New Multidimensional Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand {dcno– = [(NC)2CC(O)O(CH2)2OH]–}
Identifieur interne : 001182 ( Istex/Corpus ); précédent : 001181; suivant : 001183New Multidimensional Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand {dcno– = [(NC)2CC(O)O(CH2)2OH]–}
Auteurs : Samia Benmansour ; Fatima Setifi ; Smail Triki ; Jean-Yves Salaün ; Fanny Vandevelde ; Jean Sala-Pala ; Carlos J. G Mez-García ; Thierry RoisnelSource :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2007-01.
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Abstract
New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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DOI: 10.1002/ejic.200600449
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ISTEX:D0F151EAB21E95BC0184CBD6AF2319FB8DB10DD4Le document en format XML
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P. 809, 29285 Brest Cedex, France</mods:affiliation></affiliation><affiliation><mods:affiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</mods:affiliation></affiliation></author><author><name sortKey="Setifi, Fatima" sort="Setifi, Fatima" uniqKey="Setifi F" first="Fatima" last="Setifi">Fatima Setifi</name><affiliation><mods:affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</mods:affiliation></affiliation><affiliation><mods:affiliation>Permanent address: Département de Chimie, Faculté des Sciences, Université Ferhat‐Abbas, Sétif 19000, Algeria</mods:affiliation></affiliation></author><author><name sortKey="Triki, Smail" sort="Triki, Smail" uniqKey="Triki S" first="Smail" last="Triki">Smail Triki</name><affiliation><mods:affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: triki@univ‐brest.fr</mods:affiliation></affiliation></author><author><name sortKey="Salaun, Jean Ves" sort="Salaun, Jean Ves" uniqKey="Salaun J" first="Jean-Yves" last="Salaün">Jean-Yves Salaün</name><affiliation><mods:affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Vandevelde, Fanny" sort="Vandevelde, Fanny" uniqKey="Vandevelde F" first="Fanny" last="Vandevelde">Fanny Vandevelde</name><affiliation><mods:affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Sala Ala, Jean" sort="Sala Ala, Jean" uniqKey="Sala Ala J" first="Jean" last="Sala-Pala">Jean Sala-Pala</name><affiliation><mods:affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="G Mez Arcia, Carlos J" sort="G Mez Arcia, Carlos J" uniqKey="G Mez Arcia C" first="Carlos J." last="G Mez-García">Carlos J. G Mez-García</name><affiliation><mods:affiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</mods:affiliation></affiliation></author><author><name sortKey="Roisnel, Thierry" sort="Roisnel, Thierry" uniqKey="Roisnel T" first="Thierry" last="Roisnel">Thierry Roisnel</name><affiliation><mods:affiliation>UMR 6226 CNRS – Université de Rennes 1 Ave du Gal Leclerc, 35042 Rennes Cedex, France</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">European Journal of Inorganic Chemistry</title><title level="j" type="abbrev">Eur. J. Inorg. Chem.</title><idno type="ISSN">1434-1948</idno><idno type="eISSN">1099-0682</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2007-01">2007-01</date><biblScope unit="volume">2007</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="186">186</biblScope><biblScope unit="page" to="194">194</biblScope></imprint><idno type="ISSN">1434-1948</idno></series><idno type="istex">D0F151EAB21E95BC0184CBD6AF2319FB8DB10DD4</idno><idno type="DOI">10.1002/ejic.200600449</idno><idno type="ArticleID">EJIC200600449</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1434-1948</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bridging ligands</term><term>Coordination polymers</term><term>Cyano carbanions</term><term>Magnetic properties</term><term>Multidimensional networks</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract">New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</div></front></TEI><istex><corpusName>wiley</corpusName><author><json:item><name>Samia Benmansour</name><affiliations><json:string>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</json:string><json:string>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</json:string></affiliations></json:item><json:item><name>Fatima Setifi</name><affiliations><json:string>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</json:string><json:string>Permanent address: Département de Chimie, Faculté des Sciences, Université Ferhat‐Abbas, Sétif 19000, Algeria</json:string></affiliations></json:item><json:item><name>Smail Triki</name><affiliations><json:string>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</json:string><json:string>E-mail: triki@univ‐brest.fr</json:string></affiliations></json:item><json:item><name>Jean‐Yves Salaün</name><affiliations><json:string>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</json:string></affiliations></json:item><json:item><name>Fanny Vandevelde</name><affiliations><json:string>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</json:string></affiliations></json:item><json:item><name>Jean Sala‐Pala</name><affiliations><json:string>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</json:string></affiliations></json:item><json:item><name>Carlos J. Gómez‐García</name><affiliations><json:string>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. 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P. 809, 29285 Brest Cedex, France</affiliation><affiliation>Permanent address: Département de Chimie, Faculté des Sciences, Université Ferhat‐Abbas, Sétif 19000, Algeria</affiliation></author><author xml:id="author-3"><persName><forename type="first">Smail</forename><surname>Triki</surname></persName><email>triki@univ‐brest.fr</email><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation></author><author xml:id="author-4"><persName><forename type="first">Jean‐Yves</forename><surname>Salaün</surname></persName><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation></author><author xml:id="author-5"><persName><forename type="first">Fanny</forename><surname>Vandevelde</surname></persName><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation></author><author xml:id="author-6"><persName><forename type="first">Jean</forename><surname>Sala‐Pala</surname></persName><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation></author><author xml:id="author-7"><persName><forename type="first">Carlos J.