New Multidimensional Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand {dcno– = [(NC)2CC(O)O(CH2)2OH]–}
Identifieur interne : 001182 ( Istex/Corpus ); précédent : 001181; suivant : 001183New Multidimensional Coordination Polymers with μ2‐ and μ3‐dcno Cyano Carbanion Ligand {dcno– = [(NC)2CC(O)O(CH2)2OH]–}
Auteurs : Samia Benmansour ; Fatima Setifi ; Smail Triki ; Jean-Yves Salaün ; Fanny Vandevelde ; Jean Sala-Pala ; Carlos J. G Mez-García ; Thierry RoisnelSource :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2007-01.
English descriptors
- KwdEn :
Abstract
New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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DOI: 10.1002/ejic.200600449
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<front><div type="abstract">New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</div>
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<titleGroup><title type="main" xml:lang="en" sort="EUROPEAN JOURNAL OF INORGANIC CHEMISTRY">European Journal of Inorganic Chemistry</title>
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<publicationMeta level="part" position="10"><doi origin="wiley" registered="yes">10.1002/ejic.v2007:1</doi>
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<titleGroup><title type="main" xml:lang="en">New Multidimensional Coordination Polymers with μ<sub>2</sub>
‐ and μ<sub>3</sub>
‐dcno Cyano Carbanion Ligand {dcno<sup>–</sup>
= [(NC)<sub>2</sub>
CC(O)O(CH<sub>2</sub>
)<sub>2</sub>
OH]<sup>–</sup>
}</title>
<title type="short" xml:lang="en">Coordination Polymers with μ<sub>2</sub>
‐ and μ<sub>3</sub>
‐dcno Cyano Carbanion Ligand</title>
</titleGroup>
<creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1 #af2"><personName><givenNames>Samia</givenNames>
<familyName>Benmansour</familyName>
</personName>
</creator>
<creator xml:id="au2" creatorRole="author" affiliationRef="#af1 #af4"><personName><givenNames>Fatima</givenNames>
<familyName>Setifi</familyName>
</personName>
</creator>
<creator xml:id="au3" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Smail</givenNames>
<familyName>Triki</familyName>
</personName>
<contactDetails><email normalForm="triki@univ-brest.fr">triki@univ‐brest.fr</email>
</contactDetails>
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<creator xml:id="au4" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Jean‐Yves</givenNames>
<familyName>Salaün</familyName>
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<creator xml:id="au5" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Fanny</givenNames>
<familyName>Vandevelde</familyName>
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<creator xml:id="au6" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Jean</givenNames>
<familyName>Sala‐Pala</familyName>
</personName>
</creator>
<creator xml:id="au7" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Carlos J.</givenNames>
<familyName>Gómez‐García</familyName>
</personName>
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<creator xml:id="au8" creatorRole="author" affiliationRef="#af3"><personName><givenNames>Thierry</givenNames>
<familyName>Roisnel</familyName>
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<affiliationGroup><affiliation xml:id="af1" countryCode="FR" type="organization"><unparsedAffiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</unparsedAffiliation>
</affiliation>
<affiliation xml:id="af2" countryCode="ES" type="organization"><unparsedAffiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</unparsedAffiliation>
</affiliation>
<affiliation xml:id="af3" countryCode="FR" type="organization"><unparsedAffiliation>UMR 6226 CNRS – Université de Rennes 1 Ave du Gal Leclerc, 35042 Rennes Cedex, France</unparsedAffiliation>
</affiliation>
<affiliation xml:id="af4" countryCode="DZ" type="organization"><unparsedAffiliation>Permanent address: Département de Chimie, Faculté des Sciences, Université Ferhat‐Abbas, Sétif 19000, Algeria</unparsedAffiliation>
</affiliation>
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<keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Cyano carbanions</keyword>
<keyword xml:id="kwd2">Bridging ligands</keyword>
<keyword xml:id="kwd3">Coordination polymers</keyword>
<keyword xml:id="kwd4">Multidimensional networks</keyword>
<keyword xml:id="kwd5">Magnetic properties</keyword>
</keywordGroup>
<abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title>
<p>New polymeric materials [M(dcno)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
] [M = Fe<sup>II</sup>
