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Switching of Molecular Spin States in Inorganic Complexes by Temperature, Pressure, Magnetic Field and Light: Towards Molecular Devices

Identifieur interne : 001442 ( Istex/Corpus ); précédent : 001441; suivant : 001443

Switching of Molecular Spin States in Inorganic Complexes by Temperature, Pressure, Magnetic Field and Light: Towards Molecular Devices

Auteurs : Azzedine Bousseksou ; Gábor Molnár ; Galina Matouzenko

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RBID : ISTEX:595E820592F3D4FBC332CD4F3A8D2C42A54A4256

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Abstract

The spin crossover phenomenon in molecular inorganic compounds is one of the most spectacular examples of bistability phenomena leading to a switching between the high‐spin and the low‐spin states of the molecule by several means such as temperature, pressure, light and magnetic field (multi‐property molecular switching). In the present microreview we report our most important findings, both experimental results and theoretical approaches, and discuss possible technological applications for each switching method as well as the recent synthesis of new spin crossover molecular materials. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

Url:
DOI: 10.1002/ejic.200400571

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ISTEX:595E820592F3D4FBC332CD4F3A8D2C42A54A4256

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<affiliation>Laboratoire de Chimie de Coordination, UPR 8241 CNRS, 205 route de Narbonne, 31077 Toulouse, France</affiliation>
<role>
<roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal">
<namePart type="given">Galina</namePart>
<namePart type="family">Matouzenko</namePart>
<affiliation>Laboratoire de Chimie (UMR CNRS and ENS‐Lyon No. 5182), Ecole Normale Supérieure de Lyon, 46, allée d’Italie, 69364 Lyon, France</affiliation>
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<typeOfResource>text</typeOfResource>
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<publisher>WILEY‐VCH Verlag</publisher>
<place>
<placeTerm type="text">Weinheim</placeTerm>
</place>
<dateIssued encoding="w3cdtf">2004-11</dateIssued>
<dateCaptured encoding="w3cdtf">2004-07-01</dateCaptured>
<copyrightDate encoding="w3cdtf">2004</copyrightDate>
</originInfo>
<language>
<languageTerm type="code" authority="rfc3066">en</languageTerm>
<languageTerm type="code" authority="iso639-2b">eng</languageTerm>
</language>
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<internetMediaType>text/html</internetMediaType>
<extent unit="figures">27</extent>
<extent unit="references">44</extent>
</physicalDescription>
<abstract lang="en">The spin crossover phenomenon in molecular inorganic compounds is one of the most spectacular examples of bistability phenomena leading to a switching between the high‐spin and the low‐spin states of the molecule by several means such as temperature, pressure, light and magnetic field (multi‐property molecular switching). In the present microreview we report our most important findings, both experimental results and theoretical approaches, and discuss possible technological applications for each switching method as well as the recent synthesis of new spin crossover molecular materials. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)</abstract>
<abstract type="graphical" lang="en"></abstract>
<subject lang="en">
<genre>keywords</genre>
<topic>Spin crossover</topic>
<topic>Metastability</topic>
<topic>Hysteresis loop</topic>
<topic>Pressure</topic>
<topic>Magnetic field</topic>
<topic>Dielectric properties</topic>
<topic>Ising‐like model</topic>
</subject>
<relatedItem type="host">
<titleInfo>
<title>European Journal of Inorganic Chemistry</title>
</titleInfo>
<titleInfo type="abbreviated">
<title>Eur. J. Inorg. Chem.</title>
</titleInfo>
<genre type="journal">journal</genre>
<subject>
<genre>article-category</genre>
<topic>Microreview</topic>
</subject>
<identifier type="ISSN">1434-1948</identifier>
<identifier type="eISSN">1099-0682</identifier>
<identifier type="DOI">10.1002/(ISSN)1099-0682c</identifier>
<identifier type="PublisherID">EJIC</identifier>
<part>
<date>2004</date>
<detail type="volume">
<caption>vol.</caption>
<number>2004</number>
</detail>
<detail type="issue">
<caption>no.</caption>
<number>22</number>
</detail>
<extent unit="pages">
<start>4353</start>
<end>4369</end>
<total>17</total>
</extent>
</part>
</relatedItem>
<identifier type="istex">595E820592F3D4FBC332CD4F3A8D2C42A54A4256</identifier>
<identifier type="DOI">10.1002/ejic.200400571</identifier>
<identifier type="ArticleID">EJIC200400571</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Copyright © 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</accessCondition>
<recordInfo>
<recordContentSource>WILEY</recordContentSource>
<recordOrigin>WILEY‐VCH Verlag</recordOrigin>
</recordInfo>
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</metadata>
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