</forename><surname>Gómez‐García</surname></persName><affiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</affiliation></author><author xml:id="author-8"><persName><forename type="first">Thierry</forename><surname>Roisnel</surname></persName><affiliation>UMR 6226 CNRS – Université de Rennes 1 Ave du Gal Leclerc, 35042 Rennes Cedex, France</affiliation></author></analytic><monogr><title level="j">European Journal of Inorganic Chemistry</title><title level="j" type="abbrev">Eur. J. Inorg. Chem.</title><idno type="pISSN">1434-1948</idno><idno type="eISSN">1099-0682</idno><idno type="DOI">10.1002/(ISSN)1099-0682c</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2007-01"></date><biblScope unit="volume">2007</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="186">186</biblScope><biblScope unit="page" to="194">194</biblScope></imprint></monogr><idno type="istex">D0F151EAB21E95BC0184CBD6AF2319FB8DB10DD4</idno><idno type="DOI">10.1002/ejic.200600449</idno><idno type="ArticleID">EJIC200600449</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>2007</date></creation><langUsage><language ident="en">en</language></langUsage><abstract><p>New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</p></abstract><abstract xml:lang="en" style="graphical"><p></p></abstract><textClass xml:lang="en"><keywords scheme="keyword"><list><head>keywords</head><item><term>Cyano carbanions</term></item><item><term>Bridging ligands</term></item><item><term>Coordination polymers</term></item><item><term>Multidimensional networks</term></item><item><term>Magnetic properties</term></item></list></keywords></textClass><textClass><keywords scheme="Journal Subject"><list><head>article-category</head><item><term>Full Paper</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2006-05-13">Received</change><change when="2007-01">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><original>false</original><mimetype>text/plain</mimetype><extension>txt</extension><uri>https://api.istex.fr/document/D0F151EAB21E95BC0184CBD6AF2319FB8DB10DD4/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1099-0682c</doi><issn type="print">1434-1948</issn><issn type="electronic">1099-0682</issn><idGroup><id type="product" value="EJIC"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="EUROPEAN JOURNAL OF INORGANIC CHEMISTRY">European Journal of Inorganic Chemistry</title><title type="short">Eur. J. Inorg. Chem.</title></titleGroup></publicationMeta><publicationMeta level="part" position="10"><doi origin="wiley" registered="yes">10.1002/ejic.v2007:1</doi><numberingGroup><numbering type="journalVolume" number="2007">2007</numbering><numbering type="journalIssue">1</numbering></numberingGroup><coverDate startDate="2007-01">January 2007</coverDate></publicationMeta><publicationMeta level="unit" type="bookReview" position="24" status="forIssue"><doi origin="wiley" registered="yes">10.1002/ejic.200600449</doi><idGroup><id type="unit" value="EJIC200600449"></id></idGroup><countGroup><count type="pageTotal" number="9"></count></countGroup><titleGroup><title type="articleCategory">Full Paper</title><title type="tocHeading1">Full Papers</title></titleGroup><copyright ownership="publisher">Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2006-05-13"></event><event type="firstOnline" date="2006-11-21"></event><event type="publishedOnlineFinalForm" date="2006-12-21"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.6 mode:FullText source:FullText result:FullText mathml2tex" date="2010-04-20"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-24"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-16"></event></eventGroup><numberingGroup><numbering type="pageFirst">186</numbering><numbering type="pageLast">194</numbering></numberingGroup><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:EJIC.EJIC200600449.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="5"></count><count type="tableTotal" number="2"></count><count type="referenceTotal" number="27"></count></countGroup><titleGroup><title type="main" xml:lang="en">New Multidimensional Coordination Polymers with μ<sub>2</sub>‐ and μ<sub>3</sub>‐dcno Cyano Carbanion Ligand {dcno<sup>–</sup> = [(NC)<sub>2</sub>CC(O)O(CH<sub>2</sub>)<sub>2</sub>OH]<sup>–</sup>}</title><title type="short" xml:lang="en">Coordination Polymers with μ<sub>2</sub>‐ and μ<sub>3</sub>‐dcno Cyano Carbanion Ligand</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1 #af2"><personName><givenNames>Samia</givenNames><familyName>Benmansour</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1 #af4"><personName><givenNames>Fatima</givenNames><familyName>Setifi</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Smail</givenNames><familyName>Triki</familyName></personName><contactDetails><email normalForm="triki@univ-brest.fr">triki@univ‐brest.fr</email></contactDetails></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Jean‐Yves</givenNames><familyName>Salaün</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Fanny</givenNames><familyName>Vandevelde</familyName></personName></creator><creator xml:id="au6" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Jean</givenNames><familyName>Sala‐Pala</familyName></personName></creator><creator xml:id="au7" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Carlos J.