(<b>1</b>
), Co<sup>II</sup>
(<b>2</b>
)] and [M(dcno)<sub>2</sub>
] [M = Cu<sup>II</sup>
(<b>3</b>
), Mn<sup>II</sup>
(<b>4</b>
)] with dcno<sup>–</sup>
=[(NC)<sub>2</sub>
CC(O)O(CH<sub>2</sub>
)<sub>2</sub>
OH]<sup>–</sup>
= 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds <b>1</b>
and <b>2</b>
, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds <b>3</b>
and <b>4</b>
, each organic anion acts as a μ<sub>3</sub>
‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral <i>trans</i>
‐MN<sub>4</sub>
O<sub>2</sub>
environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds <b>1</b>
and <b>2</b>
and from the OH group of the cyanocarbanion ligand in compounds <b>3</b>
and <b>4</b>
. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds <b>1</b>
, <b>2</b>
and <b>3</b>
–<b>4</b>
, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</p>
</abstract>
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<name type="personal"><namePart type="given">Samia</namePart>
<namePart type="family">Benmansour</namePart>
<affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation>
<affiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</affiliation>
<role><roleTerm type="text">author</roleTerm>
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<name type="personal"><namePart type="given">Fatima</namePart>
<namePart type="family">Setifi</namePart>
<affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation>
<affiliation>Permanent address: Département de Chimie, Faculté des Sciences, Université Ferhat‐Abbas, Sétif 19000, Algeria</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
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<name type="personal"><namePart type="given">Smail</namePart>
<namePart type="family">Triki</namePart>
<affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation>
<affiliation>E-mail: triki@univ‐brest.fr</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Jean‐Yves</namePart>
<namePart type="family">Salaün</namePart>
<affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Fanny</namePart>
<namePart type="family">Vandevelde</namePart>
<affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Jean</namePart>
<namePart type="family">Sala‐Pala</namePart>
<affiliation>UMR 6521 CNRS – Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Carlos J.</namePart>
<namePart type="family">Gómez‐García</namePart>
<affiliation>ICMol, Universidad de Valencia, Edificio Institutos de Paterna, P. O. Box 22085, 46071 Valencia, Spain</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Thierry</namePart>
<namePart type="family">Roisnel</namePart>
<affiliation>UMR 6226 CNRS – Université de Rennes 1 Ave du Gal Leclerc, 35042 Rennes Cedex, France</affiliation>
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<abstract>New polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2)] and [M(dcno)2] [M = CuII (3), MnII (4)] with dcno– =[(NC)2CC(O)O(CH2)2OH]– = 2,2‐dicyano‐1‐(2‐hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X‐ray crystallography and magnetic measurements. In compounds 1 and 2, each organic ligand acts in a bridging mode with its two nitrogen atoms bound to two different metal ions, while in compounds 3 and 4, each organic anion acts as a μ3‐bridging ligand through its two nitrogen atoms and the oxygen atom of the OH group. Each metal ion has a pseudo‐octahedral trans‐MN4O2 environment with four nitrogen atoms from four different organic ligands and two oxygen atoms from two water molecules in compounds 1 and 2 and from the OH group of the cyanocarbanion ligand in compounds 3 and 4. These coordination modes give rise to 1D, 2D and 3D arrangements for compounds 1, 2 and 3–4, respectively. Magnetic measurements show weak antiferromagnetic coupling between metal centres in the four compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</abstract>
<abstract type="graphical" lang="en"></abstract>
<subject lang="en"><genre>keywords</genre>
<topic>Cyano carbanions</topic>
<topic>Bridging ligands</topic>
<topic>Coordination polymers</topic>
<topic>Multidimensional networks</topic>
<topic>Magnetic properties</topic>
</subject>
<relatedItem type="host"><titleInfo><title>European Journal of Inorganic Chemistry</title>
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<number>2007</number>
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<detail type="issue"><caption>no.</caption>
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<extent unit="pages"><start>186</start>
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