Reactions of cyanoacetylhydrazine complexes with salicylaldehyde and consequent metal-promoted reactions
Identifieur interne : 001006 ( Istex/Corpus ); précédent : 001005; suivant : 001007Reactions of cyanoacetylhydrazine complexes with salicylaldehyde and consequent metal-promoted reactions
Auteurs : M. S. Soliman ; A. M. Shallaby ; R. M. El-Shazely ; M. M. MostafaSource :
- Polyhedron [ 0277-5387 ] ; 1987.
Abstract
The reactions of salicylaldehyde with a suspension of cyanoacetylhydrazine and/or malonic acid amido-hydrazide complexes in aqueous ethanolic solutions afford novel complexes. The structures of the isolated complexes have been elucidated by conventional physical and chemical measurements. The absence of the cyano group band at 2270 cm−1 in the IR spectra of all complexes, except those of CO(II) and Ni(II) complexes, suggests the promotion of H2O to the cyano group (CN) forming amido group. Several structures have been proposed in which salicylaldehyde behaves differently toward the cyanoacetylhydrazine complexes. Also, 1-salicylhydrazo-3-imino-3-(o-formyl) phenoxy propionic acid hydrazide is synthesized either by extraction from the isolated solid complexes using disodium ethylene-diaminetetraacetate or during refluxing of Co(II) and/or Fe(II) complexes with salicylaldehyde. This novel compound is confirmed by elemental analysis, spectra (IR and 1H NMR) and mass spectra.
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DOI: 10.1016/S0277-5387(00)80889-X
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Soliman</name><affiliation><mods:affiliation>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</mods:affiliation></affiliation></author><author><name sortKey="Shallaby, A M" sort="Shallaby, A M" uniqKey="Shallaby A" first="A. M." last="Shallaby">A. M. Shallaby</name><affiliation><mods:affiliation>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</mods:affiliation></affiliation></author><author><name sortKey="El Shazely, R M" sort="El Shazely, R M" uniqKey="El Shazely R" first="R. M." last="El-Shazely">R. M. El-Shazely</name><affiliation><mods:affiliation>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</mods:affiliation></affiliation></author><author><name sortKey="Mostafa, M M" sort="Mostafa, M M" uniqKey="Mostafa M" first="M. M." last="Mostafa">M. M. 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The structures of the isolated complexes have been elucidated by conventional physical and chemical measurements. The absence of the cyano group band at 2270 cm−1 in the IR spectra of all complexes, except those of CO(II) and Ni(II) complexes, suggests the promotion of H2O to the cyano group (CN) forming amido group. Several structures have been proposed in which salicylaldehyde behaves differently toward the cyanoacetylhydrazine complexes. Also, 1-salicylhydrazo-3-imino-3-(o-formyl) phenoxy propionic acid hydrazide is synthesized either by extraction from the isolated solid complexes using disodium ethylene-diaminetetraacetate or during refluxing of Co(II) and/or Fe(II) complexes with salicylaldehyde. This novel compound is confirmed by elemental analysis, spectra (IR and 1H NMR) and mass spectra.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>M.S. Soliman</name><affiliations><json:string>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</json:string></affiliations></json:item><json:item><name>A.M. Shallaby</name><affiliations><json:string>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</json:string></affiliations></json:item><json:item><name>R.M. El-Shazely</name><affiliations><json:string>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</json:string></affiliations></json:item><json:item><name>M.M. 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Also, 1-salicylhydrazo-3-imino-3-(o-formyl) phenoxy propionic acid hydrazide is synthesized either by extraction from the isolated solid complexes using disodium ethylene-diaminetetraacetate or during refluxing of Co(II) and/or Fe(II) complexes with salicylaldehyde. 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The structures of the isolated complexes have been elucidated by conventional physical and chemical measurements. The absence of the cyano group band at 2270 cm−1 in the IR spectra of all complexes, except those of CO(II) and Ni(II) complexes, suggests the promotion of H2O to the cyano group (CN) forming amido group. Several structures have been proposed in which salicylaldehyde behaves differently toward the cyanoacetylhydrazine complexes. Also, 1-salicylhydrazo-3-imino-3-(o-formyl) phenoxy propionic acid hydrazide is synthesized either by extraction from the isolated solid complexes using disodium ethylene-diaminetetraacetate or during refluxing of Co(II) and/or Fe(II) complexes with salicylaldehyde. This novel compound is confirmed by elemental analysis, spectra (IR and 1H NMR) and mass spectra.</p></abstract></profileDesc><revisionDesc><change when="1987">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><original>false</original><mimetype>text/plain</mimetype><extension>txt</extension><uri>https://api.istex.fr/document/C532667AF84DEC2B1EB71F827AABDD2459F50302/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla"><item-info><jid>POLY</jid><aid>0080889X</aid><ce:pii>S0277-5387(00)80889-X</ce:pii><ce:doi>10.1016/S0277-5387(00)80889-X</ce:doi><ce:copyright type="unknown" year="1987"></ce:copyright></item-info><head><ce:title>Reactions of cyanoacetylhydrazine complexes with salicylaldehyde and consequent metal-promoted reactions</ce:title><ce:author-group><ce:author><ce:given-name>M.S.