRS UMR 7202, 61 Rue Buffon, 75005 Paris, France</affiliation>
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<dateIssued encoding="w3cdtf">2011-06</dateIssued>
<edition>(Received 24 March 2010; revision accepted 16 January 2011)</edition>
<copyrightDate encoding="w3cdtf">2011</copyrightDate>
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<languageTerm type="code" authority="rfc3066">en</languageTerm>
<languageTerm type="code" authority="iso639-2b">eng</languageTerm>
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<abstract>Abstract– The nakhlites contain small proportions of Cu‐Fe‐Ni sulfide minerals; we have studied these sulfides in Northwest Africa (NWA) 998, Nakhla, Governador Valadares, and NWA 817 with optical microscopy, scanning electron microscope, and electron microprobe. Modal abundances of magmatic sulfides, as estimated by image analysis on thin section, are uniformly low (0.02 to 0.05 ± 0.03 vol%), i.e., a factor 5 lower than in shergottites. Sulfides occur within the glassy mesostasis, as composite two‐phase Fe‐Ti oxide‐sulfide grains, intimately associated with interstitial grains or locally enclosed in postcumulus melt inclusions (e.g., Governador Valadares) in olivine. They exhibit a uniform low‐Ni monoclinic pyrrhotite composition ± chalcopyrite. There is a gradation of sulfide grain sizes and textures across the nakhlites flow(s): droplets in NWA 817; resorbed blebs in Governador Valadares; more massive, true intercumulus blebs in Nakhla and NWA 998. These nakhlites also show evidence for sulfide weathering. Hot desert finds (e.g., NWA 998 and NWA 817) show a few percent fracture‐filling iron (oxy) hydroxides of likely terrestrial origin. Original sulfides are 50% altered in our NWA 998 section, with iron (oxy) hydroxides at grain boundaries and as complete pseudomorphs. The compositions of unaltered pyrrhotites are homogeneous, close to that of the monoclinic endmember Fe7S8, and are too sulfur‐rich to have been in chemical equilibrium with the late magmatic redox state fixed by the fayalite‐magnetite‐quartz buffer. Therefore, the compositions of the pyrrhotites must have been altered during the later stages of magmatic crystallization, by assimilation of S‐rich regolith and hydrothermal circulation.</abstract>
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<title>Meteoritics & Planetary Science</title>
</titleInfo>
<genre type="journal">journal</genre>
<identifier type="ISSN">1086-9379</identifier>
<identifier type="eISSN">1945-5100</identifier>
<identifier type="DOI">10.1111/(ISSN)1945-5100</identifier>
<identifier type="PublisherID">MAPS</identifier>
<part>
<date>2011</date>
<detail type="volume">
<caption>vol.</caption>
<number>46</number>
</detail>
<detail type="issue">
<caption>no.</caption>
<number>6</number>
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<extent unit="pages">
<start>769</start>
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<total>16</total>
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<identifier type="DOI">10.1111/j.1945-5100.2011.01189.x</identifier>
<identifier type="ArticleID">MAPS1189</identifier>
<accessCondition type="use and reproduction" contentType="copyright">© The Meteoritical Society, 2011</accessCondition>
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