</givenNames><familyName>Gómez‐García</familyName></personName></creator><creator xml:id="au8" creatorRole="author" affiliationRef="#af3"><personName><givenNames>Thierry</givenNames><familyName>Roisnel</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="FR" type="organization"><unparsedAffiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="ES" type="organization"><unparsedAffiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</unparsedAffiliation></affiliation><affiliation xml:id="af3" countryCode="FR" type="organization"><unparsedAffiliation>UMR 6226 CNRS – Université de Rennes 1 Ave du Gal Leclerc, 35042 Rennes Cedex, France</unparsedAffiliation></affiliation><affiliation xml:id="af4" countryCode="DZ" type="organization"><unparsedAffiliation>Permanent address: Département de Chimie, Faculté des Sciences, Université Ferhat‐Abbas, Sétif 19000, Algeria</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Cyano carbanions</keyword><keyword xml:id="kwd2">Bridging ligands</keyword><keyword xml:id="kwd3">Coordination polymers</keyword><keyword xml:id="kwd4">Multidimensional networks</keyword><keyword xml:id="kwd5">Magnetic properties</keyword></keywordGroup><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>New polymeric materials [M(dcno)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>] [M = Fe<sup>II</sup> (<b>1</b>), Co<sup>II</sup> (<b>2</b>)] and [M(dcno)<sub>2</sub>] [M = Cu<sup>II</sup> (<b>3</b>), Mn<sup>II</sup> (<b>4</b>)] with dcno<sup>–</sup> =[(NC)<sub>2</sub>CC(O)O(CH<sub>2</sub>)<sub>2</sub>OH]<sup>–</sup> = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds <b>1</b> and <b>2</b>, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds <b>3</b> and <b>4</b>, each organic anion acts as a μ<sub>3</sub>‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral <i>trans</i>‐MN<sub>4</sub>O<sub>2</sub> environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds <b>1</b> and <b>2</b> and from the OH group of the cyanocarbanion ligand in compounds <b>3</b> and <b>4</b>. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds <b>1</b>, <b>2</b> and <b>3</b>–<b>4</b>, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</p></abstract><abstract type="graphical" xml:lang="en"><p><blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:14341948:media:EJIC200600449:fig000"></mediaResource><mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource><mediaResource alt="original image" rendition="webOriginal" mimeType="image/jpeg" href=""></mediaResource><mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/jpeg" href=""></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>New Multidimensional Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand {dcno– = [(NC)2CC(O)O(CH2)2OH]–}</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>New Multidimensional Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand {dcno– = [(NC)2CC(O)O(CH2)2OH]–}</title></titleInfo><name type="personal"><namePart type="given">Samia</namePart><namePart type="family">Benmansour</namePart><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation><affiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Fatima</namePart><namePart type="family">Setifi</namePart><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation><affiliation>Permanent address: Département de Chimie, Faculté des Sciences, Université Ferhat‐Abbas, Sétif 19000, Algeria</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Smail</namePart><namePart type="family">Triki</namePart><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation><affiliation>E-mail: triki@univ‐brest.fr</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Jean‐Yves</namePart><namePart type="family">Salaün</namePart><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Fanny</namePart><namePart type="family">Vandevelde</namePart><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Jean</namePart><namePart type="family">Sala‐Pala</namePart><affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Carlos J.</namePart><namePart type="family">Gómez‐García</namePart><affiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Thierry</namePart><namePart type="family">Roisnel</namePart><affiliation>UMR 6226 CNRS – Université de Rennes 1 Ave du Gal Leclerc, 35042 Rennes Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="book-reviews" displayLabel="bookReview"></genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2007-01</dateIssued><dateCaptured encoding="w3cdtf">2006-05-13</dateCaptured><copyrightDate encoding="w3cdtf">2007</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType><extent unit="figures">5</extent><extent unit="tables">2</extent><extent unit="references">27</extent></physicalDescription><abstract>New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</abstract><abstract type="graphical" lang="en"></abstract><subject lang="en"><genre>keywords</genre><topic>Cyano carbanions</topic><topic>Bridging ligands</topic><topic>Coordination polymers</topic><topic>Multidimensional networks</topic><topic>Magnetic properties</topic></subject><relatedItem type="host"><titleInfo><title>European Journal of Inorganic Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Eur. J. Inorg. Chem.</title></titleInfo><genre type="journal">journal</genre><subject><genre>article-category</genre><topic>Full Paper</topic></subject><identifier type="ISSN">1434-1948</identifier><identifier type="eISSN">1099-0682</identifier><identifier type="DOI">10.1002/(ISSN)1099-0682c</identifier><identifier type="PublisherID">EJIC</identifier><part><date>2007</date><detail type="volume"><caption>vol.</caption><number>2007</number></detail><detail type="issue"><caption>no.</caption><number>1</number></detail><extent unit="pages"><start>186</start><end>194</end><total>9</total></extent></part></relatedItem><identifier type="istex">D0F151EAB21E95BC0184CBD6AF2319FB8DB10DD4</identifier><identifier type="DOI">10.1002/ejic.200600449</identifier><identifier type="ArticleID">EJIC200600449</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. 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