</ce:given-name><ce:surname>Soliman</ce:surname></ce:author><ce:author><ce:given-name>A.M.</ce:given-name><ce:surname>Shallaby</ce:surname></ce:author><ce:author><ce:given-name>R.M.</ce:given-name><ce:surname>El-Shazely</ce:surname></ce:author><ce:author><ce:given-name>M.M.</ce:given-name><ce:surname>Mostafa</ce:surname><ce:cross-ref refid="COR1"><ce:sup>∗</ce:sup></ce:cross-ref><ce:cross-ref refid="FN1"><ce:sup>1</ce:sup></ce:cross-ref></ce:author><ce:affiliation><ce:textfn>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</ce:textfn></ce:affiliation><ce:correspondence id="COR1"><ce:label>*</ce:label><ce:text>Author to whom correspondence should be addressed.</ce:text></ce:correspondence><ce:footnote id="FN1"><ce:label>1</ce:label><ce:note-para>Present adress: Institut National De L'Enseignement, Superieur De L'Hydraulique De Tlemcen, B.P. 119, Algerie.</ce:note-para></ce:footnote></ce:author-group><ce:date-received day="14" month="1" year="1986"></ce:date-received><ce:date-accepted day="17" month="11" year="1986"></ce:date-accepted><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>The reactions of salicylaldehyde with a suspension of cyanoacetylhydrazine and/or malonic acid amido-hydrazide complexes in aqueous ethanolic solutions afford novel complexes. The structures of the isolated complexes have been elucidated by conventional physical and chemical measurements. The absence of the cyano group band at 2270 cm<ce:sup>−1</ce:sup> in the IR spectra of all complexes, except those of CO(II) and Ni(II) complexes, suggests the promotion of H<ce:inf>2</ce:inf>O to the cyano group (CN) forming amido group. Several structures have been proposed in which salicylaldehyde behaves differently toward the cyanoacetylhydrazine complexes. Also, 1-salicylhydrazo-3-imino-3-(<ce:italic>o</ce:italic>-formyl) phenoxy propionic acid hydrazide is synthesized either by extraction from the isolated solid complexes using disodium ethylene-diaminetetraacetate or during refluxing of Co(II) and/or Fe(II) complexes with salicylaldehyde. This novel compound is confirmed by elemental analysis, spectra (IR and <ce:sup loc="pre">1</ce:sup>H NMR) and mass spectra.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>Reactions of cyanoacetylhydrazine complexes with salicylaldehyde and consequent metal-promoted reactions</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Reactions of cyanoacetylhydrazine complexes with salicylaldehyde and consequent metal-promoted reactions</title></titleInfo><name type="personal"><namePart type="given">M.S.</namePart><namePart type="family">Soliman</namePart><affiliation>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">A.M.</namePart><namePart type="family">Shallaby</namePart><affiliation>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">R.M.</namePart><namePart type="family">El-Shazely</namePart><affiliation>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.M.</namePart><namePart type="family">Mostafa</namePart><affiliation>Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt</affiliation><description>Author to whom correspondence should be addressed.</description><description>Present adress: Institut National De L'Enseignement, Superieur De L'Hydraulique De Tlemcen, B.P. 119, Algerie.</description><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1987</dateIssued><copyrightDate encoding="w3cdtf">1987</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">The reactions of salicylaldehyde with a suspension of cyanoacetylhydrazine and/or malonic acid amido-hydrazide complexes in aqueous ethanolic solutions afford novel complexes. The structures of the isolated complexes have been elucidated by conventional physical and chemical measurements. The absence of the cyano group band at 2270 cm−1 in the IR spectra of all complexes, except those of CO(II) and Ni(II) complexes, suggests the promotion of H2O to the cyano group (CN) forming amido group. Several structures have been proposed in which salicylaldehyde behaves differently toward the cyanoacetylhydrazine complexes. Also, 1-salicylhydrazo-3-imino-3-(o-formyl) phenoxy propionic acid hydrazide is synthesized either by extraction from the isolated solid complexes using disodium ethylene-diaminetetraacetate or during refluxing of Co(II) and/or Fe(II) complexes with salicylaldehyde. This novel compound is confirmed by elemental analysis, spectra (IR and 1H NMR) and mass spectra.</abstract><relatedItem type="host"><titleInfo><title>Polyhedron</title></titleInfo><titleInfo type="abbreviated"><title>POLY</title></titleInfo><genre type="journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">1987</dateIssued></originInfo><identifier type="ISSN">0277-5387</identifier><identifier type="PII">S0277-5387(00)X0281-1</identifier><part><date>1987</date><detail type="volume"><number>6</number><caption>vol.</caption></detail><detail type="issue"><number>6</number><caption>no.</caption></detail><extent unit="issue pages"><start>1165</start><end>1515</end></extent><extent unit="pages"><start>1319</start><end>1323</end></extent></part></relatedItem><identifier type="istex">C532667AF84DEC2B1EB71F827AABDD2459F50302</identifier><identifier type="DOI">10.1016/S0277-5387(00)80889-X</identifier><identifier type="PII">S0277-5387(00)80889-X</identifier><recordInfo><recordContentSource>ELSEVIER</recordContentSource></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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