Serveur d'exploration sur le cobalt au Maghreb

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A new solution route to silicates. Part 3: Aqueous sol-gel synthesis of willemite and potassium antimony silicate

Identifieur interne : 000B92 ( Istex/Corpus ); précédent : 000B91; suivant : 000B93

A new solution route to silicates. Part 3: Aqueous sol-gel synthesis of willemite and potassium antimony silicate

Auteurs : L. Reynaud ; C. Brouca-Cabarrecq ; A. Mosset ; H. Ahamdane

Source :

RBID : ISTEX:807F640A159A59D977161910B6DE14B6AC3190E0

Abstract

Willemite, α-Zn2SiO4, and KSbOSiO4 (KSS) were prepared by an aqueous sol-gel process, starting from a H2Si2O5 solution as silicon source. Willemite was obtained free from impurities, in a teflon-lined bomb at 473 K under autogenous pressure. In the case of KSS, the same procedure results in a clear solution which gives, by evaporation at room temperature, an amorphous gel. Orthorhombic KSS crystallizes from this gel at 1273 K.

Url:
DOI: 10.1016/0025-5408(96)00097-9

Links to Exploration step

ISTEX:807F640A159A59D977161910B6DE14B6AC3190